Sharif Digital Repository

The hydrogenation of carbon dioxide to methanol represents a promising route for the efficient use of an anthropogenic greenhouse gas, in which catalysts play a key role in carbon dioxide conversion and methanol selectivity. In this study, firstly, CuO-ZnO-Al2O3, CuO-ZnO-ZrO2, CuO-ZnO-ZrO2-Al2O3, CuO-ZnO-Al2O3-CeO2 and CuO-ZnO-ZrO2-CeO2 catalysts were made using co-precipitation method, then these catalysts were characterized by inductively coupled plasma optical emission spectrometry, specific surface area and pore size distribution, X-ray diffraction, Field Emission Scanning Electron Microscopy, temperature programmed reduction. Finally, in order to compare the performance of the catalysts... 

Asphaltene deposition on reservoir rocks occurs during natural depletion as well as miscible injection processes. It causes reduction of effective pore space and consequent impairment of the ability of oil to flow through reservoir. Therefore, deposition of asphaltene causes significant formation damage and wellbore plugging, requiring expensive and difficult cleanup procedures. Thus it is necessary to be able to consider the onset, amount of deposition and also consequent damage of permeability and porosity reduction due to various factors. The objective of current work is to conduct experimental and simulation study of asphaltene deposition dynamics in one of the Iranian reservoirs. In... 

Thermodynamic modeling is a useful method for predicting of asphaltene precipitation due to various reasons, such as CO2 injection, mixing of different oils in oil storage and pressure changes. However, the application of solid model and thermodynamic micellization model, for prediction of asphaltene precipitation under gas injection condition, hasnot been improved. In this work, two computer codes which are based on two different asphaltene precipitation thermodynamic models, 1-Thermodynamic Micellization Model and 2- Solid Model, have been developed, and, used for predicting of asphaltene precipitation data reported in the literature as well as the experimental data obtained from high... 

ZnFe2O4 nanoparticles have been successfully prepared through a controlled microwave–assisted co-precipitation as well as conventional co-precipitation. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) and vibrating sample magnetometer (VSM) were used for the structural, morphological and magnetic investigation of the product. Average particle size was obtained as 12 nm from XRD. Catalytic activity of ZnFe2O4 nanopowder for O-acylation of alcohol and phenol has been investigated. A trace amount of ZnFe2O4 has been effectively used as a nanocatalyst for the acylation of alcohol and phenol in acetic anhydride.

 

The manufacture of ultra high strength materials has always been a target for aerospace and transportation industries. Currently, the limitation of energy resources even makes this goal more serious. Nowadays, more than 50% of total extrusion products are made from Al alloys and around 90% of them are the 6000 series alloys. Therefore, regarding to high strength, low weight, and hardening aluminum AA6000 alloys capabilities can play a major role in fulfilling this task. Over the last decade, a number of techniques collectively referred to as severe plastic deformation (SPD), have emerged as a promising approach for the production of bulk ultrafine-grained (UFG) nano-structured materials.... 

A biocompatible ferrofluid containing ?Fe?_3 O_4 nanoparticles was produced using co precipitation of ?FeCl?_2.?4H?_(2 )O and ?FeCl?_3 ?6H?_2 O under ultrasonic irradiation power with NaOH being the alkaline. Two variables studied in this research were concentration and molecular weight of PEG, as the coating agent. The impact of these variables were carefully monitored on shape, size distribution and magnetic behavior of nanoparticles through SEM, DLS, XRD and VSM characterization techniques. Moreover, MRI relaxation times,T_1and T_2, were calculated using synthesized nanoparticles as contrast agents. Accordingly these nanoparticles were biologically evaluated by MTT assay. Results... 

Nitrogen injection is a promising enhanced oil recovery process. Asphaltene precipitation during miscible gas injection is a common problem in oilfields throughout the world. In this work, a comprehensive study is conducted on effect of gas injection on phase behavior and asphaltene instability of live oil samples. Effects of oil API, gas type and concentration, pressure and temperature are studied under natural depletion and nitrogen injection processes by means of high pressure filtration and a photographic procedure coupled with image analysis. Filtration results show that nitrogen destabilizes asphaltenes more compared to methane and the problem is more severe for heavier crude samples.... 

In this study, the micro and nano particles of substituted strontium hexaferrites with nominal composition of SrFe12-xTix/2Znx/2O19 (x=0, 0.5, 1, 1.5, 2 and 2.5) were prepared by a co-precipitaion method. Ferrite-PVA composites (70:30) with thickness of 1.8mm were prepared at 220°C and 50Mpa. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FE-SEM), energy dispersive spectrometer (EDS), vibrating sample magnetometer (VSM) and vector network analyzer (VNA) were employed for characterization of synthesized powders and composites. XRD and FTIR results showed that single phase hexaferrite were obtained for almost all of the... 

Additional to Temperature, Pressure and Compositional changes of crude oils, Electro-kinetics and Electrical potential effects are also known as the most influencing parameters on Asphaltene deposition during oil production and processing.Mechanisms of electro-kinetics and asphaltene charge generation are very complex and unclear. In the previous studies on asphaltene precipitation and deposition, mostly electro-kinetics effects are ignored.While, recent studies show the great effects of electrical filed on asphaltene deposition during production and processing phase of crude oils.At reservoir porous medium and crude flow line, an electrical field can be developed along the length of the... 

The phenomenon of drought causes many damages which is not limited to arid and semi-arid areas and may have destroying effects on groundwater resources of any region. To investigate the drought effects on one of the Lake Urmia’s sub-basin, the precipitation data in 25 rain stations in period of 45 years (2011-1976) was used. After completing and restoring data, and checking the randomness and homogeneity of them, standardized precipitation index (SPI) with different time scales has been calculated. According to that, the monitoring maps of drought using ArcGIS tool with regard to best interpolation method was created in order to identify the sensitive areas in dry years.
Moreover,... 

Recently, low temperature carburizing of stainless steels, especially austenitic stainless steels, have been considered by so many researchers. The improvement of tribological properties of which is so impressive so much so that such properties like hardness and wear resistance increase to manifold. In this research, low temperature carburizing was done on two kinds of precipitation hardenable stainless steels 17-4 and 13-8 Mo. After that, microstructural investigations were done on the carburized surfaces and in 5, 10, 20, 80, and 150 micrometer depths. Moreover, in each depth, in order to phase structure and tribological properties investigation, XRD and microhardness tests were done,... 

The water-gas shift reaction, as a vital reaction in industry especially as a source of hydrogen for the manufacture of ammonia, is influential for all of the scientists and researchers in chemical engineering all around the world. In this research, high temperature water-gas shift (HTS) catalysts were investigated in order to study synthesis parameters and improvement of their performance and catalytic activity. The two catalyst categories; non pre-active and pre-active (magnetite-based samples, not requiring a reduction step prior to use) were prepared by co-precipitation method, using chloride, sulfate and nitrate metal (Fe, Cr, Cu) precursors and NaOH as precipitating agent (the aging... 

In this study melting and casting process of Ag-6.3%wt Cu-1.2%wt Ge alloy with NaBH4 additive for grain refining was investigated. ICP and XRF chemical analysis was used for calculating of Boron and Germanium lost in the processing section then an appropriate route for manufacturing of this alloy was suggested. With SEM and EDS chemical analysis which was installed on SEM sample’s microstructures after cold work and heat treatment was investigated. Solidification’s phases were identified with using DTA, XRD and EDS. To introduce a mechanism for increasing of tarnishing resistance in Argentium alloy, XPS analysis were employed. Optical microscope images reveals that casting samples with grain... 

Special features of magnesium such as low density, perfect bio-compatibility in the human body, and close elastic modulus to the human bone have increased the use of Mg alloys in the bio-medical applications. Nevertheless, low mechanical properties and poor corrosion resistance of Mg alloys have limited their bio-medical applications. The addition of alloying elements together with the use of precipitation hardening and plastic deformation are the most effective methods to improve the mechanical properties and increase the corrosion resistance of Mg alloys. Thus, the present research with the aim of improving the mechanical properties of an Mg-Zn alloy by Ca and Gd additions together with... 

Present study is designed to determine the effect of manganese content in primitive inverse spinel structure of iron oxide nanoparticles. PEG coated water base ferrofluids of Mnx¬Fe3-xO4 (0<0>1)nanoparticles were prepared by co-precipitation method in presence of nitrogen gas and ultrasonic waves using NaOH as a base for biomedical purposes. The crystallite size and structure of synthesized nanoparticles were studied using atomic absorption spectroscopy (AAS), X-ray diffraction spectrometry (XRD), field emission scanning electron microscopy (FE-SEM) and dynamic light scattering (DLS) methods. Thermogravimetric analysis (TGA) and Fourier transform infrared spectroscopy (FTIR) were used to... 

In this thesis, macrostructural evolutions in dissimilar TLP bonding of as-cast nickel based supperalloy IN792 to wrought HX was investigated. In the first step of this study solidification behavior of Ni-Cr-Fe-Si-B (MBF-15) interlayer in presence of HX as base metal at 1120 °C was surveyed. In second step, bonding of HX/HX, IN792/IN792 and HX/IN792 systems with MBF-15 interlayer at 1120 °C and different times were studied and isothermal solidification time and factors that affect this stage were discussed. In third step, synchronization of dissimilar bonding with standard heat treatment cycle of IN792 was investigated and effect of this cycle on aging response of different zones, isothermal... 

Asphaltene, the heaviest and most polarizable fraction of crude oil, has a potential to precipitate, deposit and plug pipelines, causing considerable production costs. The main objective of this study is to contribute to the thermodynamic and transport modeling of asphaltene in order to predict its precipitation, segregation and deposition. Potential calculation of some thermophysical properties of asphaltene is also explored. Predicting the flow assurance issues caused by asphaltene requires the ability to model the phase behavior of asphaltene as a function of pressure, temperature and composition. It has been previously demonstrated that the Perturbed Chain form of Statistical Association... 

In this research, a powder containing magnesium-aluminate spinel particles is prepared based on co-precipitation method and 5% , 10%, 15% and 20% zirconia-contained composites are produced as second phase from the synthesized powder. The raw materials used in the synthesis comprise hexa-hydrated magnesium nitrate, nona-hydrated aluminum nitrate, ammonium bicarbonate, 28% ammonium solution and distilled water. The properties of the powder is then investigated using STA, XRD and SEM tests. Also, XRD and SEM analyses as well as triple point flexural strength and Vickers hardness tests are carried out in order to investigate the effect of adding zirconia to the powders. The variations of the... 

In this research work, to enhance the performance of the conventional spinning disk reactors, a novel type of spinning disk reactor has been proposed and tested successfully through the synthesis of barium sulfate nanoparticles by means of the reactive precipitation. This reactor consists of two coaxial rotating disks placed horizontally in a cylindrical chamber. The experimental results clearly indicate the capability of the proposed reactor in the synthesis of nanoparticles with the smaller mean particle size and the narrower particle size distribution compared to those obtained in various process intensification devices such that barium sulfate nanoparticles with a mean particle size of... 

Growing rate of eutrophication in receiving waters has made the enhancement of wastewater treatment plants to advanced methods of nutrients removal as necessary. Nitrogen and Phosphorus as the nutrients can reduce the quality of water and even make it unusable. Phosphorus is known to be one of the main reasons of eutrophication and creation of algal bloom. In this study, chemical-biological method for phosphate removal from the municipal wastewater is studied. Experiments are implemented for hydraulic retention times of 4, 8 and 16 hours, total intake concentration of phosphorus 7 ppm, COD 400 ppm and Nitrogen 25 ppm. Ferric Chloride as the precipitator chemical substance injected into the...