Sharif Digital Repository

One of the most important operating parameters which affects the performance and efficiency of active solar stills is brine depth. In all of the previous experimental or theoretical studies, effects of water depth were investigated during only the first 24-hour period (or even shorter periods) of the operation of active solar stills. In other words, only the first day was taken into account. However, the production of an active solar still depends on several parameters such as brine temperature at sunrise (initial temperature), which are all affected by the depth variation after the first day of operation. However, the present research experimentally investigates the long-term effects of... 

Pricing for an insurance policy can be described as the process of calculation of expected compensation to be paid to property losers as well as associated costs of potential risks. Loss forecast is accurate if the risks will be identified appropriately in order to calculate the frequency and expected severity of losses.This is particularly important about environmental risks since most of them appear in the long run. Environmental risk assessment model is both able to estimate the environmental liability premium for environmental pollution and degradation, and it can play a valuable role in promoting this industry. ELIS (Environmental Liability Insurance) software calculates the... 

A novel solid-phase microextraction(SPME) fiber was prepared using sol-gel technology with ethoxylated nonylphenol as a fiber coating material. The fiber was employed to develop a headspace SPME-GC-MS method suitable for quantification of 13 polycyclic aromatic hydrocarbons (PAHs) in water samples. Surface characteristics of the fibers were inspected by energy dispersive X-ray (EDX) spectroscopy as well as by scanning electron microscopy (SEM). The SEM measurements showed the presence of highly porous nano-sized particles in the coating. Important parameters affecting the extraction efficiency such as extraction temperature and time, desorption conditions as well as ionic strength have been... 

Removal of zirconium from its dilute aqueous solution using Aspergillus niger as a dried and living biomass was investigated. Through that, the effect of some operational parameters on biosorption, including pH, temperature, contact time, initial concentration of zirconium and dose of biomass, were studied. Based on the results, it was concluded that the uptake of zirconium by both dried and living biomasses is pH dependent, and maximum uptake was observed in pH = 3.1 for both biomasses. The maximum uptake capacity of the living biomass was obtained at 30°C. However, the biosorption of zirconium by dried biomass was not affected by temperature. The maximum uptake capacity for living and... 

Global economic expansion and increasing concentration of people in the large cities, especially in developing countries leads to some environmental issues such as air pollution. Relocation of the firms as a great air pollutant can be an appropriate alternative for diminishing these pollutions. Yet, there is a lack of research about factors precluding firm relocation with respect to decision making factors when determining whether or not to relocate. Thus, the purpose of this case study is to examine firm relocation decision-making factors and to apprehend the role of environment issues in making them using a combination of SWOT matrix and Analytic Hierarchy Process (AHP). The combination... 

The fabrication of strong photocatalysts applied to the degradation of organic pollutants is necessary in environmental applications. In a single-stage method, acetate precursor and poly vinyl pyrolydine are used to produce ZnO nanostructures with various morphologies in annealing temperatures ranging from 300 °C to 900 oC. The physical properties of the prepared nanostructures were characterized by SEM, XRD and PL spectroscopy. The SEM images exhibit a variety of the as-prepared hexagonal zinc oxides including wires, rods, particles and porous network of welded particles of ZnO nanoparticles. The results of the photocatalytic degradation of methylene blue as an organic dye in aqueous... 

In this study, a laboratory-scale biotrickling filter (BTF) is used to remove Triethylamine (TEA) from gaseous wastes. The BTF is made of stainless steel with a height of 210 cm and an internal diameter of 21 cm packed with lava rocks. TEA elimination pattern was evaluated by changing empty bed residence times (EBRTs). The maximum elimination capacity (EC) has been determined to be 87 g/m3/h. At all EBRTs 52, 31, 20, and 10 s, contaminant transferring from gas phase to liquid was more than the EC. Also, the removal efficiency was 100 % for a mass loading of 100 g/m3/h. While the liquid recirculation velocity of 3.466 m3/m2/h was maintained, the flow rate was adjusted to 60, 100, 156, and 312... 

In this study the biodegradability of asphaltenes was investigated using four bacterial consortia isolated from oil contaminated soils and sludge. The species in consortium 1 were identified as Pseudomonas aeruginosa and Pseudomonas fluorescens. Consortium 2 contained Citrobacter amalonaticus and Enterobacter cloacae. Consortium 3 contained only one species identified as Staphylococcus hominis, and the species in consortium 4 were identified as Bacillus cereus, and Lysinibacillus fusiformis. Spectrophotometry at 281 nm wavelength was applied to quantify asphaltenes biodegradation. The biodegradation tests were performed in flasks with the initial asphaltenes concentrations of 2, 4, 10, 20,... 

By new advancements in vehicle manufacturing, evaluation of vehicle quality assurance has got a more critical issue. Today noise and vibration generated inside and outside the vehicles are more important factors for customers than before. So far several researchers have focused on interior noise transfer path analysis and the results have been published in related papers but each method has its own limitations. In present work, the vibration transfer path analysis and vibration path ranking of a car interior have been performed. As interior vibration is a source of structural borne noise problem, thus, the results of this research can be used to present the structural borne noise state in a... 

A high-temperature-resisant solid-phase microextraction (SPME) fiber was prepared based on polyetherimide (PEI) by the electrospinning method. The PEI polymeric solution was converted to nanofibers using high voltages and directly coated on a stainless steel SPME needle. The scanning electron microscopy images of PEI coating showed fibers with diameter range of 500-650 nm with a homogeneous and smooth surface morphology. The SPME nanofibers coating was optimized for PEI percentage, electrospinning voltage, and time. The extraction efficiency of the coating was investigated for headspace SPME of some environmentally important polycyclic aromatic hydrocarbons from aqueous samples followed by... 

Combustion emission is one of the most important issues in the design of industries. Todays' strict environmental standards have limited the productions of CO, NOx, SOx, and other hazardous pollutants from the related industries. In this work, we study a typical oil refinery incinerator, which is used to burn waste gases residue produced during bitumen production process. The waste gas mainly includes a mixture including N2, H2O-vapor, and O2 species. Additionally, there are significant amounts of CO species and CxHy droplets in the waste gas composition. The measurements show that the CO emission becomes so crucial in high flow rate of feeding waste gas to the incinerator. Here, we... 

In advanced combined-cycle power plants, significant improvements in the thermodynamic performance are mainly achieved by the development of more efficient gas-turbine systems. This paper evaluates the effect of selected decision variables in the steam system for optimization of Thermal Combined Cycle Gas Turbine (TCCGT) power plant using an iterative exergoeconomic. The design variables were the thermodynamic parameters that establish the configuration both of the steam and gas systems. The design data of an existing plant (Damavand power plant in Tehran-Iran) is used. Two different objective functions are proposed: one minimizes the total cost of production per unit of output, and the... 

A methodology was developed to project total vehicular emissions from different emission reduction policies for the light-duty vehicles in the roads network of Tehran, Iran. A road-link-based model was constructed based on a bottom-up approach by coupling COPERT emission functions with the travel demand model of EMME/2. Results showed total emission from the studied network was largely impacted by vehicles' technology and age, speeds in the links, and fuel type. The proper transportation management to reduce the part of passenger cars and improve traffic flow also leads to a significant drop in the emission, e.g., emission decreased by 43% from 20% traffic volume reduction. Results indicated... 

The present work deals with a novel approach for grafting a sol-gel based sorbent, using diazonium salts for preparation of an unbreakable capillary microextraction (CME) device in on-line combination with high performance liquid chromatography (HPLC). The use of diazonium salts modifier allowed all types of metallic and non-metallic substrates to be used without any limitation. Substrates including copper, brass, stainless steel and polytetrafluoroethylene (PTFE) were chosen to be functionalized by chemical or electrochemical reduction of 4-amino phenyl acetic acid. Then, 3-(trimethoxysilyl)propylamine (3TMSPA) was selected as the precursor and the only reagent for preparation of the... 

Phenol is one of the aromatic hydrocarbons. Phenol and its derivatives are highly toxic. These pollutants can be observed in the effluents of many industries. This research investigates the removal of phenol by the use of activated sludge in a batch system. The effects of influencing factors on biodegradation efficiency have been evaluated. The main factors considered in this study were the volume of acclimatized activated sludge inoculation, pH, temperature, and initial concentration of phenol. The inoculation volumes of 1, 3, and 5 mL of acclimatized activated sludge were taken into account. Different pH values of 3, 5, 7, 9, and 11 were examined. The experiments were conducted for... 

A number of challenges including instability, nonconvergence, nonuniqueness, nonoptimality, and lack of a general guideline for inverse modelling have limited the application of automatic calibration by generic inversion codes in solving the saltwater intrusion problem in real-world cases. A systematic parameter selection procedure for the selection of a small number of independent parameters is applied to a real case of saltwater intrusion in a small island aquifer system in the semiarid region of the Persian Gulf. The methodology aims at reducing parameter nonuniqueness and uncertainty and the time spent on inverse modelling computations. Subsequent to the automatic calibration of the... 

Reduction of air pollutants formation from hydrocarbon combustion process requires improvements in combustion systems. The moderate and intense low oxygen dilution (MILD) combustion technique is an opportunity to achieve such a goal. MILD combustion is a combustion regime which can be attained by high temperature preheating and high level dilution. In this paper, the mechanism of CO and CO2 formation for a CH4/H2 fuel mixture is studied under MILD combustion condition of a jet in hot coflow (JHC) burner. This investigation is done using the computational fluid dynamics (CFD) and also zero dimensional well-stirred reactor (WSR) analysis. The RANS equations with modified k-ε equations are... 

The present study was conducted to investigate the impacts of retrofitted CNG vehicles on air pollutant emissions in Tehran over a 20 years period using available statistical data, precise automobile tests, data analysis, and LEAP Software. The obtained results revealed an increase in air pollutant emissions including CO (equal to 1030.77 thousand tons), NOx (equal to 1030.77 thousand tons), THC (269.02 thousand tons) and CO2 (equal to 38.43 thousand tons) resulting from utilizing retrofitted CNG vehicles within the studied period. Considering the obtained results, if the current trend of producing retrofitted CNG vehicles continues, a total cost of 435 million USD will impose on the... 

A novel high-throughput device based on 96-micro-solid phase extraction (96-μ-SPE) system was constructed for multiresidue determination of nine pesticides in aquatic samples. The extraction procedure was performed on a commercially available 96-well plate system. The extraction module consisted of 96 pieces of 1cm×3cm of cylindrically shaped stainless steel meshes. The prepared meshes were fixed in a home-made polytetrafluoroethylene-based constructed ninety-six holes block for possible simultaneous immersion of meshes into the center of individual wells. Dodecyl methacrylate and ethylene glycol dimethacrylate was copolymerized as a monolithic polymer and placed in the cylindrically shaped... 

The origins and evolution of the Middle Eastern dust storms which frequently impact the residents of this arid region were studied. A methodology was adapted and developed to identify the desert regions of potential dust sources and determine their contributions to PM10 concentrations in the highly-populated receptor city of Tehran, Iran. Initially, the episodes of regional dust intrusion and the resulting amounts of increase in the particulate concentrations during these episodes were determined using a statistical analyzing methodology. The dust episodes were also inspected with the aerosol index information from the Ozone Monitoring Instrument (OMI). The Hybrid Single-Particle Lagrangian...