Sharif Digital Repository

In the present study, the ACF-TiO2 catalyst was synthesised and used as a catalyst for the destruction of toxic cyanide in both synthetic and real industrial wastewaters. The ACF-TiO2 catalyst was found to be micro-porous with the BET surface area of 163 m2/g. The effect of different operational parameters such as catalyst concentration, cyanide concentration, operation time, and ozone concentration were target parameters in the present study. The findings show that 500 mg/L of catalyst is the optimum value for the photocatalytical process to completely oxidise 25 mg/L of cyanide within 10 min. While it was found that 300 mg/L of catalyst in the presence of 200 mg/h ozone is enough to remove... 

In this research, titanium dioxide-phosphorus (TiO2-P) immobilized on silica phosphoric acid (SPA) was prepared by a simple modified sol–gel method with SPA as a precursor instead of phosphoric acid. TiO2-P thin film photocatalyst immobilized on SPA as a novel high-efficiency photocatalyst was investigated to remove naphthalene as a toxic compound from wastewater. The novel resulting photocatalyst were characterized by energy-dispersive X-ray (EDX) and X-ray diffraction pattern revealed nano-photocatalyst TiO2-P with the average size of 15–20 nm. EDX analysis showed the presence of phosphorus elements in the crystalline structure of TiO2 and diffuse reflectance spectroscopy showed the energy... 

This study aimed to evaluate and compare the performance of wastewater disinfection systems using ultraviolet radiation (UV) and ozonation to improve the secondary effluent quality of Isfahan North wastewater treatment plant. Therefore, the filtered effluent by a pretreatment unit from micro-screen drum filter type with a pore size of 20 µm entered the disinfection pilots containing medium pressure (MP) UV lamps and ozonation system as tertiary treatment. In this study, the irradiation dose of UV (430–3,680 mW/cm2), and injection dose (10–40 mg/L), and contact time (1–15 min) of ozonation were altered. The results showed that the total suspended solids were reduced by 61.27% at the maximum... 

In the present study, the ACF-TiO2 catalyst was synthesised and used as a catalyst for the destruction of toxic cyanide in both synthetic and real industrial wastewaters. The ACF-TiO2 catalyst was found to be micro-porous with the BET surface area of 163 m2/g. The effect of different operational parameters such as catalyst concentration, cyanide concentration, operation time, and ozone concentration were target parameters in the present study. The findings show that 500 mg/L of catalyst is the optimum value for the photocatalytical process to completely oxidise 25 mg/L of cyanide within 10 min. While it was found that 300 mg/L of catalyst in the presence of 200 mg/h ozone is enough to remove... 

Microbial desalination cell (MDC) is a new bio-electrochemical technique which converts chemical energy into electrical energy, and at the same time desalinates water and treats wastewater. In this study, MDC performance and water biofouling conditions were tested as an efficient pretreatment desalination process of reverse osmosis (RO). The experiments were designed in a three-chamber reactor to compare the performance of batch and continuous fed modes, using bio-cathode and synthetic wastewater in four different hydraulic retention times and 17 and 35 g/L NaCl concentrations. According to the results, maximum salt removal of about 52.3% was obtained in the continuously fed MDC at 35 g/L... 

In this study, magnetic nanoparticles (MNPs) modified with poly amidoamine (PAMAM) dendrimers - by adding methyl acrylate and ethylenediamine continuously till 10th generation- which further anchored to benzaldehyde ligand through polymeric bonding and studied as a novel method for synthesizing a nano sorbent for removing naphthalene (NAP) from aqueous environments. Synthesized nanopolymer was characterized by Fourier transform infrared spectroscopy (FTIR), Field-Emission Scanning Electron Microscopy (FE-SEM) equipped with EDS, X-ray Diffraction (XRD), Vibrating Sample Magnetometry (VSM), thermal gravimetric analysis (TGA). Based on the obtained analysis results synthesized average... 

The city of Tehran, the capital of Iran, has been facing severe air quality problems. The air quality of Tehran has been stated as unhealthy over one-third of year during the last two decades. According to the last emission inventory of Tehran for the base year of 2013 mobile sources contribute by about 6, 46, 98, 87, and 70% of total primary SOx, NOx, CO, VOC and PM emission. A number of policies have been implemented in Tehran during the last two decades to tackle the air quality issue. Concentrated mostly on transportation sector, these policies aimed to improve fuel quality and emission performance of vehicles. Nevertheless, there is no quantified evaluation regarding the effectiveness... 

Microbial contamination poses a serious threat to human health. The evaluation of alternative systems and their reliability for the treatment of water is essential. In this work, a new method for the deposit of more silver nanoparticles (AgNPs) on the external surface of Fe3O4 nanoparticles is presented. Fe3O4 nanoparticles were synthesised by chemical co-precipitation and were modified in two stages using 3-mercaptopropyl trimethoxysilane and grafting allyl glycidyl ether and N, N-dimethylacrylamide. Then, AgNPs were loaded onto the modified Fe3O4 to be used for water disinfection. The resulting nanoparticles were characterised by transmission electron microscopy, X-ray powder diffraction,... 

The network modeling approach is applied to provide a new insight into the onset of non-Darcy flow through porous media. The analytical solutions of one-dimensional Navier-Stokes equation in sinusoidal and conical converging/diverging throats are used to calculate the pressure drop/flow rate responses in the capillaries of the network. The analysis of flow in a single pore revealed that there are two different regions for the flow coefficient ratio as a function of the aspect ratio. It is found that the critical Reynolds number strongly depends on the pore geometrical properties including throat length, average aspect ratio, and average coordination number of the porous media, and an... 

Reaction thrusters (RTs) are used as an alternative to momentum exchange devices when disturbance torques exceed the control authority of momentum exchange devices. The reaction control system (RCS) can employ some rocket thrusters to provide attitude control during the thrusting or coast phase. Within the control loop, the RCS's target could be either achieving and keeping a certain attitude or controlling the rate of an attitude change. In the coast phase, some tasks such as preacceleration, settling of liquid propellant, damping of structural vibrations, providing a velocity increment to separate stages and payloads, and carrying out orbital and nonorbital maneuvers may be included in its... 

Nerve repositioning surgery is one of the treatments chosen for the patients with edentulous posterior atrophic mandible. Like any other treatments, this therapy has its advantages and disadvantages, indications and contraindications. The most important complication of this procedure is neurosensory disturbance. This problem may occur at different stages of the treatment. One common time when nerve damage happens is when the nerve is located outside the canal and drilling and insertion of the implant are performed. Accordingly, this report describes a simple and feasible method to retract and protect nerves outside the canal during the treatment of nerve transposition. This will reduce the... 

Nerve repositioning surgery is one of the treatments chosen for the patients with edentulous posterior atrophic mandible. Like any other treatments, this therapy has its advantages and disadvantages, indications and contraindications. The most important complication of this procedure is neurosensory disturbance. This problem may occur at different stages of the treatment. One common time when nerve damage happens is when the nerve is located outside the canal and drilling and insertion of the implant are performed. Accordingly, this report describes a simple and feasible method to retract and protect nerves outside the canal during the treatment of nerve transposition. This will reduce the... 

High molecular mass of naphthalene make it non-biodegradable and the biological methods for treated the pollutant are much time consuming. In this paper, two methods of ozonation and aeration are used to remove naphthalene. Because of the industrial wastewater has a great range of pH, in this study different concentrations of soluble naphthalene are placed in variable pH conditions, different contact times and changes in amount of aeration and ozonation. ANOVA results indicated a significant difference between two methods. The average removal of naphthalene by use of ozonation is 55 % and 37 % for aeration. As results, the best conditions that naphthalene are removed is in acidic environment... 

Methyl Tert-Butyl Ether (MTBE) is an oxygenated organic compound extensively substituted for lead in gasoline worldwide. MTBE can affect human and environment. In this research, biodegradation capability of MTBE by identified indigenous Bacillus cereus strain RJ1 was studied. Obtained results showed that biological removal of MTBE with 200 mg/L samples in 28°C is 27.5% while in 37°C within 120 days reaches to 34%. In addition, biodegradation of Bacillus cereus RJ1 in 500 mg/L and 1,000 mg/L is 28% and 23.9% in 28°C, respectively. Therefore, this bacterium could clean up MTBE from the environment  

A bacterial strain, FBHYA2, capable of degrading naphthalene, was isolated from the American Petroleum Institute (API) separator of the Tehran Oil Refinery Complex (TORC). Strain FBHYA2 was identified as Achromobacter sp. based on physiological and biochemical characteristics and also phylogenetic similarity of 16S rRNA gene sequence. The optimal growth conditions for strain FBHYA2 were pH 6.0, 30°C and 1.0% NaCl. Strain FBHYA2 can utilize naphthalene as the sole source of carbon and energy and was able to degrade naphthalene aerobically very fast, 48 h for 96% removal at 500 mg/L concentration. The physiological response of Achromobacter sp., FBHYA2 to several hydrophobic chemicals... 

There is a need to find cheaper and simpler techniques for rural water filtration system in developing countries. Using a filter made of blocks for the water treatment enables one to make vertical filters. It is expected that the amount of land utilized would decrease by more than 70 % if vertical filters were used. The operation and washing would be simpler than using horizontal sand filters as filters made of blocks would be used instead. The feasibility study focused on finding adequate materials, compositions and methods of making a block with enough resistance to water pressure, sufficient porosity for water transformation, and using inexpensive, readily available materials. A pilot... 

Excess pressure drop induced by inertial effects limits the applicability of Darcy's law for modeling of fluid flow through porous media at high velocities. It is expected such additional pressure drop is influenced by pore/morphology of porous media. This work concerns with fundamental understanding of how throat curvature affects intrinsic properties of porous media at non-Darcy flow conditions using network modeling. Conical, parabolic, hyperbolic, and sinusoidal capillary ducts with three types of imposed anisotropy are used to construct the network in a more realistic manner. Solutions of one dimensional Navier-Stokes equation for incompressible fluid flow through converging/diverging... 

Optimized methods for simultaneous removal of nitrate, nitrite and ammonium are important features of nutrient removal. Nitrogen removal efficiency in an intermittently aerated sequencing batch reactor (IA-SBR) with multiple filling events was studied. No external carbon source was added and three filling events were considered. Oxidationreduction potential (ORP) and pH curve at solids retention time (SRT) of 20 d were analyzed. Effects of three organic loading rates (OLR), 0.67, 1.0 and 1.5 kgCOD/m3d, and three nitrogen loading rates (NLR), 0.054, 0.1 and 0.15 kgN/m3d, on nitrogen removal were studied. Nitrate Apex in pH curve and Nitrate Knee in ORP profile indicated that the end of... 

It is not common to build a geomechanical model for depleted reservoirs as logging and coring are costly and time consuming in such reservoirs. On the other hand, in regular analysis of wellbore stability, the effect of time is completely ignored. As a result, with time there will be some errors in the evaluation of wellbore stability in depleted reservoirs. In order to determine the optimum wellbore trajectory during the reservoir life, it is necessary to have a model which can estimate the rock properties based on the first full logging suite and also consider the depletion effect. In this study, a novel model is proposed which combines a mechanical earth model, borehole circumferential...