Sharif Digital Repository

Syntheses of coats including nickel nano-particles by electrodeposition have been
investigated for over 10 years. A method of testing according to surface reply was chosen
to reveal the effect of each pulse parameters (including duty cycle, frequency, average
current density, off time (toff) and on time (ton)) and the effect of saccharin concentration
on electroplating cathode efficiency, nanostructure. Pulse electroplating test of nickel was
composed by 30 tests. Pulse electroplating with relatively high peak current density was
employed and saccharine was added to increase deposition and rate of nickel nucleation on
surface. According to the results of cathode... 

Electrochemical sensing of glucose has received paramount attention in recent years, particularly, the non-enzymatic glucose sensing is one of the trends in the whole biosensing world. In this research, synthesis and evaluation of a hybrid structure of vertical oriented nickel nanorod-reduced graphene oxide sheets as a non-enzymatic glucose sensor were performed. The 3D array of nickel nanorods was synthesized by electrodeposition of nickel sulfate electrolyte in track-etched polycarbonate template with 100 nm pore size and 6-10 μm thickness. The electrodeposition performed in various conditions, and the best result was achieved by application of potential of 3 V for 60 minutes. The shiny... 

Ni/SiO2 nanoparticle composite coatings were prepared by electrophoretic deposition (EPD) and their hardness, wear and corrosion resistance were examined. Additionally, the morphology of the coatings was observed. In the first phase, the feasibility of coating with Scanning Electron Microscopy (SEM) as well as X-ray diffraction (XRD) and Energy Dispersive Spectra (EDS) techniques was evaluated. After finding the effect of concentration of nanoparticles on coating characteristics and the results of using SEM, optimum conditions for uniform coating, acceptable adhesion at 20V and concentrations of 10 g/L for Ni, 1.2 g/L for SiO2, and choosing NiCl2 as additive with a concentration of 0.2 g/L... 

In the first part of this research, for the first time, we introduced a flexible high performance graphene-based supercapacitor using silver fiber fabric as the current collector. The silver fiber fabric offers remarkable advantages such as light weight, mechanical flexibility and ease of integration with electronic textiles, which well-suited for wearable energy storage devices. A new hybrid material of graphene-silver fiber fabric (rGO/SFF) was prepared through a facile electrophoretic deposition of graphene and being used as a binder-free flexible supercapacitor electrode. In order to obtain the optimum condition, the effect of deposition time was investigated and a duration time of 10... 

Hyperthermia (also called thermal therapy or thermotherapy) is defined as a type of cancer treatment in which body tissue is exposed to high temperatures, to damage and kill cancer cells, or to make cancer cells more sensitive to the effects of radiation and certain anticancer drugs. The temperature increase required by hyperthermia can be achieved via different heat sources, such as electromagnetic radiation waves (radiofrequency or microwave, ultrasound waves and electrical current. These techniques have shown good results, however, the major problem with present conventional methods is reaching homogenous heat distribution and therapeutic temperatures in the deep region of the tumor to be... 

Sharif University of Technology Plasma Focus (SUT-PF) is a Mather Type DPF device which has a 39 μF capacitor bank with 14 KV charging ability at its ultimate limit corresponding to 7 KJ stored energy. In the first step of this experiment, a test has been done at three distances 5, 7, 10 cm from anode tip with the different number of shots 20, 30, and 40 at 0 constant angles.In the following, a test is done at 5 and 10 degrees with 40 shots, and PF chamber has been filled up with nitrogen gas. Various tests have carried out for survey of this experiment, the result of which are as follow:The X-ray diffraction (XRD) analysis are used in order to reveal if the Nickel or Nickel nitride have... 

In this study, granular activated carbon has been modified by potassium nickel hexacyanoferrate ( KNCF), sodium dodecyl sulfate(SDS) and ammonium per sulfate(APS) as new adsorbents for cesium, cobalt and chromium(VI), respectively. The prepared adsorbents were characterized using powder X-ray diffraction(XRD), nitrogen adsorption-desorption isotherm data, infrared spectroscopy, scanning electron microscopy coupled with energy dispersive spectroscopy(SEM-EDS) and their adsorption performance were investigated. The effect of various parameters like the initial pH value of the solution, contact time, temperature, strength ionic of the solution, interference ions and the initial concentration of... 

First stage blades tempreture in the turbine rotor section for the advanced turbines has increased up to 1100oc. The blades should be under mentioned condition for the long times up to 70000 hours and accordingly creep happens. Fatigue–creep interaction is the main reason for the failures of many engineering components under high temperature and cyclic loading. In this thesis, a model for the life prediction of fatigue–creep interaction which was developed by other investigators has been modified to predict fatigue–creep interaction on the nickel-based superalloys. In this model, the law of energy conservation and the momentum conservation principle are used to describe the process of... 

Nowadays, single-crystal nickel-based superalloys are widely used in the manufacture of gas turbine blades in the aerospace industry due to their high resistance to creep, fatigue and corrosion at high temperatures. The superior behavior of these materials at elevated temperatures is a result of their two-phase microstructure, which includes the matrix phase (γ) of nickel and the precipitate phase (γ') of Ni3Al intermetallic compounds with a high volume fraction. The aim of this thesis is to develop computational modeling tools to study the creep deformation of single-crystal Ni-based superalloys. At high temperatures, the creep deformation of Ni-based superalloys is determined by the atomic... 

The aim of this study is to investigate the role of the temperature, stress, strain rate, and rhenium (Re) on the γ\/γ^' interfacial misfit dislocation network and mechanical response of Ni-based single crystal superalloys. The interfacial network plays an important role in the superior creep behavior of Ni-based superalloys. Therefore, a comprehensive understanding of this topic would help us to go through the impact of various factors on the mechanical and creep properties at high temperatures to achieve an optimal design. Due to the mismatch between the two phases, a dislocation network forms after aging at high temperatures to alleviate the stress field. The (100), (110), and (111)... 

In this paper, a machine learning-based atomistic-continuum multi-scale scheme is introduced to model the materials' geometrically and materially nonlinear behavior. The kinematic and energetic consistency principles are employed to link the atomistic and continuum scales. In order to establish the kinematic consistency principle, the periodic boundary condition is implemented for the atomistic RVE. The Ni-based superalloy, including 0 to 3% porosity, is considered for the models. Several parameter analysis is done to distinguish the proper atomistic RVE to be used in multi-scale models. The data set, including the stress-strain samples, is generated through molecular dynamics analysis... 

This study aims to investigate the creep deformation mechanisms in nickel-based single-crystal superalloys for which two-dimensional molecular dynamics (MD) simulations are conducted to model various temperature, stress conditions and phase interface crystal orientations. Ni-based single-crystal superalloys are of great importance in the aircraft industry, on account of their excellent high temperature creep resistance. This characteristic mainly originates from two features considered in their structure: first, their two-phased microstructure comprising gamma ( ) and gamma prime ( ), and the nature of this superalloy itself which is single-crystal. MD is a powerful tool to gain insight into... 

Nickel based superalloys are widely used in turbines since they are highly resistant to static, fatigue and creep loadings at high temperatures. Efficiency of turbines can be increase by application and development of these materials, which leads to reduced energy consumption. Nickel based superalloys constitutes of two phases, γ and γ' with multiscale behaviour. Thus to better understand the behaviour of this material, its behaviour should be studied across different scales.Molecular dynamics is used to model mechanical behaviour of this superalloy. This method is used for atomistic simulation of materials in which forces between atoms are modelled using an interatomic potential. Different... 

Laser cladding is a processing technique of layer-by-layer material deposition which is widely used to repair important components. However, tensile residual stresses generated in this process may result in detrimental effects such as crack, undesirable deformation and reduced fatigue life. A thermo-mechanical finite element model is developed to accurately predict residual stresses of the multiple beads laser cladding process with incorporating the cyclic plasticity into the analysis by utilizing the nonlinear kinematic hardening behavior. FE results are presented for Inconel 718, a material for which the laser cladding process is widely used. The FE results are compared with those of... 

One of the most important parts of designing turbine blades is machining (milling) process of blade root. There is some implementing problem in material removal processing by milling. Because of low heat transferring of inconel 738 in machine parts there is huge amount of heat which cause high temperature in machine and burning, which reduces the efficiency of milling.One of the common way to reduce the temperature of machine is using coolant fluids, which increases expenses and makes environmental pollution, so it is not completely efficient as an industrial work. In this paper Whit using MQL and some new lubricant had been observed more efficient condition in milling process. The main goal... 

Drilling super alloys with a good hole quality and acceptable surface finish is a constant challenge in modern industries dealing with such materials. Ultrasonic assisted drilling is a modern and nonconventional method of drilling which has attracted many researchers attention recently. In this study deep drilling on Inconel 738 LC is done using ultrasonic assisted drilling technique and the results are compared with those of Electro Discharge Machininng or EDM method. The results show that Ultrasonic Assisted Drilling or UAD is an appropriate alternative for EDM of Inconel. The whole process time is decrease dimensional accuracy is improved and surface roughness is decreased significantly.... 

Superalloys are widely used in aerospace and power industries due to the good performance at high temperatures for examples gas turbines, steam turbines and aircraft components. In addition to the turbines cobalt-base superalloys are used in medical implants such as knee and hip joints. The main strengths of the superalloys are heat-resistant, retaining their high mechanical and chemical properties at high temperatures, high melting temperatures, high corrosion resistance, resistance to thermal fatigue, thermal shock, creep, and erosion. Because of difficult to machine properties of superalloys, grinding is one of the effective methods for machining superalloys. The surface integrity of the... 

Electrochemical deposition of multilayer coatings is one of the surface engineering techniques to create thin surface layers with a controlled structure in order to create desirable surface properties. In this research, the nickel-iron-silicon carbide multilayer coating is deposited from a single bath with a sulfate composition and by changing the current density between two values (10 and 40 mA/cm2). The number of layers in multilayer coating was 4, 8, 16, 32.The effect of current density and the number of layers on chemical composition, surface morphology, phase structure, corrosion resistance, nano hardness measurement, wear resistance of multilayer coatings respectively using electron... 

Successfully bonding nickel-base alloys to titanium-base alloys has proven to be one of the most challenging modern joints. Traditional welding methods for dissimilar titanium/nickel joints often lead to cracking in the fusion and heat-affected(HAZ)zones; due to the formation of brittle intermetallic compounds with low fracture toughnesses. Additionally, the significant difference in thermal expansion coefficients between titanium and nickel introduces significant thermal stress during bonding process, exacerbating the current issue. Creating successful dissimilar Ti/Ni joints requires overcoming the formation of continuous brittle intermetallic compounds (IMCs). Brazing stands out as a... 

The brazing process is the preferred method for bonding and repairing high temperature resistant superalloys. In this process, filler metals containing MPD elements such as B and Si are used. The presence of these elements causes the formation of brittle and eutectic phases such as borides and silicides in the joint area. These phases reduce the mechanical properties and re-melting temperature of the joint. By increasing the temperature and time of bonding and using the concept of isothermal solidification, the formation of boride and silicide phases can be prevented. In wide gap joints, the time to complete the isothermal solidification is very long, and applying such temperature and time...