Sharif Digital Repository

Utilizing the cold energy of liquefied natural gas can reduce the demand of burning fossil fuels for work production and employing refrigeration cycles for seawater desalination. A novel low-temperature cascade power generation cycle combined with a seawater freeze desalination system is proposed to retrieve the cold energy from liquified natural gas. Binary working fluids are utilized to decrease the irreversibilities of the power cycle and enhance the energy recovery efficiency. The effects of the important temperatures of the cycle, pinch temperature of the heat exchangers, number of turbines and their efficiency on the cycle performance are investigated. Optimization of the work... 

In this research, Ag-Al2O3 nanostructures have been prepared via combustion synthesis and ammonium acetate and urea have been applied as fuels. The prepared Ag-Al2O3 nanostructures were characterized by DTA, XRD, SEM, TEM, and BET spectroscopy. The effect of different ratios of silver to alumina and fuel percentage on morphology and particle size of prepared products were investigated. The results showed that using ammonium acetate fuel led to the production of Ag-γ-Al2O3 nanocompounds, while using urea produced Ag-α-Al2O3. Also, the photocatalytic activity of Ag-Al2O3 nanostructures for Congo red degradation was evaluated by UV-Vis diffuse reflectance spectroscopy. The photocatalytic... 

This study investigates the secondary organic aerosol (SOA) formation potential of carburetor motorcycles exhaust. This type of two-wheeler is a popular means of transport in many Asian cities. A volatility-based numerical model was employed to predict SOA formation from a fleet of motorcycles in Tehran, capital of Iran. The fleet was a combination of four-stroke, gasoline-powered motorcycles with different engine displacement volumes. Total hydrocarbon (THC) emission factors of all motorcycles were previously measured in a chassis dynamometer laboratory according to cold start Euro-3 emissions certification test procedures. Due to incomplete combustion and lack of control on exhaust... 

The conventional relations for calculating the fracture stresses consider only elastic deformation but ignore viscoelastic and viscoplastic behaviors. Measuring the joining strength of a composite glass sealant-metallic interconnect specimen at solid oxide cell application relevant at high temperatures is a case where such effects can become significant. In the current study, three-point and four-point bending test results were analyzed using the finite element method (FEM) to assess systematic and random errors. It is shown that plastic deformation of the steel interconnect material at high temperature, although having a large effect on the stress distribution in the... 

The structural integrity of the sealant is critical for the reliability of solid oxide cells (SOCs) stacks. In this study, elastic modulus (E), hardness (H) and fracture toughness (KIC) of a rapid crystallizing glass of BaO–CaO–SiO2 system termed “sealant G” are reported as determined using an indentation test method at room temperature. A wide range of indentation loads (1 mN–10 N) was used to investigate the load-dependency of these mechanical properties. Values of 95 ± 12 GPa, 5.8 ± 0.2 GPa and 1.15 ± 0.07 MPa m0.5 were derived for E, H and KIC using the most suitable indentation loads. An application relevant annealing treatment of 500 h at 800 °C does not lead to a significant change of... 

The fast development of technologies in the smart grids provides new opportunities such as co-optimization of multi-energy systems. One of the new concepts that can utilize multiple energy sources is a hybrid fuel station (HFS). For instance, an HFS can benefit from energy hubs, renewable energies, and natural gas sources to supply electric vehicles along with natural gas vehicles. However, the optimal operation of an HFS deals with uncertainties from different sources that do not have similar natures. Some may lack in term of historical data, and some may have very random and unpredictable behavior. In this study, we present a stochastic mathematical framework to address both types of these... 

In this research, the effect of alternative fuels and the inlet charged air temperature is numerically investigated on the performance of a turbocharged spark-ignition engine. For this purpose, a one-dimensional engine and turbocharger model is created in an engine simulation and performance analysis software and validated with former experimental results. Then, the model is run with four fuel types, including two gasoline types with different octane numbers and two ethanol–gasoline blend fuels—E25 and E85. In each case, the inlet charged air temperature is changed from cold to hot condition and performance characteristics such as the spark advance timing, brake torque, brake-specific fuel... 

Recently, renewable energy sources (RESs) have increasingly being integrated into the power grids as a result of environmental and governmental perspectives. In this regard, the installation of RESs as potential power sources in active distribution systems would benefit the grid by decreasing the power losses, as well as addressing the fossil fuel shortages, and their environmental aspects. Nevertheless, the high-level integration of RESs as well as the development of distributed formations in local systems could challenge the reliable operation of the grid. In this context, conventional approaches could not optimally mitigate the regulation-voltage issue; therefore, utilities have to... 

In the present study, due to various advantages of process miniaturization, the integrated design and operation of a mobile power generation system consisting of a microreactor reformer and a proton exchange membrane fuel cell (PEMFC) are investigated. The hydrogen fuel is supplied through autothermal steam-reforming of methanol in a microreactor leading to a safer, as well as more efficient, and economical operation. A high-temperature polymer membrane fuel cell with external accessories is applied for power generation. Then, simulation-optimization programming is applied for simultaneously optimizing the process design and operation at the same level. The result shows that the implemented... 

Currently, ammonia, as a clean and sustainable energy carrier, is intensively synthesized from its elements during the Haber-Bosch technology. This process requires a large amount of energy and emits numerous amounts of carbon dioxide, because hydrogen is dominantly produced from fossil fuels through reforming processes. Biomass-derived glycerol steam reforming is an attractive alternative to traditional reforming for reducing the dependence on hydrocarbon resources and mitigating climate change. This research aims to intensify a heat-integrated process for the co-production of ammonia and syngas from glycerol valorization. In this process, glycerol reforming continuously provides hydrogen... 

Hydrogen and syngas, as two effective clean fuels, have a considerable stake in the global fuel market. These are dominantly produced from fossil fuels through reforming processes, which lose a large amount of energy and emit numerous amounts of CO2. Bio-renewable glycerol steam reforming is an attractive alternative to traditional reforming for reducing the dependence on hydrocarbon resources and mitigating climate change. This research aims to manage a heat-integrated reactor with three concentric cylinders, containing exothermic-side (methane tri-reforming), endothermic-side (glycerol steam reforming), and permeation-side for co-production of pure hydrogen and syngas. In this process,... 

This research work presents a novel integrated structure for the cogeneration of electricity and renewable syngas. The base structure of the process is developed by solid oxide cells in which electricity is generated by the natural gas-fueled fuel cell unit, and renewable syngas is produced by the electrolyzer cell unit. Direct integration between fuel cell and electrolyzer cell units is established for optimal use of fuel cell off-gases. To improve system's sustainability, a solar power cycle, including solar collectors coupled with an organic Rankine cycle (ORC), is designed to provide renewable electricity for steam and CO2 co-electrolysis operation. 1D mathematical approaches are... 

In this study, the SD-HACNEM (Sharif Dynamic - High order Average Current Nodal Expansion Method) neutron noise simulator in two energy groups using a second-order flux expansion method for two-dimensional rectangular X Y-geometry has been developed. In the first step, the calculations were performed for the steady state and results of ACNEM (Average Current Nodal Expansion Method) and HACNEM (High order Average Current Nodal Expansion Method) were examined and compared. To solve the problem, the power iteration algorithm has been used to calculate the distribution of neutron flux and neutron multiplication factor by considering the coarse-mesh (each fuel assembly one node). To validate the... 

Over 200 million motorcycles in use worldwide account for a substantial portion of global mobile source total hydrocarbons (THC) and carbon monoxide (CO) emissions. In Tehran, capital of Iran, ultrarich inefficient combustion in gasoline-fueled motorcycles results in significantly high CO and THC emissions. Motorcycle catalysts can reduce CO and C3H6(as a representative hydrocarbon) emission factors by 60-80%. In the present work, CO and propylene oxidation over a commercial Pt-Pd-based wiremesh catalyst is studied in a flow reactor setup under simulated conditions relevant to 125 cc four-stroke gasoline carburetor motorcycles. Steady-state individual and co-oxidation tests for CO and... 

Potent carbon-neutral energy carriers bring a vital solution for sustained industrialization and environmental protection. Hydrogen as a novel zero-emission energy carrier offers more than twice energy per unit mass compared to other fuels. Membrane reactor technology transforms gray hydrogen to blue by selective hydrogen separation and carbon dioxide capture from the product mixture. Moreover, improved reactant conversion during reversible steam reforming of methane, methanol, and ethanol; water gas-shift; and dehydrogenation of cyclic and aliphatic hydrocarbons as well as enhanced hydrogen yield are results of selective and distributed hydrogen separation from membrane reactor. In this... 

Solid oxide fuel cells (SOFCs) introduce a promising electrochemical conversion technology to generate electricity directly from fuel oxidization. A three-dimensional (3D) numerical model is proposed to evaluate the SOFC performance by employing computational fluid dynamics (CFD) approach based on the finite element method. This research includes simultaneously solving momentum, energy, and mass transport equations linked with the electrochemical reactions. First, the modeling results of a SOFC system with a rectangular channel in the absence of obstacles are compared with the experimental data, showing very good agreement. The effects of different shapes and numbers of obstacles on fuel... 

One of the key parts of perovskite solar cells which has great influence on their performance and stability is hole transporting layer. Spiro-OMeTAD is extensively used as organic hole transporting material in perovskite solar cells. However, Spiro-OMeTAD is expensive and has low chemical stability. In this study, the solution processed Sb2S3 and Cu3SbS4 nanocrystals have been synthesized and then the n-i-p mesoscopic perovskite solar cells have been fabricated using Spiro-OMeTAD, Sb2S3 and Cu3SbS4 nanocrystals as hole transporting layer at ambient air condition. It is shown that the conduction and valence band levels of the synthesized Sb2S3 and Cu3SbS4 nanocrystals are in the proper... 

In recent years, researchers have paid particular attention to safety, air pollution, and energy consumption, which are all affected by vehicle type. The primary objective of this study is to achieve a thorough understanding of the relationships of transportation attitudes, safety attitudes, personality, and lifestyle with vehicle type for the first time in Iran, as a developing country. For this purpose, an interview questionnaire was designed, and 740 participants were interviewed in Tehran. Vehicle types are categorized into seven groups: mini, compact, medium, heavy, Sport Utility Vehicle (SUV), pickup, and motorcycle. In the first stage, factor analysis was employed to identify the... 

The ultimate purpose of the nuclear power plant safety is to protect the public and the environment from unacceptable radiation exposure in all operational states. This paper presents a novel severe accident management framework to cope with the risk of radioactive material release to the environment. The objective is to reduce the contribution of severe accidents to the large and early release frequencies of radioactive materials for a VVER-1000 nuclear reactor. The proposed approach includes the emergency actions of NPP personnel aiming to recover the lost alternating power and restore the core cooling process by all means available at the site. In addition, mobile equipment including a... 

Renewable energies could be a good solution to the problems associated with fossil fuels. The storage of wind energy by means of small-scale devices rather than large-scale turbines is a topic that has gained lots of interest. In this study, a compact device is proposed to harvest wind energy and transform it into electrical energy, by means of oscillations of a magnet into a coil, using the concept of vortex-induced vibration (VIV) behind a barrier. For a more comprehensive investigation, this system is studied from two viewpoints of fluid mechanics (without magnet) and power generation (with the magnet). For this purpose, an oscillating plate hinging on one side and three barriers with...