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    Simulation of Heat & Momentum Balance of Vacuum Bottom Flow in Thermal Cracking Fired Heater

    , M.Sc. Thesis Sharif University of Technology Naser Shariat, Mohadese (Author) ; Farhadi, Fathollah (Supervisor)
    Abstract
    The delayed coking process is one of the common thermal process technique that used to improve the quality of heavy oil. In this process, heavy feeds such as vacuum residues have been heated in the furnace to temperatures up to the 480-500 °C. For the cracking reactions the heated feed have been sent to the drum that is placed after the furnace. Since the reactions begin inside the furnace and coke is one of the products, deposited on the wall of the tube. With the deposition of coke on the tube wall and the reduction of heat transfer, the temperature of the tube have been increased with the increasing of the flame temperature to save constant heat flux. Therefore, the study of thermal... 

    Experimental Study of ASP Flooding in Shaly Heavy Oil Reservoirs Using Five-Spot Micromodels

    , M.Sc. Thesis Sharif University of Technology Mehranfar, Amin (Author) ; Rashtchian, Davood (Supervisor) ; Masihi, Mohsen (Supervisor) ; Ghazanfari, Mohammad Hossein (Supervisor)
    Abstract
    Heavy oil reservoirs include a major part of the world’s oil reservoirs. Therefore consideration to their enhanced oil recovery (EOR) aspects has a great importance. In heavy oil reservoirs secondary and tertiary EOR methods, have an insignificant effect on oil recovery and so we’d better to use chemical methods to improve mobility and oil recovery. One of the appropriate EOR methods which has attracted a lot of attention is alkaline – surfactant – polymer (ASP) flooding which has a considerable impact on EOR from heavy oil reservoirs. In this EOR method, the low concentration of surfactant in the injecting fluid, results in a low or ultra-low interfacial tension (IFT) between residual oil... 

    Screening of the EOR Scenarios for Shaly Heavy Oil Reservoirs Using Five-Spot Glass Micromodel: an Experimental Study

    , M.Sc. Thesis Sharif University of Technology Mohammadi, Saber (Author) ; Masihi, Mohsen (Supervisor) ; Ghazanfari, Mohammad Hossein (Supervisor) ; Kharrat, Riyaz (Supervisor)
    Abstract
    Most of the heavy oil reservoirs contain discontinuous shaly structures which affect fluid flow through porous media as well as oil recovery efficiency during EOR processes. However, selecting the best EOR technique which maximizes the oil recovery remains a topic of debate in the literature. In addition the effect of shale geometrical characteristics including: spacing from wells, discontinuity, orientation, number of shale streaks, shale's spacing and length on oil recovery factor are not well understood. In this work experiments have been performed on one-quarter five-spot glass micromodels. These models have been developed by a new method using laser technology. Generally, this research... 

    Experimental Investigation of Carbonated Water Alternating Nitrogen Gas Injection to Enhance Heavy Oil Recovery From Carbonated Rock Reservoir

    , M.Sc. Thesis Sharif University of Technology Majidi, Mohammad Javad (Author) ; Ghazanfari, Mohammad Hossein (Supervisor) ; Taghikhani, Vahid (Co-Advisor) ; Badakhshan, Amir (Co-Advisor)
    Abstract
    By continuous decreasing the fossil fuel energy resources and increasing demand of such energies on the other hand with decreasing exploration of the new ones, production from these limited resources are in grate consideration. As a few percentages of the oil recovers by primary oil production and also remaining a lot of oil after water and gas injection in the secondary oil recovery process, causes that new methods to increase the oil recovery has been proposed. Water injection is a simple and common method in enhanced oil recovery process. Also water alternating gas injection and simultaneous water and gas injection causes considerable increase in oil recovery. Recently utilization of... 

    Kinetic Modeling of Slurry Phase Residue Hydroconversion

    , M.Sc. Thesis Sharif University of Technology Ghane, Asieh (Author) ; Khorashe, Farhad (Supervisor) ; Kazemeini, Mohammad (Supervisor)
    Abstract
    Existing processes to improve the quality of heavy oil cuts catalytic converter hydroconversion can be mentioned in the slurry phase. This process is usually done in the temperature 440˚C to 470˚C be a heavy craking led to the production of light weight thermal feed can be more. With more products light, adverse reaction can also lead to the formation of coke be. Coke formation of secondary radical reactions can be feed from cracking of heavy compounds. Coke production is to eliminate or limit the ability of homogeneous catalysts (eg sulfide Molybdium) about 600-1000 ppm disposable food adds to be used. The main role of catalyst in the stable radicals fail thermal compound feed is heavy. The... 

    Experimental Investigation of Polymer Flooding for more Heavy Oil Recovery; Comparing to the Thermal EOR Method

    , M.Sc. Thesis Sharif University of Technology Ashoorian, Sefatallah (Author) ; Ayatollahi, Sahab (Supervisor) ; Masihi, Mohsen (Supervisor)
    Abstract
    Heavy oil reservoirs are becoming more important as the oil price increase and more light oil reservoirs are being depleted. Thermal oil recovery, especially steam flooding is considered as the most efficient EOR technique for heavy oil reservoirs that stays on the top of the recent EOR field experiences. However this method is not applicable in some reservoir conditions like deep reservoirs or reservoirs with thin pay zones.
    Due to sever viscous fingering during water flooding heavy oil reservoirs, a large amount of oil would remain untouched in the reservoir. Polymer flooding could be a potential method for enhanced oil recovery by improving sweep efficiency. However there haven’t been... 

    Experimental Investigation of the Role of Fracture Geometrical Characteristics and Injection Scenarios on Heavy Oil Recovery during Hydrocarbon Solvent Flooding

    , M.Sc. Thesis Sharif University of Technology Saidian, Milad (Author) ; Masihi, Mohsen (Supervisor) ; Ghazanfari, Mohammad Hossein (Supervisor) ; Kharrat, Riyaz ($item.subfieldsMap.e)
    Abstract
    Due to the importance of enhanced oil recovery of heavy oil fractured reservoirs, in this work micromodel setup has been used to study the miscible solvent injection in five-spot fractured reservoirs with different fracture geometrical characteristics. Due to the visual nature and flexibility of the micromodel patterns it is a subject of interest to be used in different studies. Different patterns has been constructed by chemical etching and controlled laser etching and saturated with displaced fluid and flooded by constant rate injection of hydrocarbon solvent in abient temperature and pressure. At first, effect of fracture’s length, numbering, orientation, discontinuity and scattering on... 

    Semi-Analytical Modeling And Simulation Of Heavy Oil Recovery Through VAPEX Process

    , M.Sc. Thesis Sharif University of Technology Rasti, Fariba (Author) ; Masihi, Mohsen (Supervisor) ; Kharrat, Riyaz (Supervisor)
    Abstract
    VAPEX is a relatively new EOR process for the recovery of heavy oil. In this process solvent is used to form a vapor chamber within a reservoir. Vapor dissolves in the oil and diluted oil drains by gravity to a horizontal production well. The essential features of this recovery mechanism have been discussed in this study. Furthermore, a semi-analytical and a simulation study of VAPEX process have been performed on a specified Iranian heavy oil reservoir (such as Kuh-e-Mond). The aim of this study is to investigate an exponential functionality (correlation) witch incorporates all physical parameters that affect the production rate of VAPEX process in dimensionless form. The adjustable... 

    Experimental and Theoretical Investigation of Heavy Oil Recovery Using Chemical Flooding; Mechanistically Study

    , Ph.D. Dissertation Sharif University of Technology Dehghan, Ali Akbar (Author) ; Masihi, Mohsan (Supervisor) ; Ayatollahi, Shahaboddin (Supervisor)
    Abstract
    Chemical flooding has great potential to recover significant fractions of remaining oil for medium to heavy oil reservoirs not applicable for thermal recovery techniques. Nowadays, with gradual crude oil price increase the chemical process is receiving renewed attention, however, illustration of the possibility of various chemical injection scenarios for medium to heavy oil reservoirs has not been clearly reported and these kinds of reservoirs require more investigation for the applicability of these techniques in the fields. The interfacial active molecules are responsible for providing low IFT range and water/oil emulsions which in many cases could improve the oil displacement efficiency.... 

    Adsorption and Conversion of Heavy Oil Asphaltene on Composite Nanostructures

    , M.Sc. Thesis Sharif University of Technology Torka Bidokhti, Mostafa (Author) ; Ghotbi, Siros (Supervisor) ; Khodadadi, Abbasali (Supervisor)
    Abstract
    The aim of this project was to upgrade and reduce viscosity of heavy oils by adsorbing of asphaltene on Ni-Mo/CB and converting it into lighter and more valuable gas and liquid compounds. Asphaltene has been extracted from a heavy crude oil sample of Soroush oil field in Iran. After adsorption, Asphaltene conversion to lighter components (gas/liquid) was studied through hydrocracking process. To prepare the support of catalyst, Carbon Black, initially a thermal treatment step under the argon gas atmosphere followed by acid-washing process was performed. Afterward, the catalysts was prepared through dry impregnation method. In order to activate catalyst for hydrocracking, the catalysts has... 

    Characterization and Modeling of Heavy Oil Fields Using Artificial Neural Networks to Optimize Horizontal Wells Selection

    , Ph.D. Dissertation Sharif University of Technology Al Ali, Najeh (Author) ; Pishvaie, Mahmoud Reza (Supervisor) ; Taghi Khani, Vahid (Supervisor) ; Buzorgmehri, Ramin (Co-Advisor)
    Abstract
    Steam-Assisted Gravity Drainage (SAGD) is one of the best and the most effective methods of enhanced oil recovery (EOR) which is used in the production from Heavy Oil Reservoirs which constitute large amount of oil throughout the globe. In a typical process of SAGD, steam is injected into a horizontal well and the oil is produced several meters deeper in the ground. In order to increase the Recovery of this process, it is better to review on the Pre-heating methods around the injecting and producing wells. Pre-heating is important when the viscosity of the oil is large enough to prevent oil from any motion at the beginning of the SADG operation, and makes it necessary to to use a Pre-heating... 

    Experimental Investigation of Heavy Oil Recovery by Liquid CO2 Huff and Puff Method

    , M.Sc. Thesis Sharif University of Technology Ekhlasjoo, Iman (Author) ; Vossoughi, Manoochehr (Supervisor) ; Shadizadeh, Reza (Supervisor) ; Kharrat, Reeaz (Supervisor) ; Ghazanfari, Mohammad Hossein (Co-Advisor)
    Abstract
    In recent years, carbon dioxide is used for enhanced oil recovery of heavy oil. Steam Huff and Puff is one of the enhanced oil recovery methods used for heavy oil. In this study liquid CO2 was used as an injecting fluid instead of steam. In this paper a series of experiments were performed to demonstrate the effect of carbon dioxide injection pressure on huff and puff process. The experimental data are used in lab scale model simulated with commercial simulator Eclipse 300 to investigate the effect of soaking time, injection pore volume and rate of injection on the heavy oil recovery. Result of experiments showed that huff and puff process under miscible pressure condition gives the most... 

    The determination of effective diffusivity coefficients in a solvent gas heavy oil system for methane

    , Article Petroleum Science and Technology ; Volume 30, Issue 24 , 2012 , Pages 2582-2593 ; 10916466 (ISSN) Zamanian, E ; Dadvar, M ; Kharrat, R ; Ghazanfari, M. H ; Sharif University of Technology
    2012
    Abstract
    In this investigation, an accurate high pressure and temperature diffusion setup was applied to measure the diffusion coefficients of methane in Iranian heavy oils in presence and absence of porous media by using the pressure-decay method. The solvent diffusivity in heavy oil was determined by both graphical and numerical methods. In addition, the effects of the porous medium and the temperature on the molecular diffusion coefficient of the solvent gas in the liquid phase were discussed and finally, using experimental data, a functionality dependence of molecular diffusivity on temperature and porous medium characteristics was proposed  

    A new empirical correlation for predicting effective molecular diffusivity of gas-heavy oil-porous media systems

    , Article Special Topics and Reviews in Porous Media ; Volume 3, Issue 1 , 2012 , Pages 23-33 ; 21514798 (ISSN) Zamanian, E ; Mirjordavi, N ; Kazemeini, M ; Ghazanfari, M. H ; Sharif University of Technology
    2012
    Abstract
    Molecular diffusivity is an essential parameter for modeling of mass transfer in enhanced oil recovery processes. However, experimentally determined diffusivities for light gas-heavy oil systems in the presence of porous media are relatively rare. A few correlations are available in the literature that predict diffusivity of gases into heavy oil in presence of porous media. In this work the pressure-decay method was applied to obtain effective molecular diffusion of CO 2, CH 4 and N 2-heavy oil systems in both bulk and porous media systems at different temperatures. The diffusivity of gases in heavy oil was determined by matching the numerically calculated pressures to the measured data. A... 

    Prediction of asphaltene precipitation during solvent/CO2 injection conditions: A comparative study on thermodynamic micellization model with a different characterization approach and solid model

    , Article Journal of Canadian Petroleum Technology ; Vol. 50, issue. 3 , March , 2011 , p. 65-74 Tavakkoli, M ; Masihi, M ; Ghazanfari, M. H ; Kharrat, R ; Sharif University of Technology
    Abstract
    There are different thermodynamic models that have been applied for modelling of asphaltene precipitation caused by various reasons, such as solvent/CO2 injection and pressure depletion. In this work, two computer codes based on two different asphaltene precipitation thermodynamic models-the first being the thermodynamic micellization model with a different characterization approach and the second being the solid model-have been developed and used for predicting asphaltene precipitation data reported in the literature as well as in the obtained data for Sarvak reservoir crude, which is one of the most potentially problematic Iranian heavy oil reserves under gas injection conditions. For the... 

    Prediction of asphaltene precipitation during pressure depletion and CO2 injection for heavy crude

    , Article Petroleum Science and Technology ; Vol. 28, issue. 9 , Mar , 2009 , p. 892-902 ; ISSN: 10916466 Tavakkoli, M ; Kharrat, R ; Masihi, M ; Ghazanfari, M. , H ; Sharif University of Technology
    Abstract
    In this work, a thermodynamic approach is used for modeling the phase behavior of asphaltene precipitation. The precipitated asphaltene phase is represented by an improved solid model, and the oil and gas phases are modeled with an equation of state. The Peng-Robinson equation of state (PR-EOS) was used to perform flash calculations. Then, the onset point and the amount of precipitated asphaltene were predicted. A computer code based on the solid model was developed and used for predicting asphaltene precipitation data reported in the literature as well as the experimental data obtained from high-pressure, high-temperature asphaltene precipitation experiments performed on Sarvak reservoir... 

    Understanding the polydisperse behavior of asphaltenes during precipitation

    , Article Fuel ; Vol. 117, issue. PART A , 2014 , pp. 206-217 Tavakkoli, M ; Panuganti, S. R ; Taghikhani, V ; Pishvaie, M. R ; Chapman, W. G ; Sharif University of Technology
    Abstract
    Asphaltenes are a polydisperse fraction of the crude oil, the phase behavior of which is significantly affected by the changes in pressure, temperature and composition. The focus of this study is to model the polydisperse asphaltenes' precipitation onset condition and the amount of precipitate from solvent-diluted crude oils using the Perturbed Chain form of the Statistical Associating Fluid Theory (PC-SAFT) over a wide range of crude oil density. Heavy oil and bitumen production can involve diluting with paraffinic solvents. Different fractions of the polydisperse asphaltenes thus precipitated are predicted and when compared to the experimental data show a remarkable matching for different... 

    Prediction of asphaltene precipitation during solvent/CO2 injection conditions: A comparative study on thermodynamic micellization model with a different characterization approach and solid model

    , Article Journal of Canadian Petroleum Technology ; Volume 50, Issue 3 , 2011 , Pages 65-74 ; 00219487 (ISSN) Tavakkoli, M ; Masihi, M ; Ghazanfari, M. H ; Kharrat, R ; Sharif University of Technology
    Abstract
    There are different thermodynamic models that have been applied for modelling of asphaltene precipitation caused by various reasons, such as solvent/CO2 injection and pressure depletion. In this work, two computer codes based on two different asphaltene precipitation thermodynamic models-the first being the thermodynamic micellization model with a different characterization approach and the second being the solid model-have been developed and used for predicting asphaltene precipitation data reported in the literature as well as in the obtained data for Sarvak reservoir crude, which is one of the most potentially problematic Iranian heavy oil reserves under gas injection conditions. For the... 

    Prediction of asphaltene precipitation during pressure depletion and CO2 injection for heavy crude

    , Article Petroleum Science and Technology ; Volume 28, Issue 9 , Apr , 2010 , Pages 892-902 ; 10916466 (ISSN) Tavakkoli, M ; Kharrat, R ; Masihi, M ; Ghazanfari, M. H ; Sharif University of Technology
    2010
    Abstract
    In this work, a thermodynamic approach is used for modeling the phase behavior of asphaltene precipitation. The precipitated asphaltene phase is represented by an improved solid model, and the oil and gas phases are modeled with an equation of state. The Peng-Robinson equation of state (PR-EOS) was used to perform flash calculations. Then, the onset point and the amount of precipitated asphaltene were predicted. A computer code based on the solid model was developed and used for predicting asphaltene precipitation data reported in the literature as well as the experimental data obtained from high-pressure, high-temperature asphaltene precipitation experiments performed on Sarvak reservoir... 

    Phase behavior assessment of deposition compound (asphaltene) in heavy oil

    , Article 11th ADIPEC: Abu Dhabi International Petroleum Exhibition and Conference, Abu Dhabi, 10 October 2004 through 13 October 2004 ; 2004 , Pages 783-799 Tabibi, M ; Nikookar, M ; Ganbarnezhad, R ; Pazuki, G. R ; Hosienbeigi, H. R ; Sharif University of Technology
    Society of Petroleum Engineers (SPE)  2004
    Abstract
    In this paper, the soave-Redlich-Kwong (SRK) Eos is modified based on perturbation theory. The parameter of the new cubic equation of state considered reduced temperature and a centric factor dependent. The average of absolute deviations of predicted vapor pressure, vapor volume and saturated liquid density of 30 pure compounds are 0.814.2.G14 and 5.814%, respectively. Also comparison with the new equation of vaporization of pure compounds are given. The florry-Hugines (FH) model is similarly modified by an adjustable parameter. This parameter is defined based on molecular weight of asphaltene to molecular weight of heavy oil ratio in form of polynomial function. The phase behavior of...