Sharif Digital Repository

Thermodynamic modeling is known as a promising tool for phase behavior modeling of asphaltene precipitation under different conditions such as pressure depletion and CO2 injection. In this work, a thermodynamic approach is used for modeling the phase behavior of asphaltene precipitation. The precipitated asphaltene phase is represented by an improved solid model, while the oil and gas phases are modeled with an equation of state. The PR-EOS was used to perform flash calculations. Then, the onset point and the amount of precipitated asphaltene were predicted. A computer code based on an improved solid model has been developed and used for predicting asphaltene precipitation data for one of... 

There are different thermodynamic models that have been applied for modelling of asphaltene precipitation caused by various reasons, such as solvent/CO2 injection and pressure depletion. In this work, two computer codes based on two different asphaltene precipitation thermodynamic models-the first being the thermodynamic micellization model with a different characterization approach and the second being the solid model-have been developed and used for predicting asphaltene precipitation data reported in the literature as well as in the obtained data for Sarvak reservoir crude, which is one of the most potentially problematic Iranian heavy oil reserves under gas injection conditions. For the... 

Almost all of the heavy oil reservoirs contain discontinuous permeability barriers (shales) with different structures. However, the effect of shaly layer geometrical characteristics including: spacing from wells, discontinuity, orientation, shaly layers' spacing and length, and heterogeneous distribution on oil recovery factor in the presence of gravity force are not well understood. In this work, a series of solvent injection experiments were conducted on various vertical one-quarter five-spot glass micromodels, containing barriers, which were initially saturated with a heavy oil sample. The oil recovery was measured by analysis of the pictures provided continuously during the injection... 

Steam-assisted gravity drainage is one of the most promising strategies to develop huge heavy oil and bitumen accumulations. Like the other thermal processes, this method aims at reducing oil viscosity by increasing the temperature. But in an economical point of view, it requires a great volume of steam for injection. Moreover, early breakthrough of steam and high steam-oil ratio makes it uneconomical, especially in long production time. In this study, a new method, two wells cyclical steam-assisted gravity drainage is compared with a conventional steam-assisted gravity drainage process. Well configuration in two wells cyclical steam-assisted gravity drainage is the same as the... 

In the upstream asphaltene flow assurance community, both academics and industries are actively involved to predict the asphaltene deposit profile in wellbores and pipelines. Essential information for such a study is the amount of asphaltenes that can precipitate and, hence, deposit. In this work, the perturbed chain form of the statistical associating fluid theory (PC-SAFT) is applied to predict the asphaltene precipitation onset condition as well as the amount of precipitate under pressure depletion and high-pressure and high-temperature gas injection conditions. Previous PC-SAFT asphaltene studies in crude oil required the compositional data for both flashed gas and flashed liquid. This... 

The increasing incidence of flow assurance problems caused by asphaltene deposition during oil production has motivated the development of numerous theoretical models and experimental methods to analyze this complex phenomenon. Even more challenging are the prediction of the occurrence and the magnitude of asphaltene deposition. It is well accepted that precipitation of asphaltene is a necessary condition for deposition. Hence, a significant amount of work has been devoted to the understanding of the conditions at which asphaltene precipitate from the crude oil. Although, several models seem to work well for correlating available data of onsets of asphaltene precipitation, they usually lack... 

Steam injection process has been considered for a long time as an effective method to exploit heavy oil resources. Over the last decades, Steam Assisted Gravity Drainage (SAGD) has been proved as one of the best steam injection methods for recovery of unconventional oil resources. Recently, Fast-SAGD, a modification of the SAGD process, makes use of additional single horizontal wells alongside the SAGD well pair to expand the steam chamber laterally. This method uses fewer wells and reduces the operational cost compared to a SAGD operation requiring paired parallel wells one above the other. The efficiency of this new method in naturally fractured reservoir is not well understood.... 

This paper concerns on experimental investigation of biopolymer/polymer flooding in fractured five-spot systems. In this study, a series of polymer injection processes were performed on five-spot glass type micromodels saturated with heavy crude oil. Seven fractured glass type micromodels were used to illustrate the effects of polymer type/concentration on oil recovery efficiency in presence of fractures with different geometrical properties (i.e., fractures orientation, length and number of fractures). Four synthetic polymers as well as a biopolymer at different levels of concentration were tested. Also a micromodel constituted from dead-end pores with various geometrical properties was... 

As the oil production from conventional oil reservoirs is decreasing, oil production through Enhanced Oil Recovery (EOR) processes is supposed to compensate for both the oil production reduction in matured oil reservoirs and the worldwide dramatic increase in oil demand. Therefore, developing a strategy to choose an optimized EOR technique is crucial to find a resolution for production decline in oil reservoirs. A screening tool recommending the most appropriate EOR method is proposed in this study. An expert fuzzy logic system is employed to screen four well-known EOR methods including miscible CO2 injection, miscible HC gas injection, polymer flooding and steam injection based on the... 

Thermodynamic modeling is known as a promising tool for phase behavior modeling of asphaltene precipitation under different conditions such as pressure depletion and CO2 injection. In this work, a thermodynamic approach is used for modeling the phase behavior of asphaltene precipitation. The precipitated asphaltene phase is represented by an improved solid model, while the oil and gas phases are modeled with an equation of state. The PR-EOS was used to perform flash calculations. Then, the onset point and the amount of precipitated asphaltene were predicted. A computer code based on an improved solid model has been developed and used for predicting asphaltene precipitation data for one of... 

The concern over fossil energy shortage for the next decade leads to the extensive research activities in the area of enhanced oil recovery. Steam injection as one of well known EOR process has been used for about five decades to improve the oil production rate and recovery efficiency. Steam flooding is applied to heavy and extra-heavy oil reservoirs; however it could be used in light oil reservoirs in which water injection do not work effectively. Regardless of different performances, this method is an efficient EOR process for both heavy and light oil reservoirs. In this work, two separate numerical models were prepared to investigate steam flooding performance for the recovery of light... 

The In-Situ Combustion (ISC) as a thermal EOR process has been studied deeply in heavy oil reservoirs and is a promising method for certain non-fractured sandstones. However, its feasibility in fractured carbonates remained questionable. The aim of the present work was to understand the recovery mechanisms of ISC in fractured models and to evaluate the effect of fractures geometrical properties such as orientation, density, location and networking on the ISC recovery performance. Combustion parameters of a fractured low permeable carbonate heavy oil reservoir in Middle East called KEM; applied to simulation study. Simulator has been validated with KEM combustion tube experimental data and... 

Although alkaline-surfactant-polymer flooding is proved to be efficient for oil recovery from heavy oil reservoirs, the displacements mechanism/efficiency of this process in fractured systems needs to more discussion, especially in five-spot patterns. In this work, several ASP flooding test were performed on fractured micromodels which were initially saturated with heavy oil at constant flow rate and different fracture geometrical characteristics conditions. The ASP solutions are constituted from 5 polymers i.e. four synthetic polymers include three hydrolyzed polyacrylamide with different molecular weight as well as a non-hydrolyzed polyacrylamide and a biopolymer, 2 surfactants i.e. a... 

Many heavy oil reservoirs contain discontinuous shales which act as barriers or baffles to flow. However, there is a lack of fundamental understanding about how the shale geometrical characteristics affect the reservoir performance, especially during polymer flooding of heavy oils. In this study, a series of polymer injection processes have been performed on five-spot glass micromodels with different shale geometrical characteristics that are initially saturated with the heavy oil. The available geological characteristics from one of the Iranian oilfields were considered for the construction of the flow patterns by using a controlled-laser technology. Oil recoveries as a function of pore... 

In this work effect of composition changes of injection gas, CH4 + CO2, on the performance of immiscible WAG injection in light oil, 41 oAPI, which has been rarely attended in the available literature is investigated. Presence of CO2 helps to reduce the MMP of CH4 significantly. Core flood experiments are conducted at reservoir conditions and fixed flow rate of 0.5cc/min on a sandstone sample with the brine concentration of 5000 ppm, and the influence of injection gas composition as well as WAG ratio on oil recovery is investigated. Different mole percents of methane in mixture, 0%, to 100% are examined, and the tests continued to ten alternate cycles with a slug size of 0.1 pore volumes and... 

This work examines the operational parameters that may influence the performance of toe-to-heel steamflooding in a laboratory-scale simulation model built on the basis of the fluid and rock samples from a fractured, low-permeable, carbonate heavy oil reservoir in Southwestern Iran, called KEM (Kuh-e-Mond). Using vertical (V) or horizontal (H) injectors (I) and producers (P), the effects of different well configurations including VIVP, VIHP, 2VIHP, VI2HP, HIHP, and HI2HP, injectors' traversal distance, producers' traversal distance, and horizontal producer length have been investigated. In summary, the results show that 2VIHP scheme performs best in terms of oil recovery and areal/volumetric... 

There are different thermodynamic models that have been applied for modelling of asphaltene precipitation caused by various reasons, such as solvent/CO2 injection and pressure depletion. In this work, two computer codes based on two different asphaltene precipitation thermodynamic models-the first being the thermodynamic micellization model with a different characterization approach and the second being the solid model-have been developed and used for predicting asphaltene precipitation data reported in the literature as well as in the obtained data for Sarvak reservoir crude, which is one of the most potentially problematic Iranian heavy oil reserves under gas injection conditions. For the... 

Nitrogen has been appeared as a competitive gas injection alternative for gas-based enhanced oil recovery (EOR) processes. Minimum miscibility pressure (MMP) is the most important parameter to successfully design N2 flooding, which is traditionally measured through time consuming, expensive and cumbersome experiments. In this communication, genetic programming (GP) and constrained multivariable search methods have been combined to create a simple correlation for accurate determination of the MMP of N2-crude oil, based on the explicit functionality of reservoir temperature as well as thermodynamic properties of crude oil and injection gas. The parameters of the developed... 

Although Alkaline-Surfactant-Polymer (ASP) flooding is proved to be efficient for heavy oil recovery, the displacement mechanisms/efficiency of this process should be discussed further in fractured porous media especially in typical waterflood geometrical configurations such as five-spot injection-production pattern. In this study, several ASP flooding tests were conducted in fractured glass-etched micromodels which were initially saturated with heavy oil. The ASP flooding tests were conducted at constant injection flow rates and different fracture geometrical characteristics were used. The ASP solutions constituted of five polymers, two surfactants and three alkaline types. The results... 

The aim of this contribution is to evaluate the performance of an expanding solvent steam assisted gravity drainage (ES-SAGD) process in naturally fractured systems. Steam-assisted gravity drainage (SAGD) and ES-SAGD processes have been investigated in both conventional and fractured reservoir models and the effect of networked fractures on the recovery mechanism and performance of ES-SAGD has been investigated. Operational parameters such as steam quality, vertical distances between wells, and steam injection temperature have been also evaluated. Finally, to study the effect of a well's horizontal offset, a staggered ES-SAGD well configuration has been compared to a stacked ES-SAGD