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Facile synthesis of petal-like NiCo/NiO-CoO/nanoporous carbon composite based on mixed-metallic MOFs and their application for electrocatalytic oxidation of methanol
, Article Applied Catalysis B: Environmental ; Volume 244 , 2019 , Pages 802-813 ; 09263373 (ISSN) ; Shahrokhian, S ; Sharif University of Technology
Elsevier B.V
2019
Abstract
Porous carbon template decorated with mixed transition metals/metal oxides with tunable architecture is becoming increasingly important and attractive as a kind of novel electrode materials. In this way, mixed-metallic metal-organic frameworks (MOFs) provide an opportunity for fabrication of homogeneous mixed metals/metal oxides distribution in the porous carbon frame without any carbon precursor additive. Also, structures, dimensions and electrochemical performance of MOFs can be readily manipulated by simply tuning the metals molar ratio. In this study, we demonstrate the design and fabrication of petal-like NiCo/NiO-CoO metal/metal oxides with a rational composition embedded in 3D...