Sharif Digital Repository

In this project rotational barrier around the C-N bond in 4-ethyle-morpholine- carboxylate has been studied using DNMR spectroscopy. Spectra were taken at variable temperature, and then with simulation of bandshape broadening pattern at coalescence region, rate constants of exchange were obtained for all temperatures. For simulation of line-shape broadening Spinworks software was used, that with two interfaces made possible simulation with two bandshape simulator programs, DNMR and MEXICO. The rate constants obtained from simulations, were used for calculation of thermodynamic activation parameters (∆G#, ∆H#, ∆S# and Ea). ∆G# 298 value of 13.66 Kcal/mol for 4-ethyle-morpholine- carboxylate... 

Atomic force microscope (AFM) has a significant capability of imaging surface topography on an atomic scale. It is also widely used for Nanolithography in MEMS/NEMS (micro/nanoelectromechanical systems). Conventional AFMs consist of a cantilever with a sharp conical or pyramidal tip located at the free end of the cantilever that plays an important role in AFM measurements. Scanning across a surface, AFM interacts with the sample surface through its tip. Although the dynamic behavior of the AFM cantilever is complicated, the researchers have been interested in studying AFM dynamic behavior because it has a great influence on the surface imaging process. The imaging rate and contrast of... 

The purpose of this research is to investigate the movement and diffusion of pollution transversely around a set of stems of flexible plants with different materials and to observe the effect of resonance on lateral dispersion. Two stem samples of polyurethane and nylon were used under different Reynolds numbers. Vertically uniform dye is injected into the flow, and the evolution of the dye plume along the flow is measured using image processing. By measuring the displacements of selected stems we study the effects of resonance on stem vibration and lateral dispersion. The experiments were also conducted for no-stem dispersion and the results were compared with those with plant samples. The... 

Integrating hundreds of cores on a single chip necessitates high performance interconnection network. Due to great delay and power consumption of electrical networks in global connections, their use might be limited in future. Optical networks-on-chip are introduced recently as a proper alternative for electrical networks by providing high bandwidth, low latency, and low power consumption. Despite these outstanding advantages, optical component behavior is very sensitive to temperature fluctuations. Specifically, thermal variations affect refractive index of semiconductor, which in turn change resonating wavelength of micro-ring resonator. Therefore, the switch cannot operate properly and... 

Proton precession magnetometers are one of the most sensitive scalar magnetic sensors. Their function is based on Zeeman effect and also nuclear magnetic resonance phenomena. In this project we have designed and implemented needed coils, swithching and signal detection circuits. Because of extremely high sensitivity of this sensor to induced noises and also gradient of earth’s magnetic fileld, detection of precession signal needs design of low noise electronic circuits with special EMC considerations. The implemented system in this project contains different blocks, such as switching circuit and its related control unit, amplifier, filter and frequency meter. Using this system, the obtained... 

Obesity is a worldwide growing health challenge affecting ~30% of the world's population. Increased rate of disc degeneration and herniation, low back pain and surgery has been reported in obese individuals. Although obesity-related low back diseases have multifactorial etiology, presumably greater mechanical loads on the spine of heavier individuals during their daily activities may be considered as a risk factor. Likely larger trunk muscle sizes, disc sizes and thus passive stiffness in heavier individuals may however partly or fully offset the effect of their additional body weight on the spinal loads. In absence of in vivo approaches, the present study aims to construct subject-specific... 

NMR spectroscopy as a powerful technique is often used to investigate on structural and conformational studies on proteins and drug compounds. In this work, conformations and structural properties of drug compounds and some nucleoside derivations have been studied using advanced NMR techniques including H-H COSY, HMQC, HMBC and NOESY and quantum based calculations.Experimental analysis on Valsartan show that there are two simultaneous conformers (M and m) with unequal population in M-m type solvents and two stable conformers (N and n) in the N-n type solvents. As the results show, different intramolecular hydrogen bond is the reason for stability af all available conformers. In the... 

E-plane waveguide filters are good choices due to highly manfacturing accuracy in Q-band microwave devices.To increase the attenuation slop or selectivity of such filters one need to synthesis transmission zeros with cross coupled resonators.With this method for constanst degree and return loss, attenuation slop increases in comparison to direct coupled resonators.
In this thesis we designed and fabricated a Q-band 4th degree filter,with center frequency at 42.1746 GHz and bandwidth of 350 MHz with two transmission zeros. Results of simulations and measurments are given in chapters 3 and 5.
Microwave filters using coupled resonators are important components in microwave systems.... 

Due to the growing rate of photovoltaic plants in power systems, in the future years this type of plant will have significant contribution in electrical energy generation. For this reason, the impact of photovoltaic plants on various aspects of power system operation should be investigated. In this research dynamic impacts of photovoltaic plants on small signal stability of power systems are analyzed. For this purpose, improved dynamic equivalent models are developed for large-scale photovoltaic plants, based on integration of the plant modules. It is shown that the usual assumption of ideal DC power supply at the input of plant inverter is inappropriate, and that the DC-DC converter and DC... 

Iron oxide nanoparticles were synthesized using microemulsion technique as MRI contrast agents. Utilization of nanoparticles for biological applications and in this case as MRI contrast agents needs particles to be of small size and also narrow size distribution. For this aim, the effect of several parameters on size and size distribution has been studied. These parameters include water/surfactant ratio, precursor’s concentration and amount of polymer employed to improve nanoparticles colloidal stability. XRD, FE-SEM and TEM results reveal that the synthesized nanoparticles had small size (about 10 nm iron oxide core and 20 nm overall diameter) and possessed narrow size distribution (15-21... 

In this thesis, implementing parametric resonance for the purpose of improvement in sensitivity of MEMS gyroscopes is studied. Based on a parametric study on effect of each factor on the sensor’s performance, the desired values for each parameter is determined. Stability of periodic orbits is studied using Floquet Theory. In addition, three expositions are defined and proved in order to make Floquet Theory applicable for stability analysis of origin. Based on this analysis, the relation between stabilities in the system and occurrence of parametric resonance is illustrated. Due to the complexity of dynamics of a parametrically excited MEMS gyroscope, bifurcations are observed in performance... 

Objective: Joint analysis of multi-subject brain imaging datasets has wide applications in biomedical engineering.In these datasets, some sources belong to all subjects (joint), a subset of subjects (partially-joint), or a single subject (individual). In this thesis, this source model is referred to as joint/partiallyjoint/individual multiple datasets unidimensional (JpJI-MDU), and accordingly, a source extraction method is developed.Method: We present a deflation-based algorithm utilizing higher order cumulants to analyze the JpJI-MDU source model. The algorithm maximizes a cost function which leads to an eigenvalue problem solved with thin-SVD (singular value decomposition) factorization.... 

converters in electric vehicles, it is necessary to reduce their dimensions and increase their efficiency. It is expected that in the near future wide band gap semiconductors will be used to achieve these goals. On the other hand, usage of planar transformers is necessary to achieve slim and compact converter designs in electric vehicles. Clearly, planar transformers offer a significant advantage in replacing bulky wired transformers in high frequency LLC resonant converters with WBG transistors. planar transformers also have several other advantages, including low flux leakage, modular structure, and low thermal resistance.However, in planar transformers, due to the proximity and large area... 

Vibrations with high amplitudes in continuous systems and models with multiple degrees of freedom, in specific conditions, is concomitant with a phenomenon called internal resonance. In the presence of this phenomenon, energy is transferred from one directly excited mode to the other vibrating modes of the structure results in response of the structure to be combination of the excited modes. In that situation occurrence of the internal resonance may decrease the level of undesired vibrations of the structure. This behavior is of interest especially in sandwich structures with viscoelastic cores that are designated to improve the damping characteristics of the structure and the property may... 

Conventional MRI has been used to diagnose different types of brain injuries. However these methods have generally failed to diagnose mild types of injury. We are working on the specification of mild traumatic brain injury, using diffusion MRI data, based on a multi compartment simulation of white matter tissue. This effort is essential for better understanding of underlying tissue micro-structure changes in patients with trauma. Some studies have been used in similar data fitting approaches in order to estimate axon diameter distribution. Specifically, a comparative study between different Compartment Models has shown that “ActiveAx” model has the best agreement with underlying tissue... 

In recent years, much attention has been paid to the development of biofunctionalized nanoparticles with special magnetic properties for using in clinical imaging. Targeted magnetic materials with high MRI signal intensity can be used in tissue imaging and molecular and cellular detection as valuable tools. The aim of this study has been to synthesize the nanocomposite including the functional gadolinium oxide (Gd2O3) nanoaprticles for MRI contrast agent. Synthesis and in-situ surface modification of ultrasmall Gd2O3 nanoparticles (2.5nm) with PVP was performed by a microwave modified polyol in 5 min. The structure and size of synthesized nanoparticles were studied using X-ray diffraction... 

Surface plasmons are the result of a resonant interaction between the waves and the mobile electrons at the interface between negative and positive permittivity materials stimulated by incident light. Due to their specific quantum mechanical nature and zero electrical resistance, superconductors are capable of supporting low-loss plasma waves with extremely large propagation length. In this study, palsmon confinement in some superconducting waveguide structures has been measured by computing the effective index parameter. Superconductors are classified in to high-Tc an low-Tc categories. It is not possible for plasma waves to propagate in low-Tc superconductors, because the plasma energy... 

The Transparent electrode (transparent conductive layer) is an essential component of electro-optical devices, especially screens, solar cells and touch screens. Today, most semiconductor oxides such as ITO are used for this purpose, which have problems such as inflexibility, high cost, environmental degradation and ion penetration in organic displays. In this research, the design, simulation and fabrication of a transparent electrode with a network of metal nanowires with low resistance between cross fibers and high aspect ratio during the production stages of polymer mold, metal coating and characterization has been done. Using the reducing atmosphere in the sputtering chamber, the... 

Nowadays, power electronics converters with pulse width modulation (PWM) are widely used in different power circuits. Operation of semi-conductive switches during on and off conditions causes switching dissipation and consequently decreases the efficiency of the PWMs. Recently, by increasing the required power for power electronics applications, quasi-resonant converters attract attentions. Quasi-resonant converters, by adding resonant circuits to the PWM converters causes the soft switching operation (switching with zero current or voltage) and decreases the energy loss. In conventional control methods of these converters, the nonlinear average circuit model is linearized around the... 

So far, investigations have shown that open dielectricresonator antennas(DRAs) offer several advantages at microwaveand millimeter wave frequencies and make them appropriate in low directional-gain applications . These advantages include small size, large impedance bandwidth, high radiation efficiency, ease of manufacturing and simple feed-coupling mechanisms (such as probe coupling, aperture coupling or proximity coupling to micro-strip lines). Most microwave ferrites have dielectric constants in the desirable range and they can be used in place of dielectric materials. Such ferrite resonator antennas (FRAs) offer a potential advantage inthat their permeability tensor can be controlled by...