Sharif Digital Repository

The main purposes of this study were to scrutinize experimentally effects of polymer and rock types on the oil recovery using water and polymer flooding processes. Four dynamic flooding experiments were carried out at simulated reservoir condition of temperature and pressure. According to the obtained results, the ultimate oil recovery by water flooding in highly fractured reservoirs was less than reservoirs with the microfractures. The results of polymer flooding showed that in addition the polymer molecular weight, the sulfonation of polymers also affects the oil recovery  

Capillary pressure is one of the most important parameters for reservoir engineering studies. Although different experimental methods are devised to measure capillary pressure, these methods do not represent the physics of fluid flow, which happens at reservoir conditions. Thus, it is attempted to extract the capillary pressure from spontaneous imbibition data, the common mechanism of oil production in water wet porous media. In this work, a new approach is developed to obtain the imbibition capillary pressure curve by using spontaneous water imbibition data in oil-water-rock systems. Comparison of calculated imbibition capillary pressure curves by the new approach with experimental values... 

Interfacial tension (IFT) as one of the main properties for efficient CO2 flooding planning in oil reservoirs depends strongly on pressure, temperature, and composition of the reservoir fluids. Therefore, it is important to measure this property at real reservoir conditions for successful field development plan. In this study, an axisymmetric drop shape analysis (ADSA) has been utilized to measure the equilibrium IFTs between crude oil and CO2 at different temperatures and pressures. Moreover, minimum miscibility pressures (MMP) and first-contact miscibility pressures (P max) of crude oil/CO2 systems at different temperatures are determined by applying the vanishing interfacial tension (VIT)... 

Through this work, a novel mathematical-based approach was proposed to develop reliable models for calculation of PVT properties of crude oils at various reservoir conditions. For this purpose, a new soft computing approach namely Least Square Support Vector Machine (LSSVM) modeling optimized with Coupled Simulated Annealing (CSA) optimization technique was implemented. The constructed models are evaluated by carrying out extensive experimental data reported in open literature. Results obtained by the proposed models were compared with the corresponding experimental values. Moreover, in-depth comparative studies have been carried out between these models and all other predictive models. The... 

As the oil production from conventional oil reservoirs is decreasing, oil production through Enhanced Oil Recovery (EOR) processes is supposed to compensate for both the oil production reduction in matured oil reservoirs and the worldwide dramatic increase in oil demand. Therefore, developing a strategy to choose an optimized EOR technique is crucial to find a resolution for production decline in oil reservoirs. A screening tool recommending the most appropriate EOR method is proposed in this study. An expert fuzzy logic system is employed to screen four well-known EOR methods including miscible CO2 injection, miscible HC gas injection, polymer flooding and steam injection based on the... 

In this work, a new model based on the multilayer adsorption kinetic mechanism and four material balance equations for oil, asphaltene, gas, and water phase has been developed to account for asphaltene deposition in porous media under dynamic conditions and the model was verified using experimental data obtained in this work and also with those reported in the literature. The results showed that the developed model based on multilayer adsorption kinetic mechanism can correlate more accurately the oil flooding experimental data in comparison to the previous models based on the mechanical plugging mechanism, in particular in carbonate core samples. Also, a series of experiments was carried to... 

The objective of this study was to experimentally investigate the performance of water-alternating gas (WAG) injection in one of Iran's oil reservoirs that encountered a severe pressure drop in recent years. Because one of the most appropriate studies to evaluate the reservoir occurs generally on rock cores taken from the reservoir, core samples drilled out of the reservoir's rock matrix were used for alternating injection of water and gas. In the experiments, the fluid system consisted of reservoir dead oil, live oil, Co 2, and synthetic brine; the porous media were a number of carbonate cores chosen from the oilfield from which the oil samples had been taken. All coreflood experiments were... 

In this paper, oil recovery and permeability reduction of a tight sandstone core sample in miscible CO2 flooding processes due to asphaltene deposition were studied using an Iranian bottom hole live oil sample in order to distinguish between the mechanical plugging and adsorption mechanisms of asphaltene involved in the interfacial interaction of the asphaltene/mineral rock system. A novel experimental method was designed and proposed to measure the amount of deposited asphaltene due to different mechanisms using the cyclohexane or toluene reverse flooding and spectrophotometer. In this work, the bottom hole live oil sample was injected first to a long core and then CO 2 injection was... 

Asphaltene precipitation during natural depletion and miscible gas injection is a common problem in oilfields throughout the world. In this work, static precipitation tests are conducted to investigate the effects of pressure, temperature and gas type and concentration on asphaltene instability. Three different oil samples have been studied under reservoir conditions with/without nitrogen and methane injection. Besides applying common thermodynamic models, a new scaling equation is presented to predict asphaltene precipitation under HPHT gas injection. Extensive published data from the literature are also used in model development. The scaling approach is attractive because it is simple and... 

This work concerns the experimental investigation of surfactant alternating CO 2 injection in carbonate rocks. The core samples provided from a low-temperature fractured light oil reservoir, located in southwest Iran. The experiments were designed to observe the effect of CO 2-foam injection on gas mobility and oil recovery at different surfactant concentrations. The core samples were initially saturated with synthetic/field brine, 5,000 ppm, and then flooded with live oil to reach connate water saturation at reservoir condition, 115F and 1,700 psia. The commercial surfactant used was sodium lauryl sulfate as an anionic surfactant. The results of this work, along with field-scale simulation... 

Changes in thermodynamic properties such as pressure, temperature, and composition may result in asphaltene precipitation and deposition in porous media. In addition, asphaltene deposition can cause wettability alteration, permeability reduction, and ultimately a decrease in the productivity of a reservoir. Natural depletion is one of the most common processes of asphaltene deposition in which pressure changes destabilize the dissolved asphaltene in the oil and settle them onto the rock surface. In this work, natural depletion experiments in consolidated core samples were performed under simulated reservoir conditions to obtain reliable data and analyze the asphaltene deposition mechanisms.... 

Carbon dioxide miscible flooding has become a popular method for Enhanced Oil Recovery (EOR) because it not only efficiently enhances oil recovery but also considerably reduces green house gas emissions. However, it can significantly cause asphaltene deposition, which leads to serious production problems such as wettability alteration, plugging of the reservoir formation, blocking the transportation pipelines, etc. It is crucial to investigate the effects of different factors on asphaltene deposition. A novel experimental setup was prepared to employ a high-pressure visual cell for investigation of asphaltene deposition on a model rock under typical reservoir conditions. The evolution of... 

In this work effect of composition changes of injection gas, CH4 + CO2, on the performance of immiscible WAG injection in light oil, 41 oAPI, which has been rarely attended in the available literature is investigated. Presence of CO2 helps to reduce the MMP of CH4 significantly. Core flood experiments are conducted at reservoir conditions and fixed flow rate of 0.5cc/min on a sandstone sample with the brine concentration of 5000 ppm, and the influence of injection gas composition as well as WAG ratio on oil recovery is investigated. Different mole percents of methane in mixture, 0%, to 100% are examined, and the tests continued to ten alternate cycles with a slug size of 0.1 pore volumes and... 

Asphaltene precipitation during natural depletion and miscible gas injection is a common problem in oilfields throughout the world. In this work, static precipitation tests are conducted to investigate effect of pressure, temperature and gas type and concentration on asphaltene instability. Three different oil samples are studied under reservoir conditions with/without nitrogen and methane injection. Besides applying common thermodynamic models, a new scaling equation is presented to predict asphaltene precipitation under HPHT gas injection. Published data from literature are also used in model development. The scaling approach is attractive because it is simple and complex asphaltene... 

Experimental Investigation of the Asphaltene Deposition Process during Different Production Schemes - This paper presents the results of asphaltene precipitation and deposition during lean gas injection, CO2 injection and natural depletion in reservoir conditions. In addition, the effect of variations in operating pressure, injection gas concentration and production rate on asphaltene precipitation and deposition were investigated. The severity of asphaltene deposition was found to be more pronounced in lean gas injection in comparison with CO2 injection and natural depletion. Increasing the flow rate in natural depletion xperiments showed a considerable increase in asphaltene deposition,... 

Many oil reservoirs encounter asphaltene precipitation as a major problem during natural production. In spite of numerous experimental studies, the effect of temperature on asphaltene precipitation during pressure depletion at reservoir conditions is still obscure in the literature. To study their asphaltene precipitation behavior at different temperatures, two Iranian light and heavy live oil samples were selected. First, different screening criteria were applied to evaluate asphaltene instability of the selected reservoirs using pressure, volume, and temperature data. Then, a high pressure, high temperature filtration (HPHT) setup was designed to investigate the asphaltene precipitation... 

Interfacial tension (IFT) is known as the critical parameter affecting the efficiency of CO2 flooding during the enhanced oil recovery (EOR) process. Besides, the asphaltene precipitation phenomenon is reported as the most significant problem during CO2 injection into asphaltenic oil reservoirs. Accordingly, it is important to examine the effect of asphaltene precipitation on the IFT behavior of the oil-CO2 system at reservoir conditions. The main objective of this research work is to study of the effect of asphaltene and its type on the IFT behavior of the oil-CO2 system. The IFT between pure CO2 and a model oil both with and without asphaltene was measured using an axisymmetric drop shape... 

Interfacial tension (IFT) is known as the critical parameter affecting the efficiency of CO2 flooding during the enhanced oil recovery (EOR) process. Besides, the asphaltene precipitation phenomenon is reported as the most significant problem during CO2 injection into asphaltenic oil reservoirs. Accordingly, it is important to examine the effect of asphaltene precipitation on the IFT behavior of the oil-CO2 system at reservoir conditions. The main objective of this research work is to study of the effect of asphaltene and its type on the IFT behavior of the oil-CO2 system. The IFT between pure CO2 and a model oil both with and without asphaltene was measured using an axisymmetric drop shape... 

In this work, experimental studies were conducted to determine the effect of asphaltene deposition on the permeability reduction and porosity reduction of carbonate, sandstone and dolomite rock samples using an Iranian bottom hole live oil sample which is close to reservoir conditions, whereas in the majority of previous work, a mixture of recombined oil (a mixture of dead oil and associated gas) was injected into a core sample which is far from reservoir conditions. The effect of the oil injection rate on asphaltene deposition and permeability reduction was studied. The experimental results showed that an increase in the oil injection flow rate can result in an increase in asphaltene... 

Despite the numerous experimental studies concerning asphaltene, the extent of reversibility of asphaltene aggregation at reservoir conditions remains still an elusive and controversial issue in the available literature. In this work, a series of depressurization and repressurization experiments were performed on three different live oils for qualitative and quantitative evaluation of the reversibility of asphaltene aggregation under typical pressure and temperature conditions of oil fields. The obtained results reveal that the kinetics and the extent of reversibility of asphaltene aggregation at elevated pressure and temperature are majorly controlled by the characteristics of the reservoir...