Sharif Digital Repository

In this work the effect of recycling process and nanometric CaCO3 on the rheological and heat-sealing properties of co-polymer Polypropylene (R40) was studied. Nanocomposites with recycled and neat matrix were prepared with twin extruder. Complex viscosity, dynamic modulus, flexural and tensile properties, impact strength and sealing ability of nanocomposites of neat Co-PP (R40) and Recycled Co-PP (RPP) determined according to the relevant standard specifications.Rheological analysis revealed that incorporation of nanofiller enhances values of Complex viscosity and dynamic modulus, broadening molecular weight distribution (MWD) and decrease cross over point (ωc, GC) for RPP. In this study,... 

The rheology of oil well cement (OWC) slurries is generally more complicated than that of conventional cement paste. In order to contend with bottom hole conditions, a number of additives are usually used in the OWC slurries. The objective of this research is to develop a fundamental understanding of the important mechanisms that affect the properties of OWC slurry such as rheological properties, free water, compressive strength and thickening time incorporating various chemical and mineral admixtures. The partial replacement of OWC using different nanoparticle weight percent has been proved to be a promising method. The mechanisms underlying the effects of chemical admixtures on the... 

The aim of the present study is to investigate the effects of using hybrid fibers on rheological, mechanical and durability properties of the high-strength Self-Consolidating Concrete (SCC). For this purpose, two types of fibers including hooked-end steel fibers and polypropylene fibers were used. In this study, a total of eleven mixtures were used: one as a control mix, one containing 0.5% steel fibers, four containing 0.5% hybrid fibers (steel and polypropylene), one containing 1.0% steel fibers and the four containing 1.0% hybrid fibers (steel and polypropylene). For investigating the rheological properties, slump flow, J-ring and V-funnel tests were performed. Mechanical properties were... 

Understanding the properties of crude oil and the phenomena arising from this precious matter has always been of considerable importance. One of these important phenomena is emulsion, which is well-known in a great number of crude oil-related processes such as drilling, well completion, production, transportation and even the processing units in the refinery. One of the most important properties of crude oils and their emulsions is their flow or in other words their rheology. Therefore, in this project has also been tried to investigate the rheological behavior of crude oil and water in crude oil emulsion, experimentally and theoretically. The experiments were carried out using two crude... 

One of the most well-established methods of increasing oil production rate from existing fields is infill drilling. However, drilling these depleted reservoirs with conventional high density drilling fluids may cause formationdamage problems and subsequently reduce the expected production rate. To overcome these technical problems, the use of lightweight aphron based fluids isincreasing rapidly in the petroleum industry. Rheological and fluid loss performance of aphron based drilling fluids can be improved in the presence of nanoparticles; however, very limited information is available in this field. Moreover, a thorough knowledge about the hydrodynamic flow behavior of drilling fluids... 

In recent years, there have been huge advancements in fabrication of micron-sized devices such that they enabled engineers to create a wide range of miniaturized systems, each of which is utilized in mechanical, electrical, and thermal applications. Micromixers are one of these devices with the role of mixing various micro flows. These devices are broadly used for chemical, biological, and biomedical assays. Among variety of micromixers, one that employs electrokinetic transport phenomenon is of great popularity. For instance, mixing under electroosmotic flow enables accurate process control and eliminates the need for moving components inside micromixer. The very complex nature of electric... 

Most used polymers, such as hydrolyzed polyacrylamide, are not able to withstand high levels of salinity and high temperature of the reservoirs. To overcome these problems, in this project, new types of microstructures based on modified acrylamide with hydrophilic groups (malic anhydride monomer) and hydrophobic groups (styrene monomer) using inversible mini-emulsion were synthesized. The structure of the synthesized terpolymer was investigated using methods of FT-IR and 1H NMR. The micro-structure and the particle-size of the terpolymer particles were studied with the scanning electron microscopy (FE-SEM) and differential light scattering (DLS) method and the results showed that the average... 

Hydrogels are kind of polymers that have ability of frequently applications in agriculture, hygienic, drug delivery and etc. suitable mechanical strength is one of the features of this material. If mechanical strength reduces, efficiency of hydrogels in variety of application will decrease. There are several ways for gel strength improvement, such as cyclic structure for example fumarates, surface crosslinking and preparation of interpenetrating polymer networks (IPNs). Making of nanocomposite structure in hydrogels, using nanostructures, can improve physical-mechanical properties, surprisingly. Therefore, combination of interpenetrating polymer network (IPN) and nanocomposite structures can... 

The purpose of this project is to design a water-based drilling fluid for use in high-pressure and high-pressure conditions (Deep Drilling). This goal is usually achieved by adding the resistant polymers to the ambient conditions (temperature stability) to the drilling fluid (here the blue base fluid), and then the rheological properties of the fluid are studied. The stability of the rheological properties of the fluid in high temperature and high pressure conditions is not constant. In this situation, a sequence of events occurs, for example, decreases with increasing viscosity and turbulence, and hence the reduction of drilling fractures and the efficiency of the bottom of the well is... 

Labneh is a semisolid product that is produced by concentrating milk to approximately 23% total solids (wt/vol) by the traditional cloth bag method, ultrafiltration and direct reconstitution. For ultrafiltration membrane processing is carried out either before or immediately after fermentation. The effect of storage time on the flow properties of concentrated yogurt (labneh) was investigated using a rotational viscometer. Experiments were performed at after 0, 2, 5 and 14 days after production. The apparent viscosity of fresh sample was then measured as a function of shear rate. For a given shear rate, the apparent viscosity was measured as a function of shearing time. The increase in the... 

In recent years, Jam Petrochemical has produced and designed irrigation tape polyethylene grades but because these grades don’t have sufficient melt strength during high-speed processing, it hasn’t been welcomed by manufacturers. Therefore, in first step of this study we tried to characterize the specimens by using referenced grade and by taking advantages of thermal, rheological and mechanical analysis. We observed that main difference between jam petrochemical grades and referenced grade is related to type and content of comonomer and also long chain branches. Based on the obtained results, the ideal molecular structure of irrigation tape grade, include chains with bimodal distribution... 

In some concrete projects, the consolidation of concrete is quite challenging due to the congestion of rebar and the complex concrete placement. Self-compacting concrete (SCC) can overcome these problems. On the other hand, nanomaterials in concrete can be used to improve the engineering properties of concrete and adverse environmental effects. This study uses aluminum-nano oxide and carbon-nano tubes (by replacing 1, 3, and 5% by weight of cementitious materials) to enhance the physical and mechanical properties of SCC. Additionally, adverse environmental effects of SCC improve by replacing 35% of cement with combustion furnace slag. Experimental results showed that with increasing... 

Currently, one of the most important problems in the field of drilling is the issue of drilling fluid loss in different formations. The problem of mud loss has been evident since the beginning of oil and gas well drilling operations, so that oil companies spend millions of dollars annually to solve the problem of mud loss. Problems such as pipe jamming, loss of rig production time, well blowout, loss of a large volume of drilling mud and damage to reservoir formations due to loss of drilling fluid are caused. Regarding the drilling variables, many factors cause the decrease or increase of the loss, the most important of which are the weight on the drill bit, drilling speed, the rate of... 

The use of polymers in the EOR process is very common. Most of these polymers are sensitivity to temperature, salt, and the presence of bacteria. Among these materials, hydrolyzed polyacrylamide (HPAM) is the most widely used. Due to the sensitivity of HPAM in harsh conditions like temperature and salinity of the environment, modification of this polymer by hydrophobic groups can be very effective. Hydrophobic-hydrophilic associative polymers have shown unique rheological properties and high thermal stability, which is due to the presence of a small percentage (up to two percent) of hydrophobic monomers in their structure. Despite these excellent properties for acrylamide copolymers... 

3D bioprinting is an additive manufacturing method that facilitates the deposition of the desired cells and biomaterials at any pre-defined location. This technique also enables control over the internal structure and external dimensions of printed constructs. Among various biomaterials used as bioinks, the bioinks derived from decellularized extracellular matrixes (dECMs) have attracted significant attention due to their bioactivity and being a rich source of biochemical cues. Here in this study, the decellularized amnion membrane (dAM) has been selected as the main component of the bioink formulation because of its biocompatibility, low immunogenicity, antibacterial property, abundance,... 

The purpose of this experimental study is to obtain 3 proper 3D-Printable concrete mix designs including high-strength concrete, EPS concrete with volume ratio of 25% and carbon fiber reinforced concrete with volume ratio of 1%. After successfully reaching above mix designs, 4 concrete beam samples were 3D-Printed of which 3 of them made according to the mix designs and one using the latter 2 designs as composite section. Putting the beam samples under 4-Point Bending Test, Results show a significant improvement in the performance of the composite section  

During the drilling process, cutting concentration in vertical and inclined wells is a common problem and major issue in designing hydraulic parameters. This is becoming more important in near bit area. Cutting transport usually is affected by several parameters such as mud rheology, flow rate, nozzle size, rotation speed, and mud weight.
In this work it was aimed to design a new set-up to test all the factors on hole cleaning phenomenon especially in near bit area. The set-up consists of a 16 feet long flow loop, 3.28 feet height of the test section, and 3.33 inches inner diameter of the test section. Each parameter which has an impact on hole cleaning could be varied. The cutting... 

Although polyacrylamides and theirs modified polymers have an extremely application in the industry mechanical weakness, such as viscosity in salinity or high temperature cause this polymer loss your functional application. In recent years, many endeavors due as modified this polymer by hydrophobics monomers were done but unfortunately don’t have a significant result. Modified acrylamide monomer and hydrophobic mini-emulsion were survey Most used polymers, such as hydrolyzed polyacrylamide, are not able to high levels of salinity and high temperature of the reservoirs. Dr. Ramazani and theirs group use innovational idea of hydrophilic monomers for overcome to this problem. In this project,... 

Wax precipitation is one of the major problems in the transfer of crude oil from field production to refineries. This wax with asphaltene compounds and some water and solids, closes the oil pipeline. One of the ways to reduce the amount of wax in pipes is to use additives (flow improvers) to crude oil and improve its rheological behavior. In this research, Five Iranian crude oils were characterized with SARA test and then the effects of various additives including ethylene vinyl acetate (EVA) in concentrations of 500 and 1500 ppm, alkyl phenol ormaldehyde resins (NPFR) with 1500 ppm and styrene-(ethylene-cobutylene)- styrene (SEBS) with 1500 ppm on viscosity, wax appearance temperature... 

Polyethylene is one of the most widely used industrial materials for producing water and gas pipes due to low pricing and mechanical properties and high corrosion resistance. Various parameters such as molecular weight and the short chain branches distribution strongly affect the mechanical properties of these materials. PE100 grade of this material has been introduced with bimodal molecular weight distribution, has excellent mechanical properties and especially high creep resistance and today is used for pipe production in water distribution systems. In the first part of this study, the effect of 1-butene comonomers on different properties of three PE100 and two PE80 resins produced in...