Sharif Digital Repository

Distillation is the most applied unit in the separation processess of the oil and gas industries. Because the distillation process requires energy in the form of the utilities, integration of heat pump systems in the distillation process as an application of these systems is considered in this research. A new and effective methodology of proper integrating of heat pump and distillation columns has been proposed by collecting thermodynamic and thermoeconomic tools. Then, this procedure has been applied on the ethane recovery and NGL fractionation units of 4 & 5 phases of the south pars field. The exergy analysis of the distillation columns is the first step of this methodology as the... 

Distillation is the most widely-used but the most energy-consuming separation process in the chemical industry. The thermal energy added at the reboiler is used to evaporate a liquid mixture and is wasted when liquefying the vapor flow at the condenser to obtain a reflux liquid flow. However, the thermal energy recovered at the condenser cannot be used to heat other flows in the same distillation column since its temperature is lower than the other stages. To improve the low energy efficiency of distillation, various new ideas have been proposed in the literature. One of them is the internally heat-integrated distillation column (HIDiC). In a conventional distillation column, the temperature... 

Helium is known as a strategic material due to its unique properties and applications in the development of advanced industries. Currently, natural gas is the only source from which helium can be produced economically. The United States, Qatar, Algeria, and Russia have the largest share of helium production, respectively. In this research, the process of helium extraction from natural gas and its liquefaction, independent of LNG production based on helium in South Pars gas of Iran, which is the largest helium reservoir in the world, were designed and simulated.In the helium liquefaction section, the speed and accuracy of the process simulation were improved by developing a home code based on... 

Helium is a valuable substance that is widely used in industry and medicine because of its unique properties. Due to the increasing demand for helium in the global market, several helium extraction units have been launched in the world in recent years; Nevertheless, there is still a significant gap between projected global helium production capacity and demand. Today, natural gas is known as the main source of helium on the earth. The method of industrial extraction of helium from natural gas is cryogenic. Due to the low temperature of this process, relatively high power consumption is used to extract helium from natural gas. Therefore, the optimization of this process is of great... 

Due to its unique properties, helium has extensive applications in various fields such as medicine, life sciences, electronic industries, welding, meteorology, and the industries which require low-temperature cooling. Also, designing the cryogenic distillation columns is one of the complex aspects of these plants. In the present study, the distillation column of a helium extraction plant from natural gas has been simulated by means of theta method of convergence. The required thermodynamic properties were determined from the Enhanced Predictive Peng-Robinson (E-PPR 78) equation of state, which has high accuracy in predicting the thermodynamic properties of natural gas componens. The... 

Selecting an appropriate control structure is an important subject in the design of control systems. Distillation column is one of the most popular and widely used unit operations in industry which complete understanding of its operability and controllability is one of the most important issues in the process control engineering. The present work studies the method of Output Controllability Index for nonlinear systems and compares it with Relative Gain Array and Condition Number. By using this index, the extent of intrinsic controllability of a process can be identified quantitatively in the absence of any controller. Also, the controllability of the process can be stated numerically or... 

Finding the optimal heat integrated distillation column sequence is an utmost important optimization problem in process engineering. The frequently used approach in this area is to obtain a suitable sequencing candidate and then accomplish the heat integration based on the application of Pinch technology to finalize the design. This approach reduces the problem complexity at the expense of not necessarily reaching the best possible result. This work follows a genetic super structure approach to systematic and rigorous synthesis of optimal multi-component distillation sequences (including simple and thermally coupled complex columns) and simultaneously heat exchanger networks by using a... 

In this work steady state and dynamic performances of quaternary distillation column sequences designed based on steady state and dynamic cost functions have been investigated. To quantify the dynamic performance, product loss due to disturbances has been considered in the objective function. In addition, variations of operating costs such as utilities have been considered in the objective function. To separate a quaternary mixture into four products, twenty two configurations have been used. It has been observed that the feed composition, disturbance frequency and magnitude affect the dynamic behavior strongly. To decrease the optimization computational load, a scheme that provides a... 

Simulation and controlling nonlinear process is one of the challenging problems in academic and industrial research. Saving data for keeping history of process or arising number of calculation for optimization in control design, is forcing to decrease number of equation or order of system. One of the methods to decrease the order of distillation process is using the travelling wave theory. This solution shows god accuracy for simulation the behavior of distillation column. On the other hand finite difference method as a solver for distillation equation takes some time to converge to steady state condition and the numbers of calculation in this method are high. Finite difference method is... 

Selection of the most appropriate control configuration for two point control strategy in a distillation column is a challenging problem. In the present work, three control configurations namely , and , have been employed to control a high purity distillation column separating the binary mixture of Benzene-Toluene. A simple linear model for the process has been derived via a system identification technique. The uncertainty and performance weights have been defined and have been utilized to design a robust controller based on the μ-synthesis approach. The genetic algorithm is employed and the peak value of μ is minimized in order to obtain appropriate PI controller parameters for each...