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    Production of Uranium Dioxide Nano Powder With Hydrothermal Method in Supercritical Water Reactor

    , M.Sc. Thesis Sharif University of Technology Golzary, Abooali (Author) ; Outokesh, Mohammad (Supervisor) ; Ahmadi, Javad (Supervisor) ; Karimi Sabet, Javad (Co-Advisor)
    Abstract
    Hydrothermal supercritical method is one of the most suitable methods for metal oxide nano powder, ceramics and mineral catalyst synthesis. Metal oxides nanopowder in its pure or mixed form has wide potential application as chemical industrial catalyst, hot Superconductors, magnetic material, gas sensors and car catalyst convertors. One of the most important metal oxides aspects of application is uranium oxide as nuclear reactor fuel is used. In addition, UO2 is selective catalyst for converting methane to methanol process and Decomposition of organic Chlorine material. In Supercritical hydrothermal method done in high pressure reactor with critical to fluid, is new method for the... 

    Design of a High Pressure Centrifugal Compressor Impeller of an Aviation Turboshaft Engine

    , M.Sc. Thesis Sharif University of Technology Sadr, Motahareh (Author) ; Ghorbanian, Kaveh (Supervisor)
    Abstract
    The purpose of this study is developing the design means of a high pressure centrifugal compressor impeller for aviational applications i.e. turboshaft engines. The logic and constraints of designing a high pressure centrifugal impeller for a turboshaft engine is different from those of low pressure aerial or high speed industrial ones. This kind of impeller is deployed in a number of advanced generation of aero engines. In this study, the centrifugal impeller design tools are developed using two design methods. Then, the results are compared, validated and corrected with an existing high pressure impeller data. A number of impellers with pressure ratios ranging from 6 to 11 are designed and... 

    Integrated Geomechanical Modeling of Casing Failure; From Lab to Simulation

    , Ph.D. Dissertation Sharif University of Technology Taheri, Reza (Author) ; Pak, Ali (Supervisor) ; Shad, Saeed (Co-Supervisor)
    Abstract
    Casing failure is one of the mainly problems of hydrocarbon fields that may cause wells out of service and impose heavy costs on oil companies. There exist many theories that may cause casing failure including: the plastic behavior of surrounding formations, the effects of reservoir depletion, over-pressured formations, weak cementing operations, fault activation, and local stresses applied on casing. In salt-rich formations, creep behavior can be the main cause of casing failure, too.The purpose of this study is to evaluate the causes affecting casing failure via experimental studies and numerical simulation with the focus on the conditions governing south-west Iranian oil fields, where the... 

    Analysis of Premium Connections of Oil Well Equipment Under Very High Pressure Conditions

    , M.Sc. Thesis Sharif University of Technology (Author) ; Arghavani Hadi, Jamal (Supervisor)
    Abstract
    Thread connections are widely used in tubular downhole equipment. Connections are usually weaker than tubulars and their failure will result in very high cost. Thread connections of downhole equipment are divided into two groups: standard connections and premium connections. Standard connections, despite being widely used, have limitations and will loose their efficiency in complex loadings. According to the mentioned limitations, premium connections have been proposed according to the existing need related to improving the strength of the structure, proper sealing and resistance to galling. One of the most obvious applications of premium connections is in downhole tubulars that are... 

    Numerical Study of Gas Release, Diffusion and Explosion in the High Pressure Gas Pipeline

    , Ph.D. Dissertation Sharif University of Technology Adibi, Omid (Author) ; Farhanieh, Bijan (Supervisor) ; Afshin, Hossein (Co-Supervisor)
    Abstract
    With the advent and development of modern technologies, the need for energy in industrial societies has been dramatically increased. Currently, natural gas is considered as one of the most important energy sources in the world. High pressure transmission lines are widely used to transfer natural gas from wells and natural resources to industrial centers. High costs, limited results, and the potential risks of empirical experiments along with further need for problem simplification in analytical studies have led numerical methods to become the most practical tools for researchers in the safety field of high pressure gas transmission lines. Numerical simulations of explosive events require a... 

    Effect of Iron Ore Concentrate Morphology on Pellet Quality of Gol-e-Gohar Concentrate

    , Ph.D. Dissertation Sharif University of Technology Abazarpoor, Armin (Author) ; Halali, Mohammad (Supervisor)
    Abstract
    In this study, the effect of iron ore concentrate morphology on green pellet quality was studied. In order to produce concentrate with different morphology using ball mill, ball charge (20-40 %V), grinding time (30-50 min) and ball distribution (15 mm, 23 mm, 15+23 mm) was varied. It was deduced that increasing grinding time and ball charge would result in reduction of D80 but would increase Blaine number. The interaction parameters of ball distribution-grinding time and ball distribution-ball charge had significant effect on Blaine and D80. It was also observed that mixed level of ball distribution would lead to higher Blaine numbers. The equation obtained by CCD was verified by the... 

    Experimental Investigation of the Effect of Pressure and Gas Composition on the Interfacial Behavior of Gas/Oil System under High Pressure High Temperature Conditions

    , M.Sc. Thesis Sharif University of Technology Meghrazi, Emad (Author) ; Fatemi, Mobeen (Supervisor) ; Ghazanfari, Mohammad Hossein (Co-Supervisor)
    Abstract
    Gas injection process is one of the main methods to increase the hydrocarbon reservoirs. Minimum Miscibility pressure is a key parameter that controls the efficiency of the gas injection process. It depends on the temperature, the composition of the injected gas and the composition of the reservoir fluids. In this study, the interfacial tension of the live oil-gas system of one of the reservoirs of southwestern Iran was obtained by analyzing the Pendant drop method at 225 ° F and different pressures, and then by using the Vanishing Interfacial Tension method, the Minimum Miscibility Pressure has been computed .In this study, pure and base gases such as nitrogen, methane and injection gas of... 

    Wettability Alteration of Reservoir Rocks to Super Gas-Wet Condition Using Nanocomposite by Applying Contact Angle Measurement for Gas-Crude Oil System

    , M.Sc. Thesis Sharif University of Technology Zandi, Ahmad (Author) ; Ghazanfari, Mohammad Hossien (Supervisor) ; Fatemi, Mobeen (Supervisor) ; Esmaeilzadeh, Pouriya (Co-Supervisor)
    Abstract
    Today, increasing the productivity of reservoirs is more important than in the past, while the use of nanoparticles to change the wettability of rock and increase the recovery factor from the reservoir has been considered by many researchers. Despite previous studies on the use of nanoparticles to change the wettability of rock to gas-wet, the use of nanocomposites with super gas-wet at high temperature and pressure in the crude oil-gas system has rarely been considered. In this research, several nanocomposites with different structures have been synthesized in the laboratory and nanofluids with different formulations have been used to coat the rock thin sections and measure droplet contact... 

    Study of Physical and Chemical Properties of Suitable Rubber Compound in Acidic Media with High Temperatures and High Pressure

    , M.Sc. Thesis Sharif University of Technology Mahmoudi, Saeed (Author) ; Musavi, Abbas (Supervisor) ; Shojaei, Akbar (Supervisor)
    Abstract
    In This thesis the properties of a compatible rubber compound for a specific chemical environment (acidic media) with high temperature and high pressure (HTHP) is studied. After primary studies, six formulations are designed on the basis of Nitrile rubber. after tensile and hardness tests at ambient temperature and 120 °C, samples putted in aging reservoir for aging tests. After that, tensile and hardness tests were performed again. Finally, by analyzing the results, the best formulation have chosen. Test results show that the NBR / PVC compound with higher filler load, has the best chemical resistance  

    Improving Temperature Stability of Drilling Fluids Polymers Using Nano Particles

    , M.Sc. Thesis Sharif University of Technology Halali, Mohamad Amin (Author) ; Ghotbi, Siroos (Supervisor)
    Abstract
    Water base drilling fluids are the most common drilling fluids in oil and gas operations and biopolymers are the requisite additives used in such kind of fluids frequently. Unfortunately, at harsh conditions of HPHT the polymers undergo thermal degradation which cause serious loss in fluid rheological and filtration properties. Accordingly, this will induce operational pitfalls and tremendous cost. The power of economy along with environmental regulations force us to search for reasonable chemically benign additives to fulfill this need. Nanoparticles are the most promising additives proposed in this study to address this challenge. Regarding their unique exclusive properties, they are able... 

    Optimization of Dynamic Performance of Gas Transmission Networks

    , Ph.D. Dissertation Sharif University of Technology Ahmadian Behrooz, Hesam (Author) ; Bozorgmehry, Ramin (Supervisor)
    Abstract
    In this work, a non-isothermal model of natural gas in pipelines including mass, momentum and energy balance equations are used as model equations for modeling and state estimation in gas pipeline systems. An algorithm is proposed to handle the discontinuities that appear in the dynamic model of a GTN. The states of GTN are estimated using the continuous/discrete form of the extended Kalman filter for two benchmarks and some heuristic rules for sensor placement in a GTN are concluded. Also, a framework for distributed and decentralized state estimation in high-pressure and long-distance gas transmission networks (GTNs) is proposed. Some heuristic rules are suggested for system decomposition... 

    Theoretical and Experimental Study of Gas-Solid Fluidized Beds Dpm Approach

    , M.Sc. Thesis Sharif University of Technology Banaei, Mohammad (Author) ; Molaei Dehkordi, Asghar (Supervisor)
    Abstract
    Because of the importance of gas-solid fluidized beds in industrial plants, many efforts have been done for predicting their behavior up to now. Generally, there are two major attitudes for describing and simulating the hydrodynamics of fluidized beds, Eulerian-Eulerian methods and Eulerian-Lagrangian metods. Both of these approaches have their own advantages and disadvantages and a lot of studies have been done to understand the nature of gas-solid fluidized beds with aid of these models. Due to fewer presumptions in the basic structure of Eulerian-Lagrangian methods such as DEM in comparison with Eulerian-Eulerian methods like TFM, these models can predict the hydrodynamics of fluidized... 

    Experimental and modelling investigations of asphaltene precipitation during pressure depletion and gas injection operations

    , Article Petroleum Science and Technology ; Vol. 32, issue. 15 , August , 2014 , pp. 1868-1875 ; ISSN: 10916466 Nakhli, H ; Alizadeh, A ; Afshari, S ; Kharrat, R ; Ghazanfari, M ; Sharif University of Technology
    Abstract
    Asphaltene precipitation problems manifest themselves in different stages of oil reservoirs production. Experimental and modeling investigations are, therefore, employed as promising tools to assist in predictions of asphaltene precipitation problems and selection of proper production facilities. This study concerns experimental and modeling investigations of asphaltene precipitation during natural production and gas injection operations for a heavy Iranian crude oil at reservoir conditions. First, with design and performance of high pressure-high temperature experiments, asphaltene precipitation behavior is comprehensively investigated; the effects of pressure and temperature are fully... 

    Investigating the possibility of Sonofusion in Deuterated acetone

    , Article International Journal of Hydrogen Energy ; Vol. 39, issue. 21 , July , 2014 , pp. 11328-11335 ; ISSN: 03603199 Zoghi-Foumani, N ; Sadighi-Bonabi, R ; Sharif University of Technology
    Abstract
    In this article, energetic implosion of a single vapor bubble induced by a standing acoustic wave is theoretically studied and the Sonoluminescing bubble parameters involved in Sonofusion in Deuterated acetone (C3D 6O) are investigated. Parameters such as radius, wall velocity, interior temperature and pressure of the bubble influenced by various driving pressure amplitudes in Deuterated acetone at ∼0 °C are investigated. Based on the obtained results, the possibility of thermonuclear fusion inside imploding cavitation bubbles is discussed. The interior pressure of C 3D6O vapor bubbles at the collapse time is extremely high and the increase of the pressure amplitude increases the pressure... 

    Miniaturized salting-out liquid-liquid extraction in a coupled-syringe system combined with HPLC-UV for extraction and determination of sulfanilamide

    , Article Talanta ; Vol. 121 , April , 2014 , pp. 199-204 ; ISSN: 00399140 Sereshti, H ; Khosraviani, M ; Sadegh Amini-Fazl, M ; Sharif University of Technology
    Abstract
    In salting-out liquid-liquid extraction (SALLE) technique, water-miscible organic solvents are used for extraction of polar analytes from saline solutions. In this study, for the first time, a coupled 1-mL syringes system was utilized to perform a miniaturized SALLE method. Sulfanilamide antibiotic was extracted and determined via the developed method followed by high performance liquid chromatography-ultraviolet detection (HPLC-UV). The extraction process was carried out by rapid shooting of acetonitrile as extraction solvent (syringe B) into saline aqueous sample solution (syringe A), and then the shooting was repeated several times at a rate of 1 cycle s-1. Thereby, an extremely large... 

    Precipitated asphaltene amount at high-pressure and high-temperature conditions

    , Article Energy and Fuels ; Vol. 28, Issue. 3 , 2014 , pp. 1596-1610 ; ISSN: 08870624 Tavakkoli, M ; Panuganti, S. R ; Taghikhani, V ; Pishvaie, M. R ; Chapman, W. G ; Sharif University of Technology
    Abstract
    In the upstream asphaltene flow assurance community, both academics and industries are actively involved to predict the asphaltene deposit profile in wellbores and pipelines. Essential information for such a study is the amount of asphaltenes that can precipitate and, hence, deposit. In this work, the perturbed chain form of the statistical associating fluid theory (PC-SAFT) is applied to predict the asphaltene precipitation onset condition as well as the amount of precipitate under pressure depletion and high-pressure and high-temperature gas injection conditions. Previous PC-SAFT asphaltene studies in crude oil required the compositional data for both flashed gas and flashed liquid. This... 

    High pressure effects on electronic and magnetic properties of LaOFeAs superconductor

    , Article Journal of Superconductivity and Novel Magnetism ; Vol. 27, issue. 7 , 2014 , p. 1689-1692 Khosroabadi, H ; Sandoghchi, M ; Akhavan, M ; Sharif University of Technology
    Abstract
    The effect of pressure has been studied on structural and electronic properties of LaOFeAs high-T c superconductor by ab initio density functional theory by using pseudopotential Quantum Espresso code. The lattice parameters and ionic positions in the ambient pressure and some high pressure up to 20 GPa have been calculated. The obtained data versus the simple scaling relation for the ionic positions and distances for mechanical pressures have been discussed. The results of band structure and magnetic moment calculations of this compound versus the applied pressure are presented in this paper. The results are compared with the other experimental and computational data in the literature  

    Investigation of segregation of large particles in a pressurized fluidized bed with a high velocity gas: A discrete particle simulation

    , Article Powder Technology ; Volume 246 , September , 2013 , Pages 398-412 ; 00325910 (ISSN) Alavi Shoushtari, N ; Hosseini, S. A ; Soleimani, R ; Sharif University of Technology
    2013
    Abstract
    A numerical study on mixing/segregation phenomena in a pressurized fluidized bed with large particles of Geldart D type of binary density but same diameter with high velocity gas was performed by the use of discrete particle simulation. Particle mixtures are composed of spherical particles with 2mm diameter and 1g/cm3 flotsam density and different jetsam densities of 1.25, 2 and 2.5g/cm3 with jetsam volume fraction of 0.5. The particles are initially packed approaching perfect mixing state in a rectangular bed and then fluidized by gas uniformly injected at the bottom of the bed. Effect of increase of pressure and density ratio was investigated and mixing/segregation behavior is discussed in... 

    Molecularly imprinted polydopamine nano-layer on the pore surface of porous particles for protein capture in HPLC column

    , Article Journal of Colloid and Interface Science ; Volume 404 , 2013 , Pages 117-126 ; 00219797 (ISSN) Nematollahzadeh, A ; Shojaei, A ; Abdekhodaie, M. J ; Sellergren, B ; Sharif University of Technology
    2013
    Abstract
    Bio-inspired Human Serum Albumin (HSA) imprinted polydopamine nano-layer was produced through oxidative polymerization of dopamine on the pore surface of HSA modified porous silica particles. The coating thickness was controlled by the reaction time and thereby varied within 0-12. nm. The samples were characterized by elemental analysis, FT-IR, DSC, SEM, TEM, TGA, physisorption and thermoporometry. The characterization confirmed the success of evolution and deposition of polydopamine layer on the silica pore surface. Batch rebinding experiment showed that the molecularly imprinted polymer (MIP) with 8.7. nm coating thickness, in comparison with the thinner and thicker coatings, displays the... 

    Investigating the effects of temperature, pressure, and paraffin groups on the N2 miscibility in hydrocarbon liquids using the interfacial tension measurement method

    , Article Industrial and Engineering Chemistry Research ; Volume 52, Issue 29 , 2013 , Pages 9851-9857 ; 08885885 (ISSN) Zolghadr, A ; Riazi, M ; Escrochi, M ; Ayatollahi, S ; Sharif University of Technology
    2013
    Abstract
    In this study, interfacial tension measurement (IFT) is utilized to assess the impact of temperature, pressure, and paraffin type on a nitrogen injection process as an efficient enhanced oil recovery method. The pure and equilibrium densities of oil in contact with nitrogen are examined to find IFT behavior and gas solubility in oil. The minimum miscible pressure (MMP) of different systems has been measured using the vanishing interfacial tension technique. The experimental results show that IFT decreases linearly with pressure, with two different slopes. The results indicate that IFT values decrease linearly with temperature at different pressure conditions. The obtained IFT values for...