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    Modelling and Simulation of Heat Transfer in the Moicrowave Sintering Process of Uranium Dioxide

    , M.Sc. Thesis Sharif University of Technology Ahmadi, Mustafa (Author) ; Outokesh, Mohammad (Supervisor) ; Mousavian, Khalil (Supervisor)
    Abstract
    One of the steps in the production of nuclear fuel pellets used in the core of a nuclear reactor is sintering. Sintering means the consolidation of a pressed powder sample into an integrated solid. This process can be done in different ways, such as traditional sintering, microwave, spark plasma, etc. In the process of fabrication of nuclear fuel pellets, after producing uranium dioxide in powder form and making corrections on the size distribution of powder grains, it would be nolded and then sintered. In this research, the temperature evolution of the green pellets introduced to microwave heating were investigated. In this report, a brief overview of the principles of microwave heating is... 

    Simulation of Heat and Mass Balance in Rotary Kiln of Iron Pellets Induration

    , M.Sc. Thesis Sharif University of Technology Najafi, Alireza (Author) ; Yuzbashizadeh, Hossein (Supervisor)
    Abstract
    In this study, the heat and mass balance of rotary kiln of iron pellets induration was simulated. Due to large amount of heat transfer calculations, a quasi three-dimensional model has been used in this study. First, the freeboard heat condition was simulated via fluent program and the average temperature of freeboard was stablished. Then, a one-dimensional heat transfer model was developed using heat transfer equations. In this model, the heat transfer via conduction, convection and radiation in different parts of the kiln was included. Also, the bed reactions and their effect on bed temperature were evaluated. Finally, transversal movement and velocity of particles was studied. Transversal... 

    Fabrication of Nuclear Fuel Pellet With a Mixture of Micro and Nano UO2 Powders And Investigation of Its Physical and Mechanical Properties

    , M.Sc. Thesis Sharif University of Technology Karami, Mahdiyeh (Author) ; Otukesh, Mohammad (Supervisor) ; Taghizade, Mohammad (Supervisor) ; Roshanzamir, Manouchehr (Co-Advisor)
    Abstract
    Uranium dioxide (UO2) has been widely used as nuclear fuel in water cooled reactors since 1960s. UO¬2 is a refractory oxide with a melting point in excess of 28000C and therefore, requires high sintering temperature around 17000C in a hydrogen atmosphere for several hours. In the conventional method, the sintering is incorporated with indirect heating of green pellets in a refractory-type electrical resistance furnace. This furnace, however, uses a large number of expensive heating elements and refractory materials to achieve and maintain the high temperature for a long time. Moreover, it consumes much electrical energy and time. Since nanocrystalline materials contain a large fraction of... 

    Effect of Iron Ore Concentrate Morphology on Pellet Quality of Gol-e-Gohar Concentrate

    , Ph.D. Dissertation Sharif University of Technology Abazarpoor, Armin (Author) ; Halali, Mohammad (Supervisor)
    Abstract
    In this study, the effect of iron ore concentrate morphology on green pellet quality was studied. In order to produce concentrate with different morphology using ball mill, ball charge (20-40 %V), grinding time (30-50 min) and ball distribution (15 mm, 23 mm, 15+23 mm) was varied. It was deduced that increasing grinding time and ball charge would result in reduction of D80 but would increase Blaine number. The interaction parameters of ball distribution-grinding time and ball distribution-ball charge had significant effect on Blaine and D80. It was also observed that mixed level of ball distribution would lead to higher Blaine numbers. The equation obtained by CCD was verified by the... 

    The Feasibility of Decreasing FeO Index in the Final Product of Pellet Factory of Golgohar Mining and Industrial Company

    , M.Sc. Thesis Sharif University of Technology Memarian, Moein (Author) ; Askari, Masoud (Supervisor) ; Yoozbashizadeh, Hossein (Supervisor)
    Abstract
    As one of the most important agglomeration methods, pelletizing has a very important place in the iron and steel production chain. In the present study, the feasibility of improving FeO index in the final product of Pellet Factory No.1 of GolEGohar Mining and Industrial Company was investigated. The remaining FeO in the iron oxide pellet represents the amount of Magnetite that was not oxidized during the pelletizing process. The remaining FeO in the primary Magnetite is a disturbing structure for the direct reduction process and will cause a decrease in the compressive strength of the pellet (CCS) and as a result it will be crushed. Therefore, the percentage of the remaining FeO in the... 

    Synthesis and characterization of Al2O3-SiC nano composite by sol-gel method and the effect of tio2 on sintering

    , Article Journal of Nano Research ; Volume 13 , 2011 , Pages 7-19 ; 16625250 (ISSN) Rezaie, H. R ; Mohammad Rahimi, R ; Nemati, A ; Samadani, M ; Sharif University of Technology
    2011
    Abstract
    In the present article, α-Al2O3 nano powder was synthesized by a simple aqueous sol-gel method by using AlCl3 as precursor. It was shown that the gel calcined at 1000°C, 1100 °Cand 1200 °Cresulted in the formation of a crystalline ?-Al2O3 nano powder. In continue TEOS and saccharose was used to prepare SiO2 xerogels containing carbon nano particles. The conversion of the gel to β-SiC nano powders was accomplished by carbothermal reduction at 1500°Cfor 1 h in argon atmosphere. In second pace alumina matrix composites with nano particles of 5 vol% SiC were prepared with the addition of TiO 2 as sintering aid and densified by pressureless sintering method at 1600°Cand 1630°C for 2 h in nitrogen... 

    Spark plasma sintered YSZ gas electrode produced from powders synthesized by a large-scale method

    , Article Materials Chemistry and Physics ; Volume 289 , 2022 ; 02540584 (ISSN) Ghayoor, R ; Yousefi, M. H ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    Monitoring the oxygen in the fume and controlling its amount at high temperatures is an efficient way to regulate combustion efficiency. Zirconia can be an attractive candidate for use in oxygen sensors due to its good physical and chemical properties. The crystal structure of pure zirconia nanopowder due to the lack of cubic phase cannot be used for the fabrication of gas sensor electrodes. Moreover, the change of temperature during ceramic processing and application can promote structural and phase stresses. In this work, to achieve a pure cubic phase, yttria was successfully added to zirconia by a large-scale and effective method called Pechini. The yttria-stabilized zirconia nanopowders... 

    Simulation of thermal profile in a single pellet during drying process with CFD method

    , Article Proceedings of the 24th International Mining Congress of Turkey, IMCET 2015, 14 April 2015 through 17 April 2015 ; 2015 , Pages 797-803 ; 9786050107050 (ISBN) Gitiara, A ; Namehi, A ; Vali, H ; Shahrokhshahi, H. R ; Soltani, H ; Alamdari, E. K ; Cheraghi, A ; Karadeniz, M ; Gulsun Kilic, M ; Torun Bilgic, E ; Basarir, H ; Onel, O ; Sharif University of Technology
    TMMOB Maden Muhendisleri Odasi  2015
    Abstract
    Green iron oxide pellets are indurated with thermal treatment in pelletizing plant to achieve sufficient mechanical properties and to be used in iron-steel industry. In the first stage, the pellets are dried with hot air coming from the firing unit. High heat transfer makes the evaporation rate exceeding the outgoing steam rate from the pellets and as a result, increasing the inner pressure of the pellets and fragment. On the other hand, low heat transfer causes low production rate. Using the related equations and considering the pellets' moisture and porosity and applying the pellets' condition on parameters such as specific heat capacity and heat conductivity, an acceptable standard is... 

    Optimization of particle size and specific surface area of pellet feed in dry ball mill using central composite design

    , Article Indian Journal of Science and Technology ; Volume 9, Issue 44 , 2016 ; 09746846 (ISSN) Abazarpoor, A ; Halali, M ; Sharif University of Technology
    Indian Society for Education and Environment  2016
    Abstract
    Objective: The dimensional properties of iron ore pellet feed including specific surface area and particle size distribution in the ball mill was studied using response surface area method. Methods/Statistical analysis: The effect of the operational parameters of dry ball mill including ball charge (20-40%), grinding time (30-50 min) and balling distribution (Small, Mixed and Large) on dimensional properties of pellet feed was meticulously examined and optimized using response surface methodology based on Central Composite Design (CCD). Responses were 80% passing size (D80) and Blaine (BL). A total of 30 grinding experiments were designed and carried out in the CCD method. Regression models... 

    Numerical investigation of nonisothermal reduction of hematite using Syngas: The shaft scale study

    , Article Modelling and Simulation in Materials Science and Engineering ; Volume 15, Issue 5 , 2007 , Pages 487-507 ; 09650393 (ISSN) Valipour, M. S ; Saboohi, Y ; Sharif University of Technology
    2007
    Abstract
    A mathematical model is developed to investigate the reduction process of hematite in the reduction zone of the Midrex shaft furnace as a moving bed reactor. It is described as a counter-current moving bed cylindrical reactor in which hematite pellets are reduced by a gaseous mixture of hydrogen, water vapour, carbon dioxide and carbon monoxide, namely Syngas. It is laterally injected into the bed at the lower part close to the bottom. Governing equations, including continuity, momentum, energy and mass equations, are derived based on the conceptual model for both gas and solid phases in the cylindrical coordinate system. A three interface unreacted shrinking core model (USCM) is applied to... 

    Modeling hydrogen fluoride adsorption by sodium fluoride

    , Article Journal of Industrial and Engineering Chemistry ; Volume 16, Issue 6 , November , 2010 , Pages 978-985 ; 1226086X (ISSN) Afzal, S ; Rahimi, A ; Ehsani, M. R ; Tavakoli, H ; Sharif University of Technology
    2010
    Abstract
    In the current study, hydrogen fluoride (HF) adsorption onto the sodium fluoride pellets is modeled. For this purpose a two-dimensional, non-isothermal model was developed and the governing equations were solved numerically. The contributions of diffusion transport in axial and radial directions also were considered in mathematical formulations. The model results of effluent concentration and breakthrough curves of HF were compared with the experimental data obtained in a lab-scale adsorption unit, reported in our previous work [1]. The results indicate while the feed gas velocity decreases, the HF adsorption capacity on NaF is significantly enhanced and there is a delay in breakthrough... 

    Mathematical modeling of the reaction in an iron ore pellet using a mixture of hydrogen, water vapor, carbon monoxide and carbon dioxide: An isothermal study

    , Article Advanced Powder Technology ; Volume 17, Issue 3 , 2006 , Pages 277-295 ; 09218831 (ISSN) Valipour, M. S ; Motamed Hashemi, M. Y ; Saboohi, Y ; Sharif University of Technology
    VSP BV  2006
    Abstract
    A mathematical time-dependent and isothermal model based on the grain model has been developed to simulate the kinetic and thermal behaviors of a porous iron oxide pellet undergoing chemical reactions with a mixture of hydrogen, carbon monoxide, carbon dioxide and water vapor. Its novelty consists in fact that it can deal with a multi-species reducing gas and oxide pellet. In spite of previous models in which the pure reductant was applied as reducing gas, this model can indicate an actual view of pellet reduction including the effects of reducing gas utility and reducing gas ratio. A finite volume fully implicit technique was applied for solving the governing equations. The model has been... 

    Mathematical model for a straight grate iron ore pellet induration process of industrial scale

    , Article Computational Materials Science ; Volume 44, Issue 2 , December , 2008 , Pages 296-302 ; 09270256 (ISSN) Sadrnezhaad, K ; Ferdowsi, A ; Payab, H ; Sharif University of Technology
    2008
    Abstract
    A mathematical model is developed for induration of the iron-ore pellets in an industrial-scale plant based on the laws of mass, heat and momentum transfer. Physicochemical processes occurring during the induration of pellets such as drying of moisture, calcination of limestone and coke-magnetite reaction are considered to evaluate the gradient of temperature within the pellets. Differential equations describing transport phenomena in a grate bed are simultaneously solved by dividing the space in both x- and z- directions and numerically solving the phenomenological equations. A kinetic model is used for estimation of the change of the strength of the pellets due to firing. The model... 

    Investigation of iron ore particle size and shape on green pellet quality

    , Article Canadian Metallurgical Quarterly ; Volume 59, Issue 2 , 2020 , Pages 242-250 Abazarpoor, A ; Halali, M ; Hejazi, R ; Saghaeian, M ; Sheikh Zadeh, V ; Sharif University of Technology
    Taylor and Francis Ltd  2020
    Abstract
    Particle size and shape of iron ore concentrate are effective parameters in the production of quality green pellets. In this research, the effect of particle morphology on green pellet quality was studied. It was concluded that pellet quality improved with increasing specific surface area. Drop number and green compression strength of pellets ground by HPGR were found to be superior over those ground in the ball mill. The chief reasons were related to particle shape and the fraction of fine particles. Smaller particle size results in a higher order of bonding between particles and therefore the formation of a stronger system. Also, the rougher and less circular shape of particles resulted in... 

    HPGR effect on the particle size and shape of iron ore pellet feed using response surface methodology

    , Article Transactions of the Institutions of Mining and Metallurgy, Section C: Mineral Processing and Extractive Metallurgy ; 2017 , Pages 1-9 ; 03719553 (ISSN) Abazarpoor, A ; Halali, M ; Hejazi, R ; Saghaeian, M ; Sharif University of Technology
    Taylor and Francis Ltd  2017
    Abstract
    In this study the effect of HPGR operational parameters on the dimensional properties of pellet feed was examined and optimized using factorial methodology. The operational parameters considered include feed moisture, specific pressure and roll speed. For this study, size and shape of particles with Blaine number in the range 1800–2200 cm2 g−1 was thoroughly investigated. It was deduced that increasing the specific pressure and decreasing the roll speed would result in reduction of D80 but would increase the Blaine number. The circularity, aspect ratio and roughness descriptors of the particles were measured by SEM micrographs and image analysis software. It was observed that particles... 

    HPGR effect on the particle size and shape of iron ore pellet feed using response surface methodology

    , Article Mineral Processing and Extractive Metallurgy: Transactions of the Institute of Mining and Metallurgy ; Volume 127, Issue 1 , 2018 , Pages 40-48 ; 25726641 (ISSN) Abazarpoor, A ; Halali, M ; Hejazi, R ; Saghaeian, M ; Sharif University of Technology
    Taylor and Francis Ltd  2018
    Abstract
    In this study the effect of HPGR operational parameters on the dimensional properties of pellet feed was examined and optimized using factorial methodology. The operational parameters considered include feed moisture, specific pressure and roll speed. For this study, size and shape of particles with Blaine number in the range 1800–2200 cm2g−1 was thoroughly investigated. It was deduced that increasing the specific pressure and decreasing the roll speed would result in reduction of D80 but would increase the Blaine number. The circularity, aspect ratio and roughness descriptors of the particles were measured by SEM micrographs and image analysis software. It was observed that particles tended... 

    A non-isothermal, transient model of a non-catalytic reaction in a packed bed with a multi-component high-temperature gas mixture

    , Article 3rd M.I.T. Conference on Computational Fluid and Solid Mechanics, Boston, MA, 14 June 2005 through 17 June 2005 ; 2005 , Pages 1023-1025 ; 0080444814 (ISBN); 9780080444819 (ISBN) Valipour, M. S ; Saboohi, Y ; Sharif University of Technology
    2005
    Abstract
    A mathematical model has been developed to simulate heterogeneous reactions with a complex set of physicochemical and thermal phenomena in a packed bed. These include the chemical reaction itself, the transport of gaseous species in the pores, the generation or consumption of heat by the reactions, and the transport of heat in the porous domain. Solution of complicated sets of governing equations is based upon the concept of a finite volume fully implicit approach. The model has then been applied to analyze the reduction of a hematite pellet in a moving packed bed reactor. © 2005 Elsevier Ltd