Sharif Digital Repository

In the industry, there are nonlinear processes that can not be controlled with classical methods. Also, there are many processes that are more than one controlled variable that with classical methods, the design of a multiple input - multiple output controler is very difficult for them as well as the constraints on the inputs and outputs of the process exist, using classical controllers will be far more difficult. A model-based predictive control method for controlling nonlinear processes is useful in addition to having very high efficiency, extended to multi-mode interference together with constraints on the control variables and other controlled Problem with dynamic properties such as... 

The purpose of this study is the implementation of multi-model predictive control (MMPC) approach for the co-polymerization system of methyl methacrylate - vinyl acetate. Simpler development of local models and controllers and also convenience of understanding the model and controller structure are the main reasons for using this approach. In the first step, RGA analysis has been used for pairing input and output variables. Then the performance of PI controller on the system has been investigated. For designing model predictive controller (MPC) the nonlinear model has been linearized at operational point and the controller has been designed in MPC toolbox of MATLAB software R2013a. In the... 

In industries there are many nonlinear processes which cannot be easily controlled with classical methods. Model predictive control is a useful method for nonlinear processes which not only has high efficiency, but also extension of this control to interferential multi variable case, with constraint on the controlled and manipulated variables and other problematic dynamic specifications such as slow dynamics and inverse response is very simple. Industrial polymerization processes are regarded as significant nonlinear processes. Optimization and control of polymerization reactors have considerable importance in process applicability and in economics. The molecular structure of polymer such as... 

Nonlinear nature of polymerization reactors has always attracted great attentions in various scientific areas such as modeling, simulation, dynamical behavior investigation and control engineering as well. Free radical polymerization in continuous reactors, whether in terms of design and startup or in terms of economical concerns, has numerous fans in industrial aspects. In the following thesis, the dynamical behavior of continuous stirred tank reactor of Vinyl Acetate free radical polymerization is examined in an industrial scale. A control system with optimum performance is designed for this CSTR as well. According to the common behavior of this type of reactor, it may demonstrate... 

In this thesis, ionic liquids and polymeric ionic liquids were investigated as solvent and support for immobilization of molybdenum and palladium catalysts. Three newly synthesized room temperature ionic liquids containing molybdate anion, [DMIm][MoO2(NCS)4], [RPy][MoO2(NCS)4] (R = butyl or decyl), and previously reported [BMIm][MoO2(NCS)4] were used as catalysts for the reduction of sulfoxides. For facilitating the recyclability of the catalysts, the ionic liquid solvents, [RMIm][PF6] and [RPy][PF6] (RMIm=1-n-alkyl-3-methylimidazolium, RPy= 1-n-alkylpyridinium), were applied to immobilize molybdenum catalysts. These catalysts showed high catalytic activity for sulfoxide reduction in this... 

Novel electrospun nanofibers and their applications as the microextractionsorbents are the centre of this research. Polymeric nanofibers with diameter in the scale of nano-to-micro were prepared by the electrospinning method and employed for microextraction purposes. Two major microextraction methods included solid phase microextraction (SPME) and micro-Solid phase extraction (µ-SPE). In the first work, a novel SPME fiber was fabricated by electrospinning method. A thin stainless steel wire was coated by the network of polymeric nanofibers. The polymeric nanofiber coating on the wire was mechanically stable due to the fine and continuous nanofibers formation around the wire with a three... 

Dissipative particle dynamics (DPD) is an emerging mesoscopic computational method in which the interparticle forces arise because of coarse-graining at the molecular level. In the asymptotic limit of large length scales, the governing equations of continuum are reproduced, as demonstrated in this work. This method of simulation has the capability of simulating larger order of time and space in compare with dynamic molecular method. One of the important applications of DPD is simulating the dilute polymer solution. In this project, we developed a general code to simulate dilute polymer behavior which consists of polymeric forces and different types of usual DPD boundary conditions. This code... 

The main object of this thesis is synthesizing poly(vinyl acetate)/ colloidal silica nanocomposites via emulsion and in-situ polymerization methods. At the first, nanocomposites were produced in the presence of poly(vinyl alcohol) as the protective colloid, ammonium persulphate as the initiator and sodium bicarbonate as the buffer in an aqueous solution. Then, structural, thermal, rheological, mechanical and surface properties of produced nanocomposites with various colloidal silica content (0.5 %, 1 %, 1.5 %) were evaluated by DLS, FTIR, SEM-EDS, DSC, TGA, dynamic and steady rheological tests, tensile and shear mechanical tests, AFM and static water contact angle. The particle size of... 

As the reservoir matures, especially in fractured reservoirs, oil production is usually accompanied by the production of some unwanted water. Water production causes environmental problems and imposes high costs on the production system, including the cost of separating water and oil, corrosion of facility, and sometimes, leading to abandoning well. One way to solve this problem is to use gels as a blocking agent. Today, preformed particle gels are used as an alternative to in situ gels, which can solve some issues of in-situ gels, such as uncertainty in gelling time and penetration depth.This research comprises three main parts. In the first part, four samples of preformed particle gels... 

Suspension polymerization is an important industrial process. Product of this process is particulate polymers that have a widely use in human lives. An important property of suspension polymerization process is the particle size distribution (PSD), which affects the end-use properties of the products. Therefore, the evolution of PSD is a major concern in the design of a suspension polymerization process. In a suspension polymerization reactor the evaluation of particle size distribution is the result of the interaction of the mixing conditions and the kinetics of the polymerization reactions. Mathematical modeling of particle size distribution in suspension polymerization processes should... 

Nowadays, regarding the wide achievements in micro scale technology, it is possible to manufacture a micro robot. Micro swimmer have extensive applications in different fields especially in medical sciences. One of the most important problems of the micro robot is their propulsion system. The locomotion of microorganisms in fluids is ubiquitous and plays an important role in numerous biological processes. The physics of swimming governing life under the microscope is very different from the one we experience in the macroscopic world. This project is aimed at designing a propulsion system for a micro swimmer based on the swimming mechanism of the eukaryotic Spermatozoa. Simplicity to build is... 

In this project, inverse emulsion polymerization (IEP) modeling of poly acrylamid (PAM) using population balance equations (PBEs) has been performed. For this porpuse zero-one and pseudo- bulk models and hybrid model including the zero-one and pseudo- bulk are applied based on the process conditions. The effects of surfactant steric barrier and surfactant reaction with radicals including monomeric radicals on the radical entry rate into the particle have been taken into account for these models. In the modeling, coagulation phenomenon was included by considering the effects of non-DLVO forces such as hydration and steric forces in addition to the DLVO forces. Simulation results for zero-... 

In this thesis, heterogenous catalysts based on magnetic nanoparticles coated with organosilanes and poly(ionic liquids) were synthesized. These catalysts were synthesized by hydrolysis of tetraethyl organosilanes and other organosilicons such as 3-aminopropyl triethoxy silane and polymerization of some monomers in the presence of ionic cross-link agents. The synthesized matrixes were used to stabilize precious metals such as Pd and Au. The magnetic properties of the catalysts aid to easy separation from the reaction medium by an external magnetic field. High thermal stability low toxicity and high-level loading of metals are some beneficiaries of the magnetic catalysts. At the end,... 

In this thesis, it reports the fabrication of novel magnetic nanocomposites combining the unique properties of magnetic nanoparticles and cross-linked basic polymers that their surface functionalized by suitable groups such as carboxylate groups, pentaethylenehexamine and so on to achieve the maximum adsorption capacity of dyes and heavy metal ions. The performance of the magnetic nanocomposites for removal of anionic and cationic dyes and heavy metal ions were evaluated in different conditions of pH, contact time and initial concentrations. Moreover, the adsorption mechanism was investigated by kinetic models and isotherm studies. The results showed that the abovementioned adsorbents can... 

During the over balanced drilling operation in high permeability or fractured formations, drilling fluid loss and in more severe occasions fluid lost occurs which causes many problems and dangers and delayed the drilling operation until it was repaired. On the one hand, because of the high value of this material, and on the other hand, due to the increase in rig/day costs resulting from lost circulation control, leads to a significant increase in drilling costs. In this research, polymer-fiber composites have been designed and manufactured using extrusion method and have been investigated as fluid lost control agent in the laboratory scale for the first time in Iran. The effective parameters... 

In the present study we examined the fabrication of electrospun polymer drug delivery system for the production of polymeric film containing Rizatriptan drug. Fabricated films were underwent X-ray diffraction and DSC tests to ensure that the drug is not in crystalline and amorphous form. And the results revealed the fact that the drug is fully dispersed in the polymer. pH changes in the aqueous phase is too low so that it enable the polymeric film to be suitable for use in oral administration. In-vitro assay for different combination of sublingual polymeric suggested that Rizatriptan film with 3% weight by volume and 30% by weight by volume of electrospun polymer PVP is the best combination... 

Systems composed of electrical and mechanical elements in micrometer scale are called microelectromechanical systems which are commonly fabricated on silicon substrates. These systems are in connection with environment by the means of sensors and actuators. Thermal microactuators as one of the most applicable actuators produce force and displacement on the basis of thermal expansion.Recently, by the advent of some polymers compatible with microfabrication methods such as SU8 and due to their remarkable thermal properties,polymeric thermal microactuators are attracting more attention in a way that polymeric type of almost every predesigned thermal microactuators are fabricated and much... 

In this research application of Ionic Polymer Metal Composite (IPMC) as actuator in a deformable ring capable of locomotion is studied. Such a deformable ring moves as a result of gravitational force acting on its body when its shape changes. A deformable robot made of IPMC can be used in exploration, search and rescue missions in future, where using conventional robots with rigid bodies and actuators is impossible. Large deformation induced by small stimulating voltage, low stiffness and the sensing characteristics that in future work can be used in feedback control make IPMC a good choice for such an application. In this work first a model for IPMC is introduce that can be used in... 

This thesis focuses on modeling, simulation and control of bulk polymerization of styrene in an autorefrigerated reactor where the generated heat is removed by heat of vaporization of the monomer. By means of two mathematical models for the kinetics of reaction, static and dynamic simulations were performed. For this purpose the equilibrium points were calculated using the steady state analysis, and then the reactor temperature was controlled at the unstable point using PI and adaptive generalized predictive controller (AGPC). In order to implement the GPC scheme a process model is required to provide the process output estimate over the prediction horizon. For this purpose an auto... 

In this work, a comprehensive dynamic model has been used for vinyl acetate emulsion polymerization in a continuous reactor to predict the evolution of product particle size distribution under isothermal condition. Method of finite-volume has been applied for solving the population balance equations and the results are compared with the results obtained from moment method. Finite-volume method has been selected as a precise technique to predict sustained oscillations, which occurs in continuous emulsion polymerization. After performing sensitivity analysis and verification of system’s controllability, feed rate of surfactant and initiator have been selected as proper manipulated variables to...