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    New high-entropy transition-metal sulfide nanoparticles for electrochemical oxygen evolution reaction

    , Article Electrochimica Acta ; 2022 , Volume 436 ; 00134686 (ISSN) Moradi, M ; Hasanvandian, F ; Bahadoran, A ; Shokri, A ; Zerangnasrabad, S ; Kakavandi, B ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    Developing extremely efficient electrocatalysts for oxygen evolution reactions (OER) is a decisive step toward the progression of rechargeable metal-oxygen batteries, CO2 reduction, and water-splitting. Nanoporous high-entropy transition-metal sulfides (np-HETMS) represent a new generation of promising OER catalysts by virtue of their exceptional catalytic activity. However, their synthesis maintains to be a challenge by reason of the thermodynamic immiscibility of the constituting multi-principal metallic elements in the sulfide structure. Herein, for the first time, the np-HETMS ((CoFeNiMnCu)S2) nanoparticles with pyrite-phase was synthesized via a facile and easy adaptable... 

    Impact of rock mineralogy on reservoir souring: A geochemical modeling study

    , Article Chemical Geology ; Volume 555 , November , 2020 Li, H ; Zhang, L ; Liu, L ; Shabani, A ; Sharif University of Technology
    Elsevier B. V  2020
    Abstract
    The petroleum industry suffers from reservoir souring phenomena, which has negative impacts on production facilities, health, and environment. Injection of incompatible water into the reservoir (waterflooding), which is considered as an enhanced oil recovery (EOR) method, is one of the most common causes of reservoir souring. In general, injected brine, especially seawater, contains high amounts of sulfate ion (SO42−). A high concentration of sulfate in the presence of sulfate-reducing bacteria (SRB) leads to the microbial reservoir souring. During this phenomenon, sulfide, specifically hydrogen sulfide gas (H2S) appears in the producing fluid of the reservoir. In this paper, a coupled... 

    Biodesulfurization of the tabas deposit coal by microorganisms

    , Article Journal of Mining Science ; Volume 40, Issue 3 , 2004 , Pages 310-320 ; 10627391 (ISSN) Jorjani, E ; Rezai, B ; Vossoughi, M ; Osanloo, M ; Sharif University of Technology
    2004
    Abstract
    The results are presented for the investigations of sulfur removal from coal by a mixed culture of microorganisms. Optimal conditions of the process are established (pH, size of coal particles, pulp density, temperature, etc.). They make it possible to reduce the content of pyrite and total sulfur by 91.84 and 53.5%, respectively. The decrease in ash content of coal under its leaching is noted. © 2004 Springer Science+Business Media, Inc