Sharif Digital Repository

Noble metallic nanostructures based on their localized surface plasmon resonance (LSPR) exhibit a phenomenon known as surface-enhanced Raman scattering (SERS) in which the scattering cross sections are dramatically enhanced for molecules adsorbed thereon. The enhancement factor (EF) in typical cases can reach 106 and in recent years, it has been reported that even single-molecule spectroscopy is possible by SERS, suggesting that the EF can be as much as 1014-1015. In this study, we report a simple method to synthesize nanostructures of Ag and Au on metallic wafers and semiconductor via electroless deposition method. This approaches has been demonstrated to deposit metal nanostructures, thin... 

In this thesis periodic plasmonic nanostructures are studied for detection of biological specious. The behavior of metal nanostructure arrays under normal incidence has been widely reported. However, simulation of periodic dispersive structures under oblique incidence requires newer formulations. Formulations, and algorithms based on modified split-field finite-difference time-domain (SF-FDTD) method are introduced, permitting analysis of metallic nanostructures arrays under oblique incidence. These novel algorithms are practically implemented on a parallel processing system based on graphics processing unit (GPU). Test and verification of these formulations are done by analyzing referenced... 

In recent years, thin-film photovoltaic cells with thicknesses of less than 1-2 µm have been developed with potentially lower production costs. Due to the small thickness of the absorbing semiconductor in these cells, the absorption is inevitably low at energies close to the electronic band gap of the semiconductor. This is particularly a problem for thin-film devices. Recently، periodic metallic nanostructures supporting surface plasmons have been introduced as alternative solutions to achieve light trapping in thin-film solar cells.Full numerical methods are usually used for the analysis of these periodic structures. The main drawback of these methods is that they are time-consuming and... 

One of the different sensing techniques for biosensors is based on surface plasmon resonance which provides high reliability and efficiency. In this project working operating principles of biosensors based on surface plasmon resonance will be examined. For investigation of sensing meachanism we assume that there an array consisting of alternating graphen ribbons which by applying light leads to an effective magnetic field coupling to the localized surface plasmon. The numerical calculations are based on the exact solution of Maxwell's equation using Fuorier Model Method and Matlab coding. In these calculations, the coefficients of transmission, reflection and absorption of light versus... 

Due to the growing need for plasmonic wavs in microwave and terahertz spectra, a periodic arrangement of one-dimensional cut-through slits is investigated and an equivalent model based on the effective medium theory is derived. In contrast to the all previous attempts that were successful in mimicking only the zeroth-order diffracted waves, the proposed effective medium is capable of mimicking all diffraction orders. The parameters of the equivalent model are established by comparing the scattered waves of the semi-homogeneous medium and those of the main structure obtained by invoking the rigorous mode matching approach based on the single mode approximation inside the slits. This medium is... 

In this study, we simulated and analyzed a plasmonic waveguide modulator based on single layer graphene. It includes a graphene sheet, which sandwiches between two layers of silicon dioxide. Then, some gates are arranged on either side of the waveguide on a periodic structure. When an electric field is applied perpendicular to the waveguide plate, the Fermi level of graphene under the gates, changes. Detailed analysis is performed by the method of lines based on Maxwell's equations along the propagation direction of the waveguide. Computation of the multi-gate device starts by examining the effect of Fermi level. Transmission coefficient of the magnetic-field norms of the modulator is... 

In this thesis, we have investigated the plasmon dispersion on the Dirac matter. The Dirac matters which we consider to this end are graphene and borophene allotrope.The borophene allotrope has smaller anisotropic Fermi velocity and tilted Dirac cone in comparison with graphene. We briefly give a short introduction to these materials and then we study the propagation of electromagnetic modes in them. We begin with graphene as a well known two dimensional Dirac material. It has been found that two kinds of plasmon modes named as plasmon mode and transverse electric filed mode are allowed to propagate in graphene but just the plasmon mode can be affected by interaction. As the correlated... 

Ultrafast signal processing in time-domain with high resolution and reconfigura-bility is a challenging task. This paper, for the first time, introduces a time-varying metasurface consisting of graphene microribbon array for implementing time-lens in the terahertz domain. Given that the surface conductivity of graphene is proportional to the Fermi energy level in the THz regime, it is possible to change the phase property of the incident electromagnetic pulse by changing the Fermi level while the Fermi level itself is a function of voltage. Upon this fact, a quadratic temporal phase modulator, namely time-lens has been realized. This phase modulation is applied to the impinging signal in the... 

Carbon nanostructures are of great importance in scientific and industrial research. Two case of the important two-dimensional carbon nanostructures are graphitic carbon nitride (g-C3N4) and graphene. In the first part of this work, adsorption of important heavy metal cations including Hg+2, Ag+, Cr+3, Pb+2, Cu+2, Ni+2, Cd+2, Tl+, Sb+3, Zn+2 and As+3 on the surface of (g-C3N4) was investigated by density functional theory (DFT). The main purpose of this theoretical study is to evaluate the ability of g-C3N4 to adsorb pollutant cations. The most prominent result of this work was the ability of g-C3N4 for effective adsorption of As+3 and Sb+3 ions from aqeous solutions. Also, another... 

The main goal of this project is analysis, design and implementation of scanning near field optical system for detection of biological species. The activities fall in two main category. Theoretical and experimental. In theoretical part, after studying different models describing near field interaction, we have developed software for computationally analysis of nonlinear interaction of light with nanostructures, considering third order nonlinear susceptibility and dispersion behavior of permittivity for metallic nanostructures. The software implements three dimensional finite difference time domain (FDTD) method for analysis of interaction of electromagnetic wave with matter. In developed... 

Lipopolysaccharide (LPS), also known as endotoxin, is a highly toxic component exists in the outer membrane of gram negative bacteria. It releases into the environment during every phase of bacterial growth cycle, so it causes contamination of a wide range of biopharmaceutical products. Even small quantities of endotoxin injected to human body can result in fever, septic shock, and death. Therefore, it is highly important to detect and also quantify endotoxin of biopharmaceutical products in quality control laboratories. The most validated method used for endotoxin detection is Limulus Amebocyte Lysate (LAL). Although this method is sensitive, it has some unavoidable drawbacks such as highly... 

Detection of pentaerythritol tetranitrate (PETN) as an explosive has been of great interest because of public safety and military concerns. Here, we have presented a simple, selective and sensitive colorimetric method for direct detection of PETN. The gold nanoparticles (AuNPs) were first exposed to arginine which has primary amines in its structure. Primary amines from arginine as electron donors could strongly interact with electron deficient –NO2 group of PETN. Also, hydrogen bonding could happen between the –NO2 group of PETN and –NH2 group of arginine molecules. Therefore, selective aggregation of AuNPs happened because of the donor-acceptor and hydrogen bonding interactions. Due to the... 

Polymerase chain reaction method is a conventional method for obtaining multiple copies of a specified segment in the DNA molecule and to amplify the DNA molecule itself. Therefore, this method has been of paramount importance in different fields of research and has been applied for different applications. PCR requires thermal cycling, or repeated temperature changes between two or three discrete temperatures to amplify specific nucleic acid target sequences. To achieve such thermal cycling, conventional bench-top thermal cyclers generally use a metal heating block powered by Peltier elements or benefit from forced convection heat transfer. Although efforts have been made in order to reduce... 

In this project, we report on two waveguide structures suitable for implementing terahertz compact devices. First structure is composed of a periodic array of metallic blocks attached to a metal plate at the bottom. By integrating the metallic teeth in a silicon ridge and then evacuating the space between metal blocks, we enhanced the field confinement. At last by putting a metal plate over the structure at a proper distance in order to enhance the normal component of the electric field to the upper face of the metal blocks as main component of power transmission, in addition to even more field confinement, we isolated the structure from outside world. We assessed waveguidng properties of... 

Although digital computers have been developed enormously in recent years, analog computing is still of great importance in some specialized application. There are basically two different methods to perform analog computing: metasurface approach (MS) and Green’s function (GF) method. In this contribution, we have focused our attention to the second method. In this approach, the associated Green’s function of the operator of choice is directly performed using a multilayered slab. Despite the applicability of this method, there are two major drawbacks regarding it. The first one is that it is only feasible to perform operators whose Green’s functions have an odd symmetry in the spatial Fourier... 

Excitation of Localized Surface Plasmons, which is one of the features of the metal nanostructures, results in the confinement of light in the dimensions smaller than the incidence wavelength, and even lower than the fundamental diffraction limit. This property causes electric field enhancement at surface, helping the occurrence of Surface Enhanced Raman Scattering (SERS). The amount of electric field enhancement and its resonance frequency depend on the type of material, its geometrical properties and its shape, and the arrangement of the scattering particles. Also, properties of surrounding environment material and the type of the excited mode of the structure, and the incidence wave... 

The purpose of this thesis is construction of a characterization system, for plasmonic nanoparticles. plasmonic nanoparticles are metallic particles in nanometer scale, which can confine the electromagnetic field, in their induced electric dipole, in a wide range of frequency. This optical property lead to many applications such as, medicine cancer therapy, controlled releasing of drugs, solar cells and interconnections in integrated photonic circuits.Since, optical properties are the most important properties of plasmonic nanoparticles, we need a system to characterize them optically. There are different ways of optical characterization, which need a common tools, including light sources,... 

Due to its extensive applications in imaging, data security, medication, etc., Terahertz has attaracted an ever-inceasing attention. Design and implementation of Terahertz sources and circuits as waveguide, filters, etc. in this band have attracted attention. The unique elec-tric characteristics of graphene, like showing plasmonic characteristics in Terahertz frequency band, made this recently recognized matter a promising one to build super-integrated plas-monic circuits in Terahertz band. In this text, the first section represents an introduction for a number of graphene waveguides as well as studying the effective refractive index method to analyze graphene waveguides. Due to the small... 

Thus far numerous components and devices have been designed and realized based on plasmonics. Hereon, we focus on PlasMOStor which is probably the first and most important CMOS compatible plasmonic modulator. It resembles to its electronic counterpart MOS transistor in geometry, unless, it has a plasmonic waveguide instead of the regular channel to modulate optical signals . By applying voltage to the gate and inset of charge carrier accumulation, optical properties of the channel changes and plasMOStor turns off. In this thesis, we carry out a through investigation of plasMOStor’s operation. We show that the proposed theoretical description of plasMOStor is fallacious. Subsequently,... 

Achieving low group velocity of light can result progress in many fields. In this project by using complex time domain frequency, achieving method to zero group velocity is proposed. The proposed structures in this thesis consist of two lossless and lossy structures which by considering the modes with complex time frequency are excitable. Using leaky modes to analyze these structures, made them suitable as they can be excited from free space. Using slow light can lead to optimized devices because of the more interaction of light and matter which besides smaller devices too. Additionally slow light is being considered in designing optical memories, quantum computers, optical processors and...