Sharif Digital Repository

In this study, titanium substrates which previously oxidized through Micro arc oxidation method, was coated by Hydroxyapatite (HAp) coating once more by means of the same method. Morphology, topography and chemical properties as well as phase composition and thickness of layers were studied to reveal the effect of the electrolyte concentration on coating features. According to results, the obtained coatings are consisted of HAp and titania as the major phases along with minor amounts of calcium titanate and α-tri calcium phosphate. Ca and P are present on surface of obtained layers as well as predictable Ti and O based on the XPS results. Thickness profile of coatings figured out that by... 

To attain superior energy density concurrently with high power density, high-performance supercapacitors have been developed. Herein an innovative strategy has been adopted to fabricate unique binder-free electrodes composed of a unique porous structure of binary metal carbonate hydroxide nanomace-decorated hydrothermal porous carbon spheres (PCSs). Hierarchical nickel-cobalt carbonate hydroxide (NiCOCH) nanomaces, directly grown on PCSs, are used as positive electrodes for supercapacitors fabrication. Furthermore, Fe2O3@PCS composites, having benefits of highly reversible redox reaction in the negative potential window and highly porous structure, are employed as the negative electrode in... 

To attain superior energy density concurrently with high power density, high-performance supercapacitors have been developed. Herein an innovative strategy has been adopted to fabricate unique binder-free electrodes composed of a unique porous structure of binary metal carbonate hydroxide nanomace-decorated hydrothermal porous carbon spheres (PCSs). Hierarchical nickel-cobalt carbonate hydroxide (NiCOCH) nanomaces, directly grown on PCSs, are used as positive electrodes for supercapacitors fabrication. Furthermore, Fe2O3@PCS composites, having benefits of highly reversible redox reaction in the negative potential window and highly porous structure, are employed as the negative electrode in... 

Thanks to a wide range of pore sizes by nano/macro composites of SiOC/Al2O3, such composites can serve as different layers of the structure of Packed Bed Reactor Membranes (PBRM). In the present study, the Polymer-Derived Ceramics method (PDC) has been used to synthesize nano/macro structures. Firstly, the effect of toluene as an extra carbon source on structure and microstructure of SiOC glass-ceramics was evaluated, such that, 4% (Vol) toluene was recognized as the proper amount to facilitate the synthesis of β-SiC at 1300 °C proved by XRD, Raman spectroscopy, and HR-TEM. Moreover, the presence of micro/meso-porosities was assessed by BET and TEM, indicating the capability of SiOC to serve... 

Nanofiber layers have exciting properties such as fine fiber diameter, small pores, suitable connectivity between pores, high surface area and high porosity. These properties make nanofibers applicable for a variety of applications, such as high-performance filters and tissue engineering scaffolds. Different applications of electrospinning layers require different porosities. Therefore, it is very important to measure the porosity of nanofiber layers to express their application. To date, many methods have been expressed for this purpose, but all methods have disadvantages. Therefore, finding the best method is a challenge that will be addressed in this project. © 2022 The Author  

This study concentrated on the formulation of self-flowing and an energy efficient lightweight aggregate foamed concrete (LAFC) to be employed as thermal insulation, thermal mass and structural material. Low density concrete mixtures (for the density values from 800 to 1300 kg/m3) were prepared by changing the volume of lightweight expanded clay aggregate (ECA) from 49.4% to 20.1%. Flowing properties of concrete mixtures were improved with the help of stable foam. Ordinary Portland cement (OPC) was replaced by the 5% and 10% silica fume (SF) to examine the influence of SF on the properties of LAFC. Compressive strength and tensile strength of LAFC mixtures were respectively enhanced from 6.5... 

This work addresses the preparation of self-flowing lightweight aggregate foamed concrete (LAFC) resulting from the mixing of stable foam, expanded clay aggregate (ECA) and silica fume (SF) as main raw materials. Formulated LAFC mixtures were tested for the mechanical, thermal, sorption and high-temperature resistance properties. Results showed that the increase in the volume of foam from 0% to 20% considerably improved the flowability of LAFC and LAFC mixtures were categorized into high stable visual stability index. Compressive strength of LAFC mixtures was reduced from 24.75 MPa to 21.10, 15.95 and 12.05 MPa respectively when foam volume was increased from 0% to 10, 15 and 20%. Thermal... 

This study investigated the influence of ultrafine fly ash (FA) on the mechanical properties, elevated temperature resistance and water stability of basalt fiber reinforced magnesium phosphate cement, and synergy mechanism was examined with the help of X-ray diffraction (XRD), thermogravimetric analysis (TGA), mercury intrusion porosimeter (MIP) and scanning electron microscopy energy dispersive spectroscopy (SEM/SEM-EDS) analysis techniques. Experimental results showed that incorporation of FA improved the mechanical properties, temperature resistance and water stability of MPC composites. TGA results exhibited that the mass loss of MPC composites was gradually reduced by increasing the... 

This paper presents a novel method for fabrication of bone-like Ti6Al4V foamy core@compact shell composite for utilization as substitutive implant for cortical bone having porous core. Seven prototypes with core-diameters of 0, 6, 8, 10, 12, 14 and 16 mm surrounded by dense shells of respective thicknesses 8, 5, 4, 3, 2, 1 and 0 were produced by an innovative two-stage packing/compaction sintering method. Density, porosity, Young's modulus and compression strength of the prototypes depended on the core diameter. Mechanical strength and Young's modulus of 10@16 (10 mm core, 16 mm diameter prototypes) resembled that of the human ulna bone. Creation of foam at the center was achieved by... 

A simple and efficient method was developed for fabricating spherical granules of CuO catalyst via a three-step procedure. In the first step, copper oxide nanoparticles were synthesized by hydrothermal decomposition of copper nitrate solution under supercritical condition. Then, they were immobilized in the polymeric matrix of calcium alginate, and followed by high-temperature calcination in an air stream as the third step, in which carbonaceous materials were oxidized, to result in a pebble-type catalyst of high porosity. The produced CuO nanoparticles were characterized by transmission electron microscopy (TEM) that revealed an average size of 5 nm, X-ray diffractometry (XRD), and thermo... 

Metallic foams are a class of lightweight materials that show high potentials for different industrial applications such as automotive and aerospace engineering. However, many factors have prevented metallic foams from being fully utilized in industrial applications. One main factor is that the influences of the porous structure on the mechanical properties of metallic foams are not well known yet. In this paper, a finite element model was used to analyze monodisperse closed cell aluminum foam in order to determine the relationship between its elastic modulus, porosity and pore diameter. A nonlinear relationship was found between the foams porosity, pore diameter and modulus of elasticity.... 

Monodisperse closed cell aluminum foam was analyzed numerically to determine the relationship between its elastic modulus, porosity and pore diameter. It was found a nonlinear relationship exists between porosity, pore diameter and modulus of elasticity. In this regard, an empirical equation is developed and implemented for the prediction of modulus of elasticity versus porosity and pore diameter. Comparing experimental and analytical approaches by other researchers with those obtained in this research shows agreement exists within 1 to 3 percent  

In the present study, a magnetic core-shell metal-organic framework (Fe3O4@PAA@UiO-66-NH2) nanocomposite was synthesized by a facile step-by-step self-assembly technique and used for selective adsorption of the anti-cancer Quercetin (QCT) drug. The synthesized nanocomposite was well characterized using FTIR, XRD, BET, FESEM, and TEM techniques. The adsorption kinetics and isotherms of the magnetic nanocomposites for QCT were investigated in detail at different initial concentrations and temperatures. It was found that the experimental adsorption kinetic and isotherm data were precisely explained by the pseudo-second-order kinetic and Langmuir isotherm models. Moreover, the selective... 

In the present study, a magnetic core-shell metal-organic framework (Fe3O4@PAA@UiO-66-NH2) nanocomposite was synthesized by a facile step-by-step self-assembly technique and used for selective adsorption of the anti-cancer Quercetin (QCT) drug. The synthesized nanocomposite was well characterized using FTIR, XRD, BET, FESEM, and TEM techniques. The adsorption kinetics and isotherms of the magnetic nanocomposites for QCT were investigated in detail at different initial concentrations and temperatures. It was found that the experimental adsorption kinetic and isotherm data were precisely explained by the pseudo-second-order kinetic and Langmuir isotherm models. Moreover, the selective... 

Characterizing the electrical resistance of the formation rock is of great importance in, for example, interpreting the well log data, calculating the porosity, and water saturation for the formation rocks. The relation between the resistivity factor and porosity and also between the resistivity index and water saturation (Archie equation) in the formation rock uses the parameters, such as the cementation factor and saturation exponent. However, the direct application of Archie equation to carbonate rocks that are very heterogeneous and mostly oil-wet needs further investigation. In this experimental work, the effects of overburden pressure, temperature, and interfacial tension on the... 

We produced bifurcated bone-like shape memory implant (BL-SMI) with desirable tooth-root fixation capability by compact-sintering of TiH2–Ni-urea mixture. The primary constituents of the porous product were Ni and Ti. We could adjust the pores' shape, size, and interconnectivity for favorite bone ingrowth by using urea as a space holder. Without urea, we obtained an average porosity of 0.30, and a mean void size of 100 μm. With 70 vol % urea, we got 62% interconnected pores of 400 μm average size. Aging allowed us to tune the austenite-martensite transformation temperatures towards the needed body tissue arouse. Differential scanning calorimetry measured the transformation temperatures.... 

Stochastic parameters of self-agglomerated metallic nanoparticles on a dielectric film surface were studied using atomic force microscopy (AFM) analysis. In this regard, the rough surfaces including the nanoparticles were analyzed and characterized using structure function, roughness exponent and power spectrum density of the AFM profiles and their gradients, for different metal concentrations and heat treatment temperatures. The diffusion parameters, such as activation energy, of the nanoparticles initially accumulated on the surface into a porous and aqueous silica thin film were obtained using the AFM spectral analysis of the profiles and their gradients. It was found that the tip... 

Carbonaceous materials (CMs) have been applied extensively for enhancing the catalytic performance of environmental catalysts, however, the self-catalytic mechanism of CMs for groundwater remediation is rarely investigated. Herein, we unveiled the catalytic ability of various CMs via Fe(III) reduction through polyvinyl alcohol-coated calcium peroxide nanoparticles (PVA@nCP) for trichloroethylene (TCE) removal. Among selected CMs (graphite (G), biochar (BC) and activated carbon (AC)), BC and AC showed enhancement of TCE removal of 89% and 98% via both adsorption and catalytic degradation. BET and SEM analyses showed a higher adsorption capacity of AC (27.8%) than others. The generation of... 

Carbonaceous materials (CMs) have been applied extensively for enhancing the catalytic performance of environmental catalysts, however, the self-catalytic mechanism of CMs for groundwater remediation is rarely investigated. Herein, we unveiled the catalytic ability of various CMs via Fe(III) reduction through polyvinyl alcohol-coated calcium peroxide nanoparticles (PVA@nCP) for trichloroethylene (TCE) removal. Among selected CMs (graphite (G), biochar (BC) and activated carbon (AC)), BC and AC showed enhancement of TCE removal of 89% and 98% via both adsorption and catalytic degradation. BET and SEM analyses showed a higher adsorption capacity of AC (27.8%) than others. The generation of... 

A study has been carried out of the effect of plasma electrolytic oxidation (PEO)on the strength of AA 5052 alloy/polypropylene joints prepared using friction stir spot welding (FSSW). The joint strengths were determined using lap-shear tests and failure modes were investigated using scanning electron microscopy. Comparisons were made between control joints prepared with the alloy in the as-rolled condition or the as-rolled condition with a mechanical key and with PEO-treated alloy, with or without a mechanical key. Mechanical keying alone, provided by infiltration of polymer into holes of either 3 or 4.5 mm diameter drilled in the alloy, yielded enhancements of the joint strength by a...