Sharif Digital Repository

Simultaneous water and CO2 injection has been performed on a sandstone core to evaluate oil recovery under the secondary and tertiary near-miscible injection modes. It is demonstrated that secondary SWACO2 injection as well as tertiary flood is an effective method for the oil/residual oil recovery from oil saturated/water-flooded porous media. In the secondary SWACO2 injection, the ultimate oil recovery increases by increasing SWAG ratio from 0.2 to 0.4 but due to some limits, e.g. topological effects, prohibiting contacting of injected gas with residual oil in pores, altering SWAG ratio from 0.4 to 0.6 showed no effect on ultimate oil recovery. Secondary SWACO2 injection can recover higher... 

Naturally fractured reservoirs (NFRs) contribute in large extent to oil and gas production to the ever increasing market demand of fossil energy. It is believed that the vertical displacement of oil during gas injection assisted by gravity drainage (GAGD) is one of the most efficient methods for oil recovery in these reservoirs. Hence, in this work, unconsolidated packed models of cylindrical geometry surrounded by fracture were utilized in order to perform a series of flow visualization experiments during which the contribution of different parameters such as the extent of matrix permeability, physical properties of oil (viscosity, density, and surface tension) and the withdrawal rate was... 

Water flooding is being widely used in the petroleum industry and has been considered as a simple inexpensive secondary recovery method. But in fractured formations, existence of fracture system in reservoir rock induces an adverse effect on oil recovery by water flooding. Polymer flooding has been successfully applied as an alternative enhanced oil recovery method in fractured formations. But, the role of fracture geometrical properties on macroscopic efficiency of polymer flooding is not yet well-understood, especially in fractured five-spot systems. In this work five-spot glass micromodel, because of micro-visibility, ease of multiple experimentations and also presence of the unexplored... 

This work concerns the experimental investigation of surfactant alternating CO 2 injection in carbonate rocks. The core samples provided from a low-temperature fractured light oil reservoir, located in southwest Iran. The experiments were designed to observe the effect of CO 2-foam injection on gas mobility and oil recovery at different surfactant concentrations. The core samples were initially saturated with synthetic/field brine, 5,000 ppm, and then flooded with live oil to reach connate water saturation at reservoir condition, 115F and 1,700 psia. The commercial surfactant used was sodium lauryl sulfate as an anionic surfactant. The results of this work, along with field-scale simulation... 

Most of the reservoirs in Iran and also around the world are in the middle of their production life and have passed their natural production period. Therefore, they should be a candidate for immiscible injection, e.g., water injection for secondary recovery, and/or miscible injection, like solvent injection for tertiary recovery. Also, it should be pointed out that most of the Iranian reservoirs are carbonate reservoirs. This type of reservoir is fractured and heterogenic. Heterogeneity causes an earlier breakthrough and immiscible injection causes an unstable front, which leads to a lower recovery. This article presents the modified equation of Buckley-Leverett and fractional flow... 

The quantification of carbon dioxide (CO2) dissolution in oil is crucial in predicting the potential and long-term behavior of CO2 in reservoir during secondary and tertiary oil recovery. Accurate predicting carbon dioxide molecular diffusion coefficient is a key parameter during carbon dioxide injection into oil reservoirs. In this study a new model based on adaptive neuro-fuzzy inference systems (ANFIS) is designed and developed for accurate prediction of carbon dioxide diffusivity in oils at elevated temperature and pressures. Particle Swarm Optimization (PSO) as population based stochastic search algorithms was applied to obtain the optimal ANFIS model parameters. Furthermore, a simple... 

Gas injection process for more oil recovery and in particular CO2 injection is well-established method to increment oil recovery from underground oil reservoirs. CO2 sequestration which takes place during this enhanced oil recovery (EOR) method has positive impact on reducing the greenhouse gas emission which causes global warming. Direct gas injection into depleted oil reservoirs, encounters several shortcomings such as low volumetric sweep efficiency, early breakthrough (BT) and high risk of gas leakage in naturally fractured carbonate oil reservoirs. Carbonated water injection (CWI) has been recently proposed as an alternative method to alleviate the problems associated with gas... 

Estimating available hydrocarbon to be produced during secondary oil recovery is an ongoing activity in field development. The primary plan is normally scheduled during early stage of field's life through master development plan studies. During this period, due to the lake of certain data, estimation of the field efficiency is usually based on rules of thumb and not detailed field characterization. Hence, there is a great motivation to produce simpler physically-based methodologies. The minimum necessity inputs of percolation approach make it a useful tool for foration performance prediction. This approach enables us to attain a better assessment of the efficiency of secondary recovery... 

The effectiveness of secondary recovery methods in reservoir development studies depends on the knowledge about how fluid-carrying regions (i.e. good-quality rock types) are connected between injection and production wells. To estimate reservoir performance uncertainty, comprehensive simulations on many reservoir model realisations are necessary, which is very CPU consuming and time demanding. Alternatively, we can use much simpler and physically based methods such as percolation approach. Classic percolation assumes connectivity between opposite 2-D faces of a 3-D system; whereas, hydrocarbon production is achieved through active wells that are one-dimensional lines (e.g. vertical,... 

Carbonated water injection (CWI) is known as an efficient technique for both CO2 storage and enhanced oil recovery (EOR). During CWI process, CO2 moves from the water phase into the oil phase and results in oil swelling. This mechanism is considered as a reason for EOR. Viscous fingering leading to early breakthrough and leaving a large proportion of reservoir un-swept is known as an unfavorable phenomenon during flooding trials. Generally, instability at the interface due to disturbances in porous medium promotes viscous fingering phenomenon. Connate water makes viscous fingers longer and more irregular consisting of large number of tributaries leading to the ultimate oil recovery... 

Determining the time of breakthrough of injected water is important when assessing waterflood in an oil reservoir. Breakthrough time distribution for a passive tracer (for example water) in percolation porous media (near the percolation threshold) gives insights into the dynamic behavior of flow in geometrically complex systems. However, the application of such distribution to realistic two-phase displacements can be done based on scaling of all parameters. Here, we propose two new approaches for scaling of breakthrough time (characteristic times) in two-dimensional flow through percolation porous media. The first is based on the flow geometry, and the second uses the flow parameters of a... 

Smart water flooding as a developing technique utilizes modified water chemistry in terms of salinity and composition to prepare the best-suited brine composition for a specific brine/oil/rock system to obtain higher oil recovery efficiency. Huge amount of unrecovered oil is expected to be remained in carbonate reservoirs; however, few research works on incremental oil recovery during smart water injection in carbonate cores at reservoir condition are reported. Several core flooding tests using one of the Iranian carbonate reservoir rock are conducted to check the effectiveness of smart water injection for more oil recovery efficiency. The results reaffirm the positive effect of sulfate ions... 

This study aims to investigate the role of fluid-fluid interactions during low salinity water flooding, using crude oil from an Iranian oil reservoir. To minimize the effects of mineral heterogeneity and wettability alteration, a synthetic sintered glass core was utilized and all coreflooding experiments were performed at low temperatures without any aging process. The effect of fluid-fluid interactions were investigated in both secondary and tertiary injection modes. pH measurements as well as UV-Vis spectroscopy and interfacial tension (IFT) analysis were performed on the effluent brine samples. Results: show that fluid-fluid interactions, mainly the dissolution of crude oil polar... 

Carbonated water injection (CWI) is known as an efficient technique for both CO2 storage and enhanced oil recovery (EOR). During CWI process, CO2 moves from the water phase into the oil phase and results in oil swelling. This mechanism is considered as a reason for EOR. Viscous fingering leading to early breakthrough and leaving a large proportion of reservoir un-swept is known as an unfavorable phenomenon during flooding trials. Generally, instability at the interface due to disturbances in porous medium promotes viscous fingering phenomenon. Connate water makes viscous fingers longer and more irregular consisting of large number of tributaries leading to the ultimate oil recovery... 

This research evaluates the effect of filler type and content on rutting resistance of asphaltic materials by using laboratory experiments. To examine the effect of filler type, two traditional fillers (Silica sandstone powder and Portland cement) and a new recycled lime powder (Eggshell) were considered. To investigate the effect of filler content, three different filler contents were used. Marshall Stability test was performed on full mixes in order to determine the optimum binder content of the mixtures. Then, the static creep test was performed on Fine Aggregate Matrix (FAM) samples. The permanent strain after 10 minutes of recovery (PS-660) was considered as the indicator of potential... 

Low salinity waterflooding (LSWF) is a process in which by lowering the ionic strength and/or manipulation of the composition of the injection water, the long term equilibrium in oil/brine/rock system is disturbed to reach a new state of equilibrium through which the oil production will be enhanced due to fluid/fluid and/or rock/fluid interactions. In spite of recent advances in the simulation of the LSWF at core scale and beyond, there are very few works that have modelled and simulated this process at the pore scale specially using direct numerical simulation (DNS). As a result the effects of wettability alteration and/or Interfacial Tension (IFT) change on the distribution of the phases... 

Preformed particle gels (PPGs) in solutions have been widely used to suppress excess water production in mature oil reservoirs and, in turn, to improve the amount of oil recovery in brown oil fields. In this study, PPG solutions were meticulously formulated and synthesized in order to be utilized in harsh environments in terms of pressure, temperature, pH, and salinity from a free radical polymerization process. In this work, nanosilica gel at different weight percentages was added to improve the mechanical and thermal stability properties of the PPG at harsh condition: high pressure, temperature, and strain. Moreover, the effects of nanosilica gel at various concentrations, ranging from 0.0... 

One of the key open questions in the area of low or controlled salinity water flooding (LSWF or CSWF) is how the observed oil recovery at macro-scale (e.g. Darcy or core-scale) can the explained and what underlying microscopic mechanisms drive it. Thus far, the micromodel investigation of LSWF has been limited to sandstones, remaining challenging to apply to carbonates. In this paper we aim to i) extend the capability to fabricate a novel calcite micromodel using Iceland spar calcite crystal, ii) investigate the pore-scale mechanisms leading to oil recovery from carbonates. A target crude oil-brine-rock (COBR) system was first selected. To screen potential brines which can produce... 

The efficiency of low salinity waterflooding, particularly during tertiary mode injection, is highly controlled by in situ mixing between the stagnant regions holding high salinity water (HSW) and the flowing regions containing low salinity water (LSW) because it impacts directly the electrokinetics of wettability alteration and the time scale of the low salinity effect. This study aims to address the effects of oil polarity and charged rock surfaces on the time scale of mixing and transport under two-phase flow conditions. A systematic series of micromodel experiments were performed. The micromodels were first saturated with high salinity formation brine and oil (both model and crude oil);...