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Modeling and Economic Assessment of CO2 Capture by Oxy-fuel Combustion in Power Plants
, M.Sc. Thesis Sharif University of Technology ; Soltanieh, Mohammad (Supervisor)
Abstract
Considering the drastical increase of greenhouse gases in the atmosphere, especially carbon dioxide, reduction of these gases seems necessary to combat global warming. Fossil fuel power plants are one of the main sources of CO2 emission. In this paper, CO2 capture from a natural gas fired steam cycle power plant using oxy-fuel combustion technology is studied. The Integrated Environmental Control Model (IECM) developed by Carnegie Mellon University was used to evaluate the effect of this capture technology on the plant efficiency and economic parameters of the system. Since the oxygen production plant, CO2 capture and transport are cost and energy intensive, the cost of electricity generated...
Worm-like micelles:a new approach for heavy oil recovery from fractured systems
, Article Canadian Journal of Chemical Engineering ; Volume 93, Issue 5 , 2015 , Pages 951-958 ; 00084034 (ISSN) ; Saidian, M ; Mavaddat, M ; Ghazanfari, M. H ; Kharrat, R ; Rashtchian, D ; Sharif University of Technology
Wiley-Liss Inc
2015
Abstract
In this work, a new type of flooding system, "worm-like micelles", in enhanced heavy oil recovery (EOR) has been introduced. Application of these types of surfactants, because of their intriguing and surprising behaviour, is attractive for EOR studies. Fundamental understanding of the sweep efficiencies as well as displacement mechanisms of this flooding system in heterogeneous systems especially for heavy oils remains a topic of debate in the literature. Worm-like micellar surfactant solutions are made up of highly flexible cylindrical aggregates. Such micellar solutions display high surface activity and high viscoelasticity, making them attractive in practical applications for EOR. In this...
The semi-analytical modeling and simulation of the VAPEX process of ""Kuh-e-Mond"" heavy oil reservoir
, Article Petroleum Science and Technology ; Vol. 29, issue. 5 , Oct , 2009 , p. 535-548 ; ISSN: 10916466 ; Masihi, M ; Kharrat, R ; Sharif University of Technology
Abstract
The vapor extraction process (or VAPEX) uses vaporized solvents injected into a horizontal well to form a vapor chamber within the reservoir. Vapor dissolves in the oil and enhances the oil production by decreasing the oil viscosity in heavy oil reservoirs. To evaluate the process we conduct a simulation study on an Iranian heavy oil reservoir called Kuh-e-Mond. In addition, a semi-analytical investigation of the VAPEX process has been performed. The idea is to perform VAPEX simulation for a laboratory model and find a methodology to compare the results of the simulator with the semi-analytical Butler's model. In particular, a semi-analytical dimensionless correlation for production rate...
The semi-analytical modeling and simulation of the VAPEX process of "Kuh-e-Mond" heavy oil reservoir
, Article Petroleum Science and Technology ; Volume 29, Issue 5 , 2011 , Pages 535-548 ; 10916466 (ISSN) ; Masihi, M ; Kharrat, R ; Sharif University of Technology
Abstract
The vapor extraction process (or VAPEX) uses vaporized solvents injected into a horizontal well to form a vapor chamber within the reservoir. Vapor dissolves in the oil and enhances the oil production by decreasing the oil viscosity in heavy oil reservoirs. To evaluate the process we conduct a simulation study on an Iranian heavy oil reservoir called Kuh-e-Mond. In addition, a semi-analytical investigation of the VAPEX process has been performed. The idea is to perform VAPEX simulation for a laboratory model and find a methodology to compare the results of the simulator with the semi-analytical Butler's model. In particular, a semi-analytical dimensionless correlation for production rate...
The role of CO2 and ion type in the dynamic interfacial tension of acidic crude oil/carbonated brine
, Article Petroleum Science ; Volume 16, Issue 4 , 2019 , Pages 850-858 ; 16725107 (ISSN) ; Zeinolabedini Hezave, A ; Ayatollahi, S ; Sharif University of Technology
China University of Petroleum Beijing
2019
Abstract
The effects of CO2 and salt type on the interfacial tension (IFT) between crude oil and carbonated brine (CB) have not been fully understood. This study focuses on measuring the dynamic IFT between acidic crude oil with a total acid number of 1.5 mg KOH/g and fully CO2-saturated aqueous solutions consisting of 15,000 ppm of KCl, NaCl, CaCl2 and MgCl2 at 30 °C and a wide range of pressures (500–4000 psi). The results of IFT measurements showed that solvation of CO2 into all the studied aqueous solutions led to an increase in IFT of acidic crude oil (i.e., comparison of IFT of crude oil/CB and crude oil/brine), while no significant effect was observed for pressure. In contrast, the obtained...
Thermophysical interface properties of crude oil and aqueous solution containing sulfate anions: experimental and modeling approaches
, Article Petroleum Science and Technology ; Volume 37, Issue 21 , 2019 , Pages 2167-2173 ; 10916466 (ISSN) ; Ayatollahi, S ; Sharif University of Technology
Taylor and Francis Inc
2019
Abstract
Sulfate anion is well-known for being one of the most active agents to be injected into the oil reservoirs and being capable of not only altering the interfacial properties of crude oil but also enhancing the water solution properties in oil recovery. In the current study, the effects of temperature and pressure were studied on interfacial tension (IFT) as well as the adsorption behavior of two different solutions containing sulfate anion using experimental measurements and modeling approaches. Although it was expected that IFT values of the studied systems might decrease as temperature increased due to the improvement in the molecule mobility and solubility of crude oil in water, which...
The effects of pH, acidity, asphaltene and resin fraction on crude oil/water interfacial tension
, Article Journal of Petroleum Science and Engineering ; Volume 162 , 2018 , Pages 341-347 ; 09204105 (ISSN) ; Ayatollahi, S ; Sharif University of Technology
Elsevier B.V
2018
Abstract
A basic understanding of the activities of indigenous surfactants of crude oil at the water/oil interface as a function of aqueous phase pH can give us a better insight into the alkaline enhanced oil recovery processes. The present study aimed to elucidate the effect of salinity and crude oil type, specifically the influence of resin and asphaltene molecules during alkaline flooding through interfacial tension (IFT) measurements via pendant drop and spinning techniques. Several model oils containing asphaltene and resin fractions were prepared and their IFTs were compared with those of the original crude oils. Moreover, the elemental analyses of asphaltene and resin fractions were performed,...
Swelling behavior of heavy crude oil during injection of carbonated brine containing chloride anion
, Article Journal of Molecular Liquids ; Volume 276 , 2019 , Pages 7-14 ; 01677322 (ISSN) ; Zeinolabedini Hezave, A ; Ayatollahi, S ; Sharif University of Technology
Elsevier B.V
2019
Abstract
Carbonated brine (CB) injection, known as one of the effective enhanced oil recovery processes, is highly dependent on the reservoir conditions (i.e. temperature and pressure) as well as the type of dissolved salt in aqueous solution. This study is aimed to investigate the influential parameters on the swelling of crude oil as the most important mechanism during CB injection. The swelling of crude oil in the presence of different CB solutions consisted of different salts such as KCl, NaCl, CaCl2 and MgCl2 with constant concentration of 15,000 ppm is studied using a high-pressure, high-temperature visual cell which measures the volume of drop using image processing software based on...
Simulation study of Steam Assisted Gravity Drainage (SAGD) in fractured systems
, Article Oil and Gas Science and Technology ; Volume 64, Issue 4 , 2009 , Pages 477-487 ; 12944475 (ISSN) ; Sharif University of Technology
2009
Abstract
The Steam Assisted Gravity Drainage (SAGD) process, a developed Enhanced Oil Recovery (EOR) process to recover oil and bitumen, has been studied theoretically and experimentally in conventional reservoirs and models and is found a promising EOR method for certain heavy oil reservoirs. In this work simulation studies of the SAGD process were made on different fractured models consisting of fractures in both Near Well Region (NWR) and Above Well Region (AWR) and even in the presence of networked fractures. At early stage of the SAGD process in fractured system, steam moves through the fractures first and then the matrix blocks are heated primarily by conduction and possibly some steam...
Prediction of the interfacial tension between hydrocarbons and carbon dioxide
, Article Petroleum Science and Technology ; Volume 36, Issue 3 , 1 February , 2018 , Pages 227-231 ; 10916466 (ISSN) ; Bemani, A ; Sharif University of Technology
Taylor and Francis Inc
2018
Abstract
In the recent years due to increasing demand for energy and declination of reservoir production, an impressive notice on enhancement of oil recovery has been found. The gas injection especially carbon dioxide injection due to low cost and friendly environmentally of this approach the special attention to CO2 injection increased. The miscibility is known as key factor which effects on enhancement of recovery. The miscibility is controlled by interfacial tension of hydrocarbons and carbon dioxide so the importance of investigation of the interfacial tension becomes highlighted.in this investigation by using radial basis function (RBF) artificial neural network (ANN) as a novel approach the...
Performance evaluation of a new nanocomposite polymer gel for water shutoff in petroleum reservoirs
, Article Journal of Dispersion Science and Technology ; 2018 ; 01932691 (ISSN) ; Ayatollahi, S ; ZareNezhad, B ; Sharif University of Technology
Taylor and Francis Inc
2018
Abstract
A new polymer gel nanocomposite is fabricated for excess water production control (water shut off) in petroleum reservoirs and its rheological behavior is evaluated in the presence of sea water and formation water at the temperature of 100 °C. It is shown that at a high salinity without using SiO2 nanoparticles, the elastic modulus of synthesized polymer gel in the presence of sea water and formation water are 12.5 Pa and 9.8 Pa respectively. However by incorporation of SiO2 nanoparticles in the polymer gel matrix, the elastic modulus of synthesized polymer gel in the presence of sea water and formation water can be improved to 13.56 Pa and 11.57 Pa respectively, which is quite interesting...
Performance evaluation of a new nanocomposite polymer gel for water shutoff in petroleum reservoirs
, Article Journal of Dispersion Science and Technology ; Volume 40, Issue 10 , 2019 , Pages 1479-1487 ; 01932691 (ISSN) ; Ayatollahi, S ; ZareNezhad, B ; Sharif University of Technology
Taylor and Francis Inc
2019
Abstract
A new polymer gel nanocomposite is fabricated for excess water production control (water shut off) in petroleum reservoirs and its rheological behavior is evaluated in the presence of sea water and formation water at the temperature of 100 °C. It is shown that at a high salinity without using SiO2 nanoparticles, the elastic modulus of synthesized polymer gel in the presence of sea water and formation water are 12.5 Pa and 9.8 Pa respectively. However by incorporation of SiO2 nanoparticles in the polymer gel matrix, the elastic modulus of synthesized polymer gel in the presence of sea water and formation water can be improved to 13.56 Pa and 11.57 Pa respectively, which is quite interesting...
Mechanistical study of effect of ions in smart water injection into carbonate oil reservoir
, Article Process Safety and Environmental Protection ; Volume 105 , 2017 , Pages 361-372 ; 09575820 (ISSN) ; Ayatollahi, S ; Riazi, M ; Sharif University of Technology
Institution of Chemical Engineers
2017
Abstract
The concerns for water availability, affordability and environmental consideration have motivated more research on the development of smart water injection for enhanced oil recovery process. Although wettability alteration has been considered as the dominant mechanism, there is an ample space in this area needs to be explored more. Therefore, a systematic series of experiments is designed and performed to examine the effect of salinity and ion type on the wettability of the carbonate rock surface to find the active mechanisms. For this purpose, the concentrations of different salts including NaCl, KCl, CaCl2 and MgCl2 are examined during 10 days of soaking for salts concentrations range of...
Low salinity injection into asphaltenic-carbonate oil reservoir, mechanistical study
, Article Journal of Molecular Liquids ; Volume 216 , 2016 , Pages 377-386 ; 01677322 (ISSN) ; Riazi, M ; Hajibagheri, F ; Ayatollahi, S ; Sharif University of Technology
Abstract
The impacts of salinity adjustment of displacing fluid have recently gained special attention to enhanced oil recovery (EOR). Different mechanisms have been studied widely in the literature while some of them are still subjugated to more scrutiny. The effects of diluted sea water on the interfacial properties of brine and asphaltenic-acidic crude oil and the wettability alteration of carbonate reservoir rock are investigated in this experimental observational work. The measurements of interfacial tension (IFT) and contact angle (CA) as two main parameters are studied. Besides, the effects of asphaltene and resin in the crude oil on the IFT values between the crude oil and aqueous solution...
Investigation of gas injection flooding performance as enhanced oil recovery method
, Article Journal of Natural Gas Science and Engineering ; Volume 29 , 2016 , Pages 37-45 ; 18755100 (ISSN) ; Lashkar Bolooki, M ; ZeinolabediniHezave, A ; Ayatollahi, S ; Sharif University of Technology
Elsevier
Abstract
Asphaltene precipitation and deposition within the reservoir formation is one of the main concerns during enhanced oil recovery (EOR) processes especially during the gas injection. In the current study, different aspects of carbon dioxide (CO2) and nitrogen (N2) injection in the reservoir, was thoroughly examined. The feasibility of using these gases as the injection gas was explored using Bayesian network-based screening method. After recombination and preparation of the live crude oil, precipitation of asphaltene using vanishing interfacial tension (VIT) method and core flooding experimentation was examined. Besides, swelling test was utilized to investigate the effect of CO2 and N2...
Investigating injection of low salinity brine in carbonate rock with the assist of works of cohesion and adhesion and spreading coefficient calculations
, Article Journal of Petroleum Science and Engineering ; Volume 161 , 2018 , Pages 381-389 ; 09204105 (ISSN) ; Ayatollahi, S ; Sharif University of Technology
Elsevier B.V
2018
Abstract
Low salinity (LS) and smart water (SW) flooding processes which receive a great interest as cost-effective and environmental friendly techniques are relatively new enhanced oil recovery methods. Although shifting carbonate surfaces towards a water-wet state is the main mechanism behind these methods, effects of controlling factors (for instance: ion type or salinity) are already remained unsettled. In this regard, the effects of sulfate ion types (i.e. Na2SO4, MgSO4 and CaSO4) and their concentrations (i.e. 0–45,000 ppm) on wettability alteration are investigated using contact angle (CA) measurement technique. In addition, work of cohesion, work of adhesion and spreading coefficient of all...
Foam stability and foam-oil interactions
, Article Petroleum Science and Technology ; Vol. 32, issue. 15 , May , 2014 , p. 1843-1850 ; ISSN: 10916466 ; Ghotbi, C ; Badakhshan, A ; Sharif University of Technology
Abstract
Gas injection into reservoirs can be used to increase oil recovery. However, reservoir heterogeneity and high gas mobility reduce sweep efficiency and decrease recovery. Using foam can reduce gas mobility and therefore increase sweep efficiency. Foam is thermodynamically unstable, so it is important to predict the foam stability. In order to understand the influence of oil presence on foam stability, static experiments performed on foam by varying the type and amount of added oil and molecular weight of added alkane. Also static foam properties have been investigated by varying the surfactant concentration, ionic strength, composition of different salts in the sample, and addition of polymer...
Experimental study of nanoparticle-surfactant-stabilized CO2 foam: Stability and mobility control
, Article Chemical Engineering Research and Design ; Volume 111 , 2016 , Pages 449-460 ; 02638762 (ISSN) ; Riahi, S ; Ayatollahi, S ; Ahmadi, H ; Sharif University of Technology
Institution of Chemical Engineers
2016
Abstract
CO2 injection has proved to be the most common and efficient enhanced oil recovery techniques which leads to more residual oil recovery. Unfavorable sweep efficiency which results in fingering propagation and causes early gas breakthrough is the most challenging issue of gas flooding process. The aim of this work is to study foam stability and analyze the mobility of CO2 foam stabilized by mixture of raw silica nanoparticles and ethyl hexadecyl dimethyl ammonium bromide (cationic surfactant). The result is obtained through both dynamic and static techniques using a new adsorption index.NPS-stabilized foams are generated using Ross-Miles method. A novel index for the adsorption of surfactant...
Experimental study of asphaltene precipitation behavior during miscible carbon dioxide injection
, Article Energy Sources, Part A: Recovery, Utilization and Environmental Effects ; Vol. 36, issue. 14 , July , 2014 , pp. 1523-1530 ; ISSN: 15567036 ; Nakhli, H ; Kharrat, R ; Ghazanfari, M. H ; Aghajani, M ; Sharif University of Technology
Abstract
Many reservoir and production engineers face asphaltene precipitation as a major problem during miscible carbon dioxide flooding projects. Experimental studies regarding asphaltene precipitation are therefore employed to assist in selecting appropriate facilities and proper operation schemes. During this study, a series of high pressure, high temperature experiments are designed and performed to analyze asphaltene precipitation behavior of an Iranian light reservoir crude at reservoir conditions due to natural production and miscible CO2 gas injection. For both sets of experiments, two different temperature levels (including reservoir temperature) are selected to investigate the role of...
Experimental investigation of the influence of supercritical carbon dioxide and supercritical nitrogen injection on tertiary live-oil recovery
, Article Journal of Supercritical Fluids ; Volume 117 , 2016 , Pages 260-269 ; 08968446 (ISSN) ; Vaezian, A ; Zeinolabedini Hezave, A ; Ayatollahi, S ; Riazi, M ; Sharif University of Technology
Elsevier
2016
Abstract
Generally, there are different enhanced oil recovery (EOR) methods. One of the most promising EOR method is the gas injection especially carbon dioxide (CO2) injection since it introduce several unique characteristic desired for higher tertiary oil recovery. In this study, the performance and feasibility of supercritical carbon dioxide (SC-CO2) and supercritical nitrogen (SC-N2) injection to enhanced oil recovery was investigated. In this regard, swelling tests and core flooding experiments were performed to find out whether the injections of these gases are efficient to recover trapped oil in the reservoir. Based on the experimental results, the possible active mechanisms were discussed on...