Sharif Digital Repository

During various stages of processing uranium in Isfahan’s UCF plant, liquid waste containing uranium compounds, is directed to evaporation lagoons. Gradually, a considerable amount of precipitation will form at the bottom of the lagoons. Since the concentration of uranium in evaporation ponds is relatively high, it seems that in addition to environmental issues, recycling uranium from existing pools is also economical. Uranium may be recovered from an aqueous solution by precipitation, solvent extraction and ion exchange. The solvent extraction is the best option for our purpose because of simple operation without increased consumption of heat or chemicals. It is also preferable when large... 

During the Acidizing process in oil and gas reservoirs, the injected acid reacts with the rock grains, changes the rock pore structure and affects the flow conditions. Due to the presence of a large concentration gradient at the vicinity of the rock grains and the continuous changes in rock-fluid interfaces of the porous medium, the continuum assumption has been remained debatable for the effective local mass transport and effective molecular diffusion coefficients and the porosity-permeability relation in the continuum scale modeling of this process. Therefore, the need for pore scale modelling is evident. The novelty of this study relies in adapting the grid refinement method on the... 

Gas injection is one of the common methods for enhance oil recovery from oil reservoirs. At miscible injection condition, the efficiency of the process is majorly affected by the molecular diffusion coefficient of the gas in the oil. Therefore, the accurate value of this coefficient is an essential for applying in reservoir simulator. However, determination of this coefficient only is possible through experimental methods. In this study, pressure decay method was applied to determine the diffusion coefficient of nitrogen, methane and carbon dioxide gases in crude oil. The reasons for choosing this method are : accuracy in designing the experiment, covering a wide range of pressure... 

Vortex flow reactor (VFR) is used for biochemical reactions and separation applications. By using the second flow regime, called Taylor-Couette flow, VFR provides high amounts of mass transfer and mixing for biological components sensitive to shear stress. Mass transfer in a bench-scale Taylor-Couette contactor with a radius ratio, equal to 0.77 and an aspect ratio, equal to 30.7 was studied for solid particles dissolution. The working fluid was water and the suspended particles were benzoic acid. In this project the concentration of fluid phase was measured by injection of definite amount of the solid particles in to the contactor and sampling in different time intervals and the effects of... 

Liquid-liquid extraction is one of the most important processes of chemical industries. So determination of operatiol condition in extraction columns is important. In this study, in various regimes of jet flow mass transfer coefficient during jet formation was measured and predicted experimentally. Results shown turbulent flow regime has higher mass transfer coefficient and axisymmetric jetting flow has lower mass transfer coefficient. Whereas studies related to mass transfer in liquid-liquid system are afew, numericall study was performed in this project. In this study system was simulated in unsteady state.Front-tracking method was used for simulating two phase flow and finite-volume... 

The theory of mass transfer accompanied by chemical reaction for gas-liquid systems was used to measure the specific interfacial area and mass transfer coefficient in a two impinging jets reactor (TIJR) in the presence of γ-Al_2 O_3 nanoparticles.The absorption of oxygen in sulfite solutions used for the determination of mass transfer characteristics. First 3 liters of nanofluids were prepared at concentration of 1 w% then diluted To produce 10 Liters of nanofluids containing 0.3 w%. The stability of this nanofluid was determined using uv-vis to be less more than 95% in the first 3 hours. The influence of weight percent of nanoparticles (0, 0.05, 0.1, 0.15, 0.2, 0.3) on the specific... 

There are many different opinions about the mass transfer contribution during jet formation in liquid - liquid extraction columns, and this could impact on their design. In this work, using experimental data obtained in two RDC columns and unpublished data of the jet mass transfer coefficients, mass transfer can be predicted during jet formation. The jet length and diameter were anticipated by using existing relations, and then the jet mass transfer coefficient was predicted, jet mass transfer rate and total column mass transfer rate were calculated and finally the contribution of mass transfer during jet formation in the column was predicted. Mass transfer contribution in the jet in various... 

Liquid-liquid extraction is one of most important processes in chemical industries. So determination of operating condition effects is very critical. In this thesis we modeled concentration profile in the jet via mathematical equations and compare with experimental data. The major problem in concentration profile and solving equations is lack of knowledge in velocity profile within the jet was formed. Therefore, different flow models such as piston flow model, parabolic flow model, vortex flow model and a cone flow model was used and terminal concentrations inside the jet compared with laboratory values. Results shows the most accurate model to predict the flow concentration along the... 

Extraction and separetion of molybdenum is important because of its application in different industries. Since molybdenum resources are finite and low-grade, hydrometallurgical methods can be used to extract molybdenum. Solvent extraction of rare metals one of the important processes of hydrometallurgy.In the first of research, molybdenum solvent extraction from sulfate msoloution was investigated in batch and semi-industrial scale. In the laboratory scale, molybdenum solvent extraction from aqueous solution was investigated by using of D2EHPA, Cyanex272 and TBP. The effects of various parameters such as extractrant concentration, synergistic enhancement factor for mixture of extractants,... 

In this research the performance of the Moving Bed Biofilm Rector (MBBR) in different amounts of dissolved oxygen (DO) was investigated. Reactor with a useful volume of 15 liters was used in this study. In order to obtain optimum oxygen concentration, stayed at 6, 10 and 15 hours, and at different levels of dissolved oxygen in the range 0.5 -6 mg/lit, the amount of organic material was removed respectively. Also, in two different aeration intensity of 3.5 and 5.5 liters per minute at different values of e% (percentage of filling of media) the mass transfer coefficient values were obtained. When the aeration intensity increases from 3.5 to 5.5 liters per minute, and the percentage of 40%... 

It has been shown that absorption of carbon dioxide can be enhanced using nanoparticles and in the presence of magnetic field. In the present work, the influences of ferrofluids and magnetic fields on the absorption of CO2 in packed-bed contactors have been investigated carefully. In this regard, multi-tube approach has been applied to model the contactor. The simulation results were validated against experimental data reported in the literature in the absence of nanoparticles and magnetic fields and good agreement was obtained. The influences of variable operating conditions on the contactor performance were carefully investigated. It was found that for 3.4% volume percent of magnetic... 

In present study, it is tried to investigate the effect of physical properties on hydrodynamic and overall mass transfer coefficient of single drops using different experiments and then simulation of drop motion with OpenFOAM software version 1.7.1. the systems were choosen are toluene/acetone/water and n-butanol/succinic acid/water which their interfacial tensions are 36 and 1.6 mN/m respectively. Various type of nozzles have been used for produce of 1.5, 2, 3 and 4 millimeter drops. The results show that in absence of solute component, the rising velocity of toluene drops in each size is higher than rising velocity of butanol drops inside the water between 25 to 75 percent. But with... 

The importance of gases and liquids absorption in the liquid falling film is mostly due to the wide applications of liquid falling film reactors in the chemical industries. In such a reactor the mass and heat transfer occur simultaneously, but in most cases, the importance of mass transfer is predominant. Therefore, the study of heat transfer in this kind of reactor is neglected. In order to improve the efficiency of absorption, different methods have been employed by researchers. Owing to the rapid growth of nanotechnology, nanofluids have widely been used for increasing the absorption of solution, recently. Magnetic fluids due to their unique combination, among different kinds of... 

Nanofluids are new engineering materials with great potential for application in process industries. Their enhanced heat-transfer properties are reported in recent literatures. However, with respect to the influence of nanoparticles on mass transfer characteristics, limited number of studies available in the literature, deal primarily with gas-liquid systems. In this work, mass transfer performance and droplet behavior along a pulsed liquid-liquid extraction column, is studied where SiO2 nanoparticles with concentrations of 0.01, 0.05 and 0.1 vol% and different hydrophobicities are applied to the dispersed phase. Using ultrasonication, nanoparticles were dispersed in kerosene as the base...