Sharif Digital Repository

Because of the compatibility with tandem devices and the ability to be manufactured at low temperatures, inverted perovskite solar cells have generated far-ranging interest for potential commercial applications. However, their efficiency remains inadequate owing to various traps in the perovskite film and the restricted hole blocking ability of the electron transport layer. Thus, in this work, a wide-bandgap n-type semiconductor, 4,6-bis(3,5-di(pyridin-4-yl)phenyl)-2-phenylpyrimidine (B4PyPPM), to modify a perovskite film via an anti-solvent method is introduced. The nitrogen sites of pyrimidine and pyridine rings in B4PyPPM exhibit strong interactions with the undercoordinated lead ions in... 

Nickel oxide (NiOx) is a promising hole transport material in inverted organic-inorganic metal halide perovskite solar cells. However, its low intrinsic conductivity hinders its further improvement in device performance. Here, we employ a trimercapto-s-triazine trisodium salt (TTTS) as a chelating agent of Ni2+ in the NiOx layer to improve its conductivity. Due to the electron-deficient triazine ring, the TTTS complexes with Ni2+ in NiOx via a strong Ni2+-N coordination bond and increases the ratio of Ni3+:Ni2+. The increased Ni3+ concentration adjusts the band structure of NiOx, thus enhancing hole density and mobility, eventually improving the intrinsic conductivity of NiOx. As a result,... 

Perovskite materials with ABX3 structure (A: organic, B: metal, and X: halides) have attracted tremendous attention due to their outstanding optoelectronic properties. Herein, a novel approach is developed using chemical vapor deposition (CVD), i.e., metal alloying of halide-perovskite domain via ion-transfer (MAHDI) for the growth of high-quality perovskite films, grown directly from a metal precursor. This technique easily enables us to replace the toxic Pb metal (B site) with other metals using alloying approach. Using the proposed approach, we fabricated stable and efficient Pb–In perovskite solar cells (PSCs) with a maximum power conversion efficiency (PCE) of 21.2%, which is more... 

In this research, the design of a solar reverse osmosis desalination plant was investigated by integrating various components using TRNSYS and ROSA software. To this goal, a two-stage reverse osmosis system with 50% recovery in the city of Chabahar was modeled. The calculations were performed in three different case studies, i.e., a photovoltaic power plant, a solar collector power plant with Organic Rankine Cycles, and a photovoltaic thermal power plant with Organic Rankine Cycles, with the reverse osmosis desalination plant being a novel investigation. Water production and electrical energy generation of each case study were evaluated both on a daily and yearly bases. The simulation... 

The solar humidification-dehumidification desalination system with a subsurface condenser is a promising renewable energy-based desalination system. This desalination system is particularly suitable for condensation irrigation in greenhouses, especially where conventional energy sources are limited. A computational model of the system comprising a horizontal solar film evaporator and a subsurface condenser is developed. A previously proposed hybrid analytical–numerical model for horizontal ground heat exchangers is modified for the subsurface condenser. An experimental setup of the subsurface condenser is also built and used to verify the developed model of the subsurface condenser. The... 

Nowadays, the world is facing a shortage of fresh water. Utilizing adsorbent materials to adsorb air moisture is a suitable method for producing freshwater, especially combining the adsorption desalination system with solar energy devices such as solar collectors. The low temperature of solar collectors has caused some water to remain in the adsorbents in the desorption process and has reduced the possibility of using these systems. In this research, for the first time, an evacuated tube collector (ETC) is used as an adsorbent bed so that the temperature of the desorption process reaches higher values and as a result, more fresh water is expected to produced. In this study, two adsorption... 

The thermal energy received by each surface of an Earth-orbiting satellite strongly depends on its position and orientation. In this sense, simultaneous orbit and attitude estimation (SOAE) using the surface temperature data has been focused in the present study. The Earth infrared (IR) radiation and the Earth's top-of-atmosphere (TOA) albedo are two key sources of radiation affecting the satellite surface temperature rate. The Earth's radiation information has been monitored for the past two decades by the Clouds and the Earth's Radiant Energy System (CERES) project, producing a comprehensive set of Earth radiation budget (ERB) data for climate, weather and applied science research. The... 

A comprehensive investigation of historical hydro-climatic changes at a county level is an essential prerequisite of developing any adaptation or mitigation strategies to deal with the destructive impacts of climate change. In this study, spatial distributions and trends in thirty-seven hydro-climatic mean and extreme indices across Iran were analyzed based on the state-of-the-art reanalysis datasets (ERA5-Land and AgERA5) at the county level from 1986 to 2015 using several nonparametric approaches such as multiple modified Mann–Kendall statistical tests and Sen’s Slope estimator. Their interannual oscillations were also examined using continuous wavelet transform to portray a complete... 

In this research, for the first time, the effect of primary particles (boulders) and secondary particles (fines) in organic mixtures of coffee, black walnut hull, madder, and tea (which are cheap, abundant, and biodegradable) on the improvement of solar stills' daily efficiency is evaluated as an alternative to metal-based nanofluids. A laboratory still simulator is utilised under laboratory conditions to measure the organic mixture's behaviour accurately. Furthermore, the effect of the concentration of organic mixtures and the particle size of organic materials are investigated, as well as the effect of boulders and fines, independently. In addition, two identical solar still systems are... 

Solar-driven ejector refrigeration (SER) systems have been granted special attention as a green and sustainable replacement for conventional vapor compression cooling systems. However, despite their significant advantages, SER systems suffer from a relatively low coefficient of performance and failure at high ambient temperatures and low solar radiations. Therefore, the need for an auxiliary heat source and cooling system has hindered their adoption in practice. In an attempt to eliminate the need for an auxiliary heat source and cooling system, this contribution puts forward a novel Solar-driven Multi-Ejector Refrigeration (SMER) system with an internal heat exchanger, a regenerator, and a... 

This paper proposes a new energy management model for residential buildings to handle the uncertainties of demand and on-site PV generation. For this purpose, the building energy management system (BEMS) organizes a transactive energy (TE) market among plug-in electric vehicles (PEVs) to determine their charge/discharge scheduling. According to the proposed TE framework, the PEV owners get reimbursed by the BEMS for the flexibility they offer. In this regard, the PEV owners submit their response curves for reimbursement upon arrival. Then, the BEMS solves an optimization problem to maximize its own profit and determine the real-time TE market-clearing price. Afterward, based on the clearing... 

Due to the accelerated climate change, it is anticipated that the number and severity of natural disasters such as hurricanes, blizzards, and floods will be increased in the coming years. In this regard, this paper presents a distribution system planning model to improve the system resilience against hurricane. A scenario-based mathematical model is proposed to capture the random nature of weather events. Moreover, a stochastic optimization model is developed to simultaneously harden the distribution lines and place different types of distributed generation (DG) units such as microturbines (MTs), wind turbines (WTs), and photovoltaic cells (PVs). The conditional value at risk (CVaR) is used... 

The bifacial photovoltaic/thermal module is an emerging concept that can provide electricity and heat simultaneously, taking advantage of both front and rear sides of the panel; therefore, exhibiting a better performance compared to a conventional photovoltaic module or photovoltaic thermal module. In this study, four configurations of the bifacial photovoltaic/thermal module with different cooling methods have been proposed, i.e., cooling performed at either the upper or the lower surface, in parallel (applied to both upper and lower surfaces having similar start/endpoints), and swinging air back and forth (by guiding the air over the upper and lower surfaces, respectively). The... 

Switchable photochromic dyes have benefited greatly from the use of heterocyclic chemicals. The imidazole group is particularly essential because it can be transformed into dimers, which can then be radicalized in the presence of light photons. Imidazole dimers have been optimized throughout thirty years of research, allowing derivatives with diverse colors, quick reversibility, and sensitivity to different wavelengths from UV to near IR ranges. These imidazole dimers are interesting to be used in the matrices of polymers, hydrogels, glasses, solar cells, and even pharmaceuticals. The goal of this review is to look at the history, development, and future of imidazole dimers. We will also... 

Perovskite solar cells (PSCs) have shown rapid progress in a decade of extensive research and development, aiming now towards commercialization. However, the development of more facile, reliable, and reproducible manufacturing techniques will be essential for industrial production. Many lamination methods have been initially designed for organic photovoltaics (OPVs), which are conceptually similar to PSCs. Lamination could provide a low-cost and adaptable technique for the roll-to-roll production of solar cells. This review presents an overview of lamination methods for the fabrication of PSCs and OPVs. The lamination of different electrodes consisting of various materials such as metal back... 

Current energy systems face multiple problems related to inflation in energy prices, reduction of fossil fuels, and greenhouse gas emissions which are disturbing the comfort zone of energy consumers and the affordability of power for large commercial customers. These kinds of problems can be alleviated with the help of optimal planning of demand response policies and with distributed generators in the distribution system. The objective of this article is to give a strategic proposition of an energy management system for a campus microgrid (µG) to minimize the operating costs and to increase the self-consuming energy of the green distributed generators (DGs). To this end, a real-time based... 

The power-to-liquid concept is a promising strategy to convert the power plants' flue gas to value-added liquid fuels using renewable energy. This technology could potentially reduce global greenhouse gases emissions and mitigate the environmental problems associated with the fossil fuels industry. In this regard, the main objective of the present study is to propose a novel power-to-liquid plant for the synthesis of formic acid and ammonia from power plants' flue gas, emphasizing the role of electrochemical technologies and renewable energy. The system's basis is developed by the integration of CO2 electroreduction cell, alkaline water electrolysis cell, and photovoltaic panel technologies.... 

Renewable hydrogen production plays a key role in transitioning to a hydrogen economy. For this, developing countries are encouraged to keep up with industrialized nations. As such, this study seeks to evaluate the potential of all capital cities of Iran in terms of solar-based hydrogen production and prioritize the nominated alternatives. This step is highly valued because finding the most suitable place for this purpose can lead to substantial outcomes and consequently avoid failure. Therefore, here a 20-kW solar power plant is simulated by PVsyst 6.7 software and meteorological data of 31 capital cities is extracted using Meteonorm 7.1 software. Considering all losses associated with... 

In this paper, a new configuration of a solar combined cooling, heating, and power (CCHP) system is proposed to recover the waste thermal energy of a steam power plant, which provides the cooling and heating needs of an apartment complex located in Tehran. The required energy of the system is supplied by the parabolic trough solar collectors (PTCs) and, if necessary, an auxiliary heater is also used. An ejector refrigeration cycle (ERC) and a steam Rankine cycle are used for cooling and power generation, respectively. The cycle is dynamically modeled over a year using a TRNSYS-EES co-simulator. It is found that the highest Rankine cycle efficiency is obtained in the cold months (January)... 

In this study, we perform numerical simulations to investigate the thermal and flow characteristics of a parabolic trough solar collector equipped with a porous receiver tube and internal longitudinal fins. The heat transfer medium is a synthetic oil-Cu-Al2O3 hybrid nanofluid. We examine the thermal characteristics of the nanofluid in response to variations in several system parameters. We find that at Reynolds numbers between 5 × 103 and 5 × 105, increasing the volume fraction of Cu nanoparticles can increase the temperature gain at the exit of the receiver tube by 6.4%. Furthermore, the temperature gradient in the cross-section of the collector increases as the direct normal solar...