Sharif Digital Repository

This research is focused on fabrication of TiO2 layers by electrophoretic deposition (EPD) for application as photoanode in Dye Sensitized Solar Cell (DSC). DSCs are third generation of solar cells, also known as the Grätzel cell, after its inventor Michael Grätzel. A DSC is composed of a porous layer of wide band gap semiconductor such as TiO2 and ZnO, covered with a molecular dye that absorbs sunlight, and a counter electrode contacted by a liquid redox electrolyte. Dye Sensitized semiconductor (photoanode) has important role in conversion of photon to electricity. To achieve higher efficiency, preparation of photoanode with high surface area resulted to enough dye adsorption is necessary.... 

Solid oxide fuel cell (SOFC) is one of the promising candidates for clean energy production. Due to the high operating temperature of SOFC, a protective coating is commonly applied on the surface of interconnects to prevent oxidation. In this study, electrophoretic deposition was employed to prepare a manganese-cobalt spinel coating on the surface of ferritic stainless steel (AISISAE430) substrates. MnCo2O4 powder with an average particle size of 60 nm was utilized and the sintering behavior of the coatings at different temperatures was studied. Non-isothermal and isothermal sintering behavior of the powder compacts were examined by employing a sensitive dilatometer. Master sintering curve... 

Recently magnesium alloys have shown great potential as biodegradable metallic implants. However, due to high corrosion rate in the body environment, these alloys would be degraded before the tissue healing time period. Therefore corrosion resistance of these alloys has to be improved in order to be used in biological environments. In the present work, supposing improvement of corrosion properties of magnesium AZ91D alloy, the alloy has been coated with biocompatible nano-Zirconia particles using Electrophoretic deposition method and the effects of deposition parameters such as bath agitation, Zirconia concentration, current density and duration of deposition process on the properties of the... 

Drug-eluting bone implant coatings is a new era that has gained a lot of attention in recent years. In this matter, drug is loaded in the coating and local and targeted release of the drug results in preventing the side effects of implantation and increasing the healing process of the patient. The aim of this project was to synthesis the antibiotic eluting chitosan-based composite using electrophoretic deposition for bone implant coating. By using electrophoretic deposition chitosan and chitosan-bioglass composite coatings were synthesized. Then the probability of loading of drug into coating by using electrophoretic deposition was evaluated and by using this process chitosan and... 

Implant-associated infections are one of the most serious complications in orthopaedic and trauma surgery as it may result in poor functional outcome, implant failure, chronic osteomyelitis or even death. Great concerns have been taken to reduce implant-associated infections through progressing in operating standards, minimizing the possibility of contamination during surgery, reducing the establishment of infection by perioperative antibiotic prophylaxis, and confining of pathogenic strains by patient isolation. In spite of these preventions, the percentage of postoperative infections is still rising. Composite coatings with bone-bioactivity and drug-eluting capacity are considered as... 

Graphene, the newborn nanomaterial whose unique properties has extensively drawnattention of many scientists in the recent years, is an ideal candidate for sensing applications due to its exclusive properties like extremely high specific surface area, excellent electrical conductivity, andcapability of being easily functionalized. In this research, after reviewing the attempts already performed on detection of DNA, in order to detect the four bases of DNA (G, A, T, and C) via electrochemical approach, graphene nanosheets were synthesized by the popular Hummer’s method and were deposited on a graphite rod by electrophoretic deposition with a vertical preferred orientation. To eliminate the... 

By consideration of increasing demands to use implants and efforts to get technical knowledge and localization of this implants, considerable research in this field is needed. Therefore, presentation of a coating which is able to provide parameters needed for an acceptable implant is the aim of this study. In this direction, modification of surface of metallic implants in order to achieve nanotubes of titanium oxide, with the purpose of providing biocompatibility was done. On the other hand, because chronic infection of the implant’s surrounding is one of the main important reasons in rejection of implants, 〖TiO〗_2 nanotubes as a drug carrier were used in order to solve this problem. So,... 

The aim of this thesis was creating Titania/RGO coating with electrophoretic method to evaluate the corrosion resistance of stainless steel 316. At first Graphene Oxide were synthesized with modified Hammers method and their physical, chemical and morphological properties have been investigated using XRD, FTIR, EDX, TGA, UV-Vis and Raman analysis. then Graphene Oxide was added to the bath of titanium and was deposited on 316 stainless steel substrates. Moreover, corrosion protection of coating has been examined using Poarization test and Electrochemical Impedance Spectrometry. The effect of deposition parameters on corrosion properties of composite coatings were examined. The key variables... 

The main purpose of this research was functionalizing graphene, in order to achieve higher hydrophobicity, and producing nanocomposite of functionalized graphene and titanium dioxide by hydrothermal method, and sequently invastigation on photocatalytic properties of the powders and corrosion properties of EPD coated samples. Graphene oxide was synthesized by improved Hummers method and reduced and sequently was functionalized through the chemical process with hydrazine and octadecylamine respectively. Then the nanocomposite of functionalized graphene-titania was synthesized by use of titanium isopropoxide precursor and its photocatalytic properties were measured. The analysis of the... 

Titania is semiconductor material and have many applications including photocatalysis, photochromic, air and water purification, sensors, and solar cell. In electrophoretic deposition, charged particles dispersed in a stable suspension move towards an oppositely charged electrode, and form dense layer of deposit on it. In this investigation electrophoretic deposition of titania nano-particles in suspensions prepared by different solvents (methanol, ethanol and butanol) with and without dispersant (triethanolamine and polyethylenimine), was studied. Well stabilized suspensions, prepared for electrophoretic deposition. The effects of solvent type, additive concentration, mechanism of particles... 

In First part, the electrophoretic deposition method was utilized to immobilize TiO2 particles on stainless steel substrates. In addition, for the first time, statistics-based experimental design using response surface methodology (RSM) was employed to investigate the effect of four key coating parameters (i.e. applied voltage, calcination temperature, photocatalyst weight percentage, and deposition time) on the photocatalytic degradation. Analysis of variance revealed that the proposed model was adequate. X-ray diffraction (XRD) and scanning electron microscope (SEM) were used to evaluate the effects of the parameters on degradation efficiency. The optimum applied voltage, calcination... 

Dye Sensitized Solar cell (DSC) is the third class of solar cell, which consists of a nanocrystalline, mesoporous of semiconductor(The best one is Tio2), covered with a monolayer of dye molecules, platinum coated on FTO as a counter electrode and a redox electrolyte. This Photovoltaic cell which is promising low-cost materials, works on electron separation of dye molecule, and electron injection to semiconductor’s conduction photo- electrode structure and its porosity is affected the DSC’s performance. Recently, use of electrophoretic deposition (EPD) for TiO2 electrode (which best found for photo-electrode in DSC) fabrication has gained increased interests. In this method charged particles...