Sharif Digital Repository

In this work, asphaltene adsorption in a sandstone core sample under dynamic conditions and during miscible CO2 injection was studied using live oil sample which is close to real conditions in petroleum reservoirs. In order to investigate of damage in sandstone core sample by the deposited material such as asphaltene, the morphology analysis of sandstone core sample using scanning electron microscopic method was studied. Also analyses of the adsorbed material in sandstone core sample by Soxhlet extraction using an azeotrope mixture and with SARA method were performed. The experimental results show that by increasing the flow rate of injected CO2, the amount of asphaltene in retained material... 

In this work, a new model based on multilayer kinetic adsorption mechanism has been proposed to account asphaltene adsorption in porous media under dynamic condition and the model was verified using experimental data obtained in this work and also with those reported in the literature. In the proposed model two steps are considered for asphaltene adsorption. The first step is taken as adsorption of asphaltenes on the surface of the porous media and the second step is taken as adsorption of asphaltenes on the asphaltenes already adsorbed on the porous media. The Crank-Nicholson method, central difference in space and trapezoidal rule in time, giving second order convergence in time was... 

Graphene oxide (GO) sheets were synthesized through a modified Hummers' method. Using high resolution transmission electron microscopy the thickness of the GO sheets in a multilayer structure of stacked GO sheets was found ∼0.8 nm. A nanosecond pulsed laser (with wavelength of 532 nm and average power of 0.3 W) was applied for effective and environment friendly reduction of the GO sheets in an ammonia solution (pH ∼9) at room temperature conditions. The deoxygenation of the GO sheets by the pulsed laser reduction method was confirmed by using UV-visible, Fourier transform infrared, X-ray photoelectron spectroscopy (XPS) and thermo gravimetric analysis. Based on XPS analysis, the O/C ratio of... 

Absorption of carbon dioxide (CO2) in aqueous solutions can be improved by the addition of other compounds. However, this requires a large amount of equilibrium data for solubility estimation in a wide ranges of temperature, pressure and concentration. In this paper, a model based on an artificial neural network (ANN) was proposed and developed with mixtures containing monoethanolamine (MEA), diethanolamine (DEA), methyldiethanolamine (MDEA), 2-amino-2-methyl-1-propanol (AMP), methanol, triethanolamine (TEA), piperazine (PZ), diisopropanolamine (DIPA) and tetramethylensulfone (TMS) to predict solubility of CO2 in mixed aqueous solution (especially in binary and ternary mixtures) over wide... 

Particulate back-reflector films are conventionally used for the improvement of light harvesting in dye solar cells (DSC). The back-reflection of the films is directly related to the scattering efficiency of the individual particles. Inspired by the idea of multilayer optical thin films, here it is demonstrated theoretically and experimentally that putting a SiO2 shell around spherical rutile-TiO2 particles leads to improved light scattering by the particles. These dielectric core-shells not only enhance the overall diffuse reflection of the films, but they also cause a relative improvement in the red and near infrared regions. Back-reflector films of these core-shell particles employed in... 

Propane dehydrogenation was carried over a commercial Pt-Sn/γ-Al 2O3 catalyst at atmospheric pressure and reaction temperatures of 580, 600, and 620°C and WHSV of 11 h-1 in an experimental tubular quartz reactor. Propane conversions were measured for catalyst time on stream of up to nine days. The amounts of coke deposited on the catalyst were measured after one, three, six, and nine days on stream using a thermogravimetric differential thermal analyzer (TG-DTA) for each reaction temperature. The coke formation kinetics was successfully described by a coke formation model based on a monolayer-multilayer mechanism. In addition, catalyst deactivation was presented by a time-dependant... 

In this paper a time-domain response and Nyquist stability criterion to acquire dependence of degree of crosstalk relative stability based on transmission lines modeling (TLM) is investigated for coupled multilayer graphene nanoribbon (MLGNR) interconnects. This is the first instance that such an analysis has been presented for coupled MLGNR consisting of both capacitive and mutual-inductive couplings. The near-end and far-end outputs of coupled MLGNR individually are compared in two cases, with considering both couplings and without them (single MLGNR). It is observed that the near-end output of the system together with both couplings is more stable and at its far-end output, an induced... 

Pressure transient analysis in vertically heterogeneous reservoirs is examined. The inclusion of a separate model for the free fluid flow in the wellbore is essential to allow for hydraulic communication and mixing of the fluid issuing from different reservoir layers. A two-dimensional model coupling Darcy flow in the reservoir with Navier-Stokes flow in the wellbore is developed and solved by the finite element technique. The coupled wellbore-reservoir flow model is used to analyze a layered reservoir with an abrupt change in permeability and a thick formation showing a gradual change in permeability with depth. Contrary to conventional reservoir models, this new model is able to capture... 

In this work, a new model based on the multilayer adsorption kinetic mechanism and four material balance equations for oil, asphaltene, gas, and water phase has been developed to account for asphaltene deposition in porous media under dynamic conditions and the model was verified using experimental data obtained in this work and also with those reported in the literature. The results showed that the developed model based on multilayer adsorption kinetic mechanism can correlate more accurately the oil flooding experimental data in comparison to the previous models based on the mechanical plugging mechanism, in particular in carbonate core samples. Also, a series of experiments was carried to... 

In this work, the goal is to find the optimum working point for intelligent wells that is equipped with down-hole chokes and producing from a multi-layer reservoir under pressure maintenance process. Two evolutionary optimization algorithms are used and results are compared from different points of view. Therefore, the differential evolution technique and genetic algorithm has been used in conjugation with a reservoir simulator. The overall optimization technique is applied to heterogeneous example problems involving smart and multi segment wells. Improvement of predicted performance, which is as high as 7% in one case is demonstrated for all of the examples studied  

Tubular ceramic membranes were synthesized by depositing a dense layer of silica-alumina on top of a multilayer substrate using co-current chemical vapor deposition (CVD) method. The multilayer substrate was prepared by coating with a series of bohemite sols with certain particle sizes. Cross-sectional and surface images obtained from high resolution FESEM showed that the intermediate layer had a thickness of about 1μm and the top selective layer was uniform and dense with a thickness of less than 100nm. Permeance tests, which were carried out with H 2, CO 2, N 2 and CH 4 at a high temperature range of 923-1073K, indicated that gas permeation took place via different mechanisms through... 

The authors studied the efficiency and accuracy of neural network model for prediction of permeability as a key parameter in reservoir characterization. So, some multilayer perceptron (MLP) neural network models with different learning algorithms of Levenberg-Margnardt, back propagation, improved back propagation (IBP), and quick propagation with three layers and different node numbers (3, 4, 5, 6, 7) in the middle layer have been presented. These models have been obtained by 630 permeability data from one of offshore reservoirs located in Saudi Arabia. The accuracy of models was studied by comparing the obtained results of each model with experimental data. So, the neural network with IBP... 

A hydrogen-selective nano-composite ceramic membrane was prepared by depositing a dense layer composed of SiO2 and Al2O 3 on top of a graded multilayer substrate using co-current chemical vapor deposition (CVD) method. The multilayer substrate was made by dip-coating a macroporous α-alumina tubular support by a series of boehmite solutions to get a graded structure. Using DLS analysis, it was concluded that decreasing hydrolysis time and increasing acid concentration lead to smaller particle size of boehmite sols. XRD analysis was carried out to investigate the structure of intermediate layer and an optimized calcination temperature of 973 K was obtained. SEM images indicated the formation... 

In this paper, oil recovery and permeability reduction of a tight sandstone core sample in miscible CO2 flooding processes due to asphaltene deposition were studied using an Iranian bottom hole live oil sample in order to distinguish between the mechanical plugging and adsorption mechanisms of asphaltene involved in the interfacial interaction of the asphaltene/mineral rock system. A novel experimental method was designed and proposed to measure the amount of deposited asphaltene due to different mechanisms using the cyclohexane or toluene reverse flooding and spectrophotometer. In this work, the bottom hole live oil sample was injected first to a long core and then CO 2 injection was... 

We demonstrate high-quality integrated inductors built from a multilayer of alternating copper and ferromagnetic films. The multilayer acts as a meta-conductor whose effective permeability becomes nearly zero at its ferromagnetic anti-resonance frequency. This leads to a suppression of the skin effect and a significant increase in the quality factor of the device. Experiments show an up to 86% increase in quality factor compared to conventional copper-based spiral inductors at high frequencies  

In this paper, free vibration of a fiber reinforced composite cylinder in which volume fraction of its fibers vary longitudinally, is studied using a semi-analytical method. The distribution of volume fraction of fiber in base matrix is based on power law model. A micromechanical model is employed to represent its mechanical properties including elastic and physical properties of this composite cylinder. In addition, kinematically the first order shear deformation shell theory is employed for strain field. Then, weak form formulation and spatial approximations of variables are utilized to discretize the equations of motion. Different problems are solved in which primarily the validity of the... 

In this paper, the buckling analysis of a multilayered composite cylindrical shell which volume fraction of its fiber varies according to power law in longitudinal direction, due to applied compressive axial load is studied. Rule of mixture model and reverse of that are employed to represent elastic properties of this fiber reinforced functionally graded composite. Strain displacement relations employed are based on Reissner-Naghdi-Berry's shell theory. The displacement finite element model of the equilibrium equations is derived by employing weak form formulation. The Lagrangian shape function for in-plane displacements and Hermitian shape function for displacement in normal direction to... 

A multilayer back propagation learning algorithm was used as an artificial neural network tool to predict the mechanical properties of porous NiTi shape memory alloys fabricated by press/sintering of the mixed powders. Effects of green porosity, sintering time and the ratio of the average Ti to Ni particle sizes on properties of the product were investigated. Hardness and tensile strength of the compacts were determined by hardness Rockwell B method and shear punch test. Three-fourths of 36 pairs of experimental data were used for training the network within the toolbox of the MATLAB software. Porosity, sintering time and particle size ratios were defined as the input variables of the model.... 

This paper deals with the problem of multicasting a set of discrete memoryless correlated sources (DMCS) over a cooperative relay network. Necessary conditions with cut-set interpretation are presented. A Joint source-Wyner-Ziv encoding/sliding window decoding scheme is proposed, in which decoding at each receiver is done with respect to an ordered partition of other nodes. For each ordered partition a set of feasibility constraints is derived. Then, utilizing the submodular property of the entropy function and a novel geometrical approach, the results of different ordered partitions are consolidated, which lead to sufficient conditions for our problem. The proposed scheme achieves... 

Single-walled carbon nanotubes (SWCNTs) and multiwalled carbon nanotubes (MWCNTs) were synthesized in aqueous solutions containing FeCl2, FeCl3, FeSO4 and Fe2(SO4) 3. The effects of iron charge and the counter ions on the formation of carbon nanotubes (CNTs) were investigated. Thermogravimetric (TG) analysis indicated that carbon multilayer structures including CNTs and multishell graphite particles were formed in deionized (DI) water without the iron precursor. SWCNTs were also synthesized in the presence of the iron ions. It was also found that the mole ratio of [Fe2+]/[Fe3+] in the solution has a significant influence on the purity of CNTs and the process yield. The highest yield was...