Sharif Digital Repository

A novel mesoporous silica-functionalized dual Brønsted acidic species has been introduced as an efficient catalyst for solvent-free esterification of fatty acids with ethanol. The structure of the catalyst has been characterized by FT-IR spectroscopy, thermal gravimetric analysis (TGA), TEM and N2 adsorption-desorption. TGA of catalyst 1 showed no weight loss before 200 °C, indicating a high degree of hydrophobicity of the surface of the mesoporous silica. TEM images and nitrogen adsorption-desorption showed no noticeable changes to the structure of the catalyst before and after acid treatment. pH metric analysis was performed for the catalyst to determine the loading of the acidic sites.... 

Radial flux variable reluctance resolvers (RFVR2s) are widely used in variety of applications. However, they suffer from an intrinsic error which is called static eccentricity (SE). Although most of the errors in the resolvers can be suppressed using electronic methods in resolver to digital (R/D) converters, static misalignment is an exception. In this paper an axial flux configuration is proposed for variable reluctance (VR) resolvers with concentric windings. Then the proposed structure is optimized to achieve the minimum sensitivity of accuracy against SE. The performance of the presented structure, so called axial flux variable reluctance resolver (AFVR2), is validated using 3-D time... 

This article explores the main tradeoffs in design of power and area efficient bandgap voltage reference (BGR) circuits. A structural design methodology for optimizing the silicon area and power dissipation of CMOS BGRs will be introduced. For this purpose, basic equations of the bandgap circuit have been adapted such that can simply be applied in the optimization process. To improve the reliability of the designed circuit, the effect of amplifier offset has been also included in the optimization process. It is also shown that the minimum achievable power consumption and area are highly depending on the fabrication process parameters especially sheet resistivity of the available resistors in... 

The paper presents further experiments with an extended version of a comprehensive model for assessment of energy technologies and research and development (R&D) planning to evaluate the impact of innovation programs on development of Iranian electricity-supply system. This analytical instrument is a model of energy R&D resource allocation with an explicit perspective of developing countries which has been linked to a bottom-up energy-systems model. Three emerging electricity generation technologies of solar PV, wind turbine and gas fuel cell are considered in the model and the impact of innovation programs on cost-reducing innovation for them is examined. The main results provided by the... 

TiO2 nanorod layers are synthesized by simple chemical oxidation of Ti substrates. Diffuse reflectance spectroscopy measurements show effective light scattering properties originating from nanorods with length scales on the order of one micron. The films are sensitized with CdSe quantum dots (QDs) by successive ionic layer adsorption and reaction (SILAR) and integrated as a photoanode in quantum dot sensitized solar cells (QDSCs). Incorporating nanorods in photoanode structures provided 4- to 8-fold enhancement in light scattering, which leads to a high power conversion efficiency, 3.03% (Voc = 497 mV, Jsc = 11.32 mA/cm2, FF = 0.54), in optimized structures. High efficiency can be obtained... 

The study develops a methodology for the aero-structural design including consideration of the starting of a small wind turbine blade. To design a fast-starting blade, starting time was combined with output power in an objective function and the blade allowable stress was considered as a constraint. The output power and the starting time were calculated by the blade-element momentum theory and the simple beam theory was employed to compute the stress and deflection along the blade. A genetic algorithm was employed to solve the constrained objective function, finding an optimal blade for which the starting time was small and output power was high while the stress limitation was also met.... 

It has been well documented that multivariate systems will benefit from application of advanced control strategies. The application of these methods has thus far been hindered for a variety of reasons which range from complexity of the design methodologies to the cost associated with implementation of these solutions. This paper shows that there exist alternative means by which existing control strategies of a multivariate system could be extended, thereby leading to increased efficiency, without the need to remove and implement a new control system installation. A realistic model of an entire pulping mill is used in this paper to show that by careful selection of only a few additional... 

-In this paper, a new optimized structure for two-speed, capacitor-run, single-phase axial flux induction motor (AFIM) for direct-drive operation is presented. Although, there are many advantages for direct-drive systems, their axial forces between the stator and rotor increases with reduction in air-gap length and is of serious concern. An increase in the air-gap length will result in the deterioration of performance characteristics of the motor. In this paper, a new construction technique is proposed to fabricate an AFIM with adjustable air-gap length. After presenting a comprehensive design algorithm, all geometrical dimensions and electrical equivalent circuit parameters are analytically... 

Theoretical study of nitrogen monoxide adsorption on small Six (x = 3-5) clusters has been carried out using the advanced hybrid meta-density functional method of Truhlar (MPW1B95). MG3 semi-diffuse basis sets were employed to improve the results. The geometry, adsorption energy, natural bond orbital charge, natural population analysis (NPA)-derived spin density and vibrational frequency of NO adsorption on all optimized nanoclusters were investigated. Also using the NPA, we have investigated the change of bond orders through adsorption. It has been found that NO is capable of making n-centre bonds (n = 1-4) from the nitrogen side but bonds to one site from the oxygen end. In the later case... 

Theoretical study of carbon monoxide adsorption on SixGe4 - x(x = 0-4) nano-clusters has been carried out using advanced hybrid meta density functional method of Truhlar (MPW1B95). MG3 semi-diffuse (MG3S) and correlation consistent valence basis sets with relativistic core potential were employed to improve the results. The agreement of the calculated ionization and dissociation energies with experimental values validates the reported structures of nano-clusters and justifies the use of hybrid meta density functional method. The geometry, adsorption energy, charge distribution, and vibrational frequency of CO adsorption on all possible structures were investigated. The maximum vibrational... 

Stability analysis of machine tool requires determining of frequency response function (FRF) of spindle. Since this response is changed with a change of tool, Receptance coupling sub-structuring analysis may be used to couple the tool and spindle FRFs. A major difficulty in this regard is the determination of joint model between the two sub-structures. In particular, the identification of rotational DOFs at joints is difficult. In this research, a joint model which accounts for rotational DOFs is proposed and verified which does not require any rotational DOF measurement on machine tool. An optimization method based on genetic algorithm is employed to find parameters of the joint model.... 

In this paper, we present a reconfigurable architecture for networks-on-chip (NoC) on which arbitrary application-specific topologies can be implemented. When a new application starts, the proposed NoC tailors its topology to the application traffic pattern by changing the inter-router connections to some predefined configuration corresponding to the application. It addresses one of the main drawbacks of the existing application-specific NoC optimization methods, i.e., optimization of NoCs based on the traffic pattern of a single application. Supporting multiple applications is a critical feature of an NoC when several different applications are integrated into a single modern and complex... 

Three-dimensional reduced graphene oxide (3D-rGO) structures decorated with CuO particles (GCu) are synthesized through a simple and scalable method for detection of hydrogen sulfide (H2S) gas. For characterization and investigation of porous structure various techniques were employed. Decorated 3D structures demonstrated higher sensitivity and selectivity in comparison to pure structure. Optimized structure for sensing was obtained through introducing different amounts of CuO. The GCu heterostructures containing 35 μmol of CuO powder demonstrated reproducible response of about 30% to the concentration of 10 ppm at room temperature, while complete recovery was obtained through heating to 150... 

This paper proposes an Age-Dependent Clustering (ADC) structure to be used for prognostics. To achieve this aim, a step-by-step methodology is introduced, that includes clustering, reproduction, mapping, and finally estimation of Remaining Useful Life (RUL). In the mapping step, a neural fitting tool is used. To clarify the age-based clustering concept, the main elements of the ADC model is discussed. A Genetic algorithm (GA) is used to find the elements of the optimal model. Lastly, the fuzzy technique is applied to modify the clustering. By investigating a case study on the health monitoring of some turbofan engines, the efficacy of the proposed method is demonstrated. The results showed... 

In this paper, an attempt is made to examine a new method for designing and applying the active vibration control system to improve building performance under mainshock–aftershock sequences. In this regard, three different structures are considered; 5-, 10-, and 15-story buildings. Seven mainshock–aftershock sequences are selected from the Iranian accelerogram database for analyzing the structures. By implementing an advanced two-step optimization method, buildings equipped with the active vibration control system (linear–quadratic regulator (LQR) algorithm) are designed to withstand all events of mainshock–aftershock sequences. In the first optimization step, a multi-objective optimization... 

In this paper, an attempt is made to examine a new method for designing and applying the active vibration control system to improve building performance under mainshock–aftershock sequences. In this regard, three different structures are considered; 5-, 10-, and 15-story buildings. Seven mainshock–aftershock sequences are selected from the Iranian accelerogram database for analyzing the structures. By implementing an advanced two-step optimization method, buildings equipped with the active vibration control system (linear–quadratic regulator (LQR) algorithm) are designed to withstand all events of mainshock–aftershock sequences. In the first optimization step, a multi-objective optimization... 

The optimum design of reinforced concrete cantilever retaining walls subjected to seismic loads is an extremely important challenge in structural and geotechnical engineering, especially in seismic zones. This study proposes an adaptive sperm swarm optimization algorithm (ASSO) for economic design of retaining structure under static and seismic loading. The proposed ASSO algorithm utilizes a time-varying velocity damping factor to provide a fine balance between the explorative and exploitative behavior of the original method. In addition, the new method considers a reasonable velocity limitation to avoid the divergence of the sperm movement. The proposed algorithm is benchmarked with a set... 

New penalty functions, which have better convergence properties, as compared to the commonly used exterior and interior penalty functions, have been proposed in this paper. The convergence behavior and accuracy of ordinary penalty functions depend on the selection of appropriate penalty parameters. The optimization of ordinary penalty functions is accomplished after several rounds of optimization where, at each round a different but fixed value of penalty parameter is used. While some useful hints and rules for the selection of suitable penalty parameter values have been provided by different authors, the objective of this paper has been to improve this procedure by including the penalty... 

Considering electronic skin applications, a pressure sensor based on periodic structure of graphene oxide-reduced graphene oxide (GO-rGO) has been designed and fabricated based on a low cost direct laser writing technique by utilizing the laser diode of DVD drive's pickup head. The optimization of sensor structure has been performed using computational modelling through Finite Element Method (FEM) in the COMSOL environment. The optimized structure is fabricated based on the deposition of thin layer of GO on the surface of Kapton and the pattering is performed by laser irradiation. The fabricated sensor structure has been characterized structurally and functionally. The results show that the... 

Multi-turn resolvers are proposed to be used in high accuracy, high-reliability applications that need to have the benefits of absolute measurement and high accuracy, simultaneously. In this paper, the influence of different arrangements of rotary transformer (RT) and resolvers' core on the accuracy of a multi-turn wound rotor (WR) resolver is discussed. Then, an optimal configuration with the aim of reducing the total cost, and the total volume of the sensor is proposed. All the analysis is done using 3-D time-variant finite element method (3-D TVFEM) and the optimal structure is built for experimental tests. Finally, experimental measurements are employed to verify the simulation results....