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    Selecting a Surfactant for Wettability Alteration In Iranian Carbonate Reservoirs

    , M.Sc. Thesis Sharif University of Technology Zangeneh Var, Alireza (Author) ; Bastani, Daruoosh (Supervisor) ; Badakhshan, Amir (Supervisor)
    Abstract
    Fractured carbonate reservoirs are mostly oil-wet to intermediate-wet. Due to the negative capillary pressure of the matrix poor spontaneous imbibition of reservoir brine occurs in such reservoirs, and water flooding leads into early break through due to the high conductivity of the fracture network. Some surfactants have the ability to change the wettability of rock matrix toward water-wet state by adsorbing onto the rock surface. The phenomenon can result in spontaneous imbibition improvement and thereby increasing water flooding efficiency and recovery from fractured carbonate reservoirs. In this thesis the effect of some surfactants on the wettability of Iranian carbonate reservoir rocks... 

    Simulator Development for 3-Dimensional 2-Phase Flow in Heterogeneous Porous Media Using Green Element Method

    , M.Sc. Thesis Sharif University of Technology Bagherinezhad, Abolfazl (Author) ; Pishvaie, Mahmoud Reza (Supervisor) ; Jamshidi, Saeed (Supervisor)
    Abstract
    In this study, the green element method is used to model petroleum problems such as oil production due to expansion mechanism, one and two dimensional spontaneous imbibition and water flooding. Despite of boundary element method that its applications in reservoir engineering are limited to simulation of single phase fluid flow in homogenous media, green element method can solve multi-phase flow in heterogamous media. In this thesis, by this method the governing partial differential equation for these processes are modeled and then solved. In one dimensional medium, green element method can successfully simulate the oil production from heterogamous reservoir due to expansion mechanism. The... 

    Simulation of Spontaneous Capilary Imbibition and Gravity Effects on Oil Recovery in Naturally Fractured Reservoirs  

    , M.Sc. Thesis Sharif University of Technology Bassirian, Mostaafa (Author) ; Jamshidi, Saeed (Supervisor) ; Bozorgmehri, Ramin (Supervisor)
    Abstract
    Oil reservoirs, have integrated identity; that is they consist of different parameters such as wettablity, initial water saturation, capillary and gravity forces, etc. which are related to each other and affect ultimate recovery simultaneously. In fractured reservoirs, other parameters such as fractures and complex geological structures are also considered  among  important  parameters  which  affect  ultimate  recovery.  Due  to  large  amount  of reserves,  fractured  reservoirs  are  subject  to  different  studies  and  simulations.  In  this  research, different  parameters  which  affect  ultimate  recovery  in  fractured  reservoirs,  are  studied  and simulated. Different  studies ... 

    Experimental Investigation of Mechanism of Wettability Alteration Induced By Hot Water and Steam Injection

    , M.Sc. Thesis Sharif University of Technology Salehi, Afshin (Author) ; Masihi, Mohsen (Supervisor)
    Abstract
    One of the most important production mechanisms of fractured reservoirs is wettability alteration. Since most fractured reservoirs are carbonate, and thus are often oil-wet; production of these reservoirs is facing their special challenges. Since most of our country reservoirs are fractured carbonate type, determination of the exact mechanisms of their production is necessary. Thermal EOR methods traditionally have been welcomed by big oil companies. Also, these methods of enhanced oil recovery techniques, have a much greater share in the production history of all EOR methods, rather than other EOR methods. Exponentially decreasing of oil viscosity on heating, is the main reason for using... 

    Experimental Investigation of Surface Properties and Wettability Using Super Gas Wetting Surface Modified Multi-Nano-Composites

    , M.Sc. Thesis Sharif University of Technology Shayesteh, Mohammad (Author) ; Ghazanfari, Mohammad Hossein (Supervisor) ; Fakhroueian, Zahra (Supervisor)
    Abstract
    Recently, the researchers try to identify the application of nanofluids for wettability alteration. Changing the wettability of reservoirs, which gas injects to them, to gas wet can lead to enhanced oil recovery. Although several studies have been conducted to introduce proper nanofluids for altering the wettability of reservoirs to gas wet, there is not enough study to investigate the application of nanocomposites for wettability alteration of carbonate reservoirs. In this study, 20 nanoparticles with different compositional structures were synthesized, and then various nanofluids were prepared for the experimental survey. Also, the potential of these nanofluids for wettability alteration... 

    Investigation of Low Salinity Waterflooding Predictive Capability and the Development of a Tool for Screening Candidates

    , M.Sc. Thesis Sharif University of Technology Golmohammadi, Meysam (Author) ; Mahani, Hassan (Supervisor) ; Ayatollahi, Shahab (Supervisor)
    Abstract
    Among different enhanced oil recovery (EOR) methods, low salinity waterflooding (LSWF) has been attractive to researchers because of its relative simplicity and lower environmental problems compared to other conventional EOR methods. Numerous researchers have attempted to find the main cause of the low salinity effect (LSE). According to previous studies, several experimental techniques have been proposed for predicting LSE and screening potential field candidates. However, there is a lack of a systematic investigation of all (or even some of) the methods to compare and determine their LSE predictive capability. Predictive capability development is essential because it saves costs and time... 

    The effect of nanoparticles on spontaneous imbibition of brine into initially oil-wet sandstones

    , Article Energy Sources, Part A: Recovery, Utilization and Environmental Effects ; Volume 41, Issue 22 , 2019 , Pages 2746-2756 ; 15567036 (ISSN) Sobhani, A ; Ghasemi Dehkordi, M ; Sharif University of Technology
    Taylor and Francis Inc  2019
    Abstract
    In this paper, the effect of silica nanoparticles on oil production due to the spontaneous imbibition of brine into oil-wet sandstones has been studied. The imbibed fluids were NaCl 3 wt. % solutions containing various concentrations of nanoparticles and the recovered oil for each solution was compared. The results revealed that nanoparticles yielded more oil recovery. Nanofluid was used after brine imbibition, and the oil recovery increased from 17.8% to 40% while in the case of using the same nanofluid as the first imbibed fluid the oil recovery was 53%. Also, the results indicated that the oil recovery depends on nanoparticle concentrations. © 2019, © 2019 Taylor & Francis Group, LLC  

    Incorporation of viscosity scaling group into analysis of MPMS index for laboratory characterization of wettability of reservoir rocks

    , Article Journal of Petroleum Exploration and Production Technology ; Volume 7, Issue 1 , 2017 , Pages 205-216 ; 21900558 (ISSN) Mirzaei Paiaman, A ; Saboorian Jooybari, H ; Masihi, M ; Sharif University of Technology
    Springer Verlag  2017
    Abstract
    Wettability is a key parameter affecting petrophysical properties of reservoir rocks. Mirzaei-Paiaman et al. (Energy Fuels 27:7360–7368, 2013) presented an index (referred to as MPMS) for laboratory characterization of wettability of native- or restored-state reservoir rock samples. To use this index two counter-current spontaneous imbibition (COUCSI) experiments are needed, one on the native- or restored-state core sample and another on the strongly water-wet (SWW) reference system. Slope analysis of recovery data in these two systems gives inputs for determination of MPMS index. The two systems must have the same pore structure, initial water saturation, and viscosity ratio. The case of... 

    Experimental study on enhanced oil recovery by low salinity water flooding on the fractured dolomite reservoir

    , Article Iranian Journal of Chemistry and Chemical Engineering ; Volume 40, Issue 5 , 2021 , Pages 1703-1719 ; 10219986 (ISSN) Ebrahimzadeh Rajaee, S ; Gerami, S ; Safekordi, A. A ; Bahramian, A. R ; Ganjeh Ghazvini, M ; Sharif University of Technology
    Iranian Institute of Research and Development in Chemical Industries  2021
    Abstract
    Enhanced Oil Recovery from carbonate reservoirs is a major challenge especially in naturally fractured formations where spontaneous imbibition is a main driving force. The Low Salinity Water Injection (LSWI) method has been suggested as one of the promising methods for enhanced oil recovery. However, the literature suggests that LSWI method, due to high dependence on rock mineralogy, injected and formation water salt concentration, and complexity of reactions is not a well-established technology in oil recovery from carbonate reservoirs. The underlying mechanism of LSWI is still not fully understood. Due to lack of LSWI study in free clay dolomite fractured reservoir, and to investigate of... 

    Brine composition effect on the oil recovery in carbonate oil reservoirs: A comprehensive experimental and CFD simulation study

    , Article Journal of Petroleum Science and Engineering ; Volume 191 , August , 2020 Fattahi Mehraban, M ; Rostami, P ; Afzali, S ; Ahmadi, Z ; Sharifi, M ; Ayatollahi, S ; Sharif University of Technology
    Elsevier B. V  2020
    Abstract
    In order to understand the potential role of divalent ions involved in smart water, fluid-fluid and rock-fluid interactions are studied through contact angle and interfacial tension (IFT) measurements. Then, the suitable brines in changing contact angle and IFT are brought into measurement with spontaneous imbibition experiments to evaluate the co-impact of fluid-fluid and rock-fluid interactions. The results show the importance of SO42− ions during smart water injection as removing them from the injection water leads to a sharp drop in ultimate oil recovery. Accordingly, when the concentration of SO42− within the injection water increases four times, 10% ultimate oil recovery is recovered.... 

    Wettability alteration and oil recovery by spontaneous imbibition of low salinity brine into carbonates: Impact of Mg2+, SO4 2− and cationic surfactant

    , Article Journal of Petroleum Science and Engineering ; Volume 147 , 2016 , Pages 560-569 ; 09204105 (ISSN) Karimi, M ; Al-Maamari, R. S ; Ayatollahi, S ; Mehranbod, N ; Sharif University of Technology
    Elsevier B.V  2016
    Abstract
    A large amount of the discovered oil reserves are reserved in carbonate formations, which are mostly naturally fractured oil-wet. Wettability alteration towards more water-wet state reduces the capillary barrier, hence improving the oil recovery efficiency in such reservoirs. In this study, wettability alteration towards favorable wetting state was investigated by combining modified low salinity brine with surfactant during water flooding. The diluted brine was modified by increasing the concentration of Mg2+ and SO4 2−, individually as well as both ions in combination. Different brine formulations were tested experimentally through the observations of contact angle measurements and... 

    Application of a water based nanofluid for wettability alteration of sandstone reservoir rocks to preferentially gas wetting condition

    , Article Journal of Molecular Liquids ; Volume 232 , 2017 , Pages 351-360 ; 01677322 (ISSN) Erfani Gahrooei, H. R ; Ghazanfari, M. H ; Sharif University of Technology
    Elsevier B.V  2017
    Abstract
    Condensate and water banking around gas condensate wells result in vital well deliverability issues. Wettability alteration of near wellbore region to gas wetting condition is known to be the most novel and the only permanent method, to improve condensate well productivity. In this work, a water based nanofluid is used to change the wettability of sandstone reservoir rocks from strongly liquid wetting to intermediate gas wetting condition. Static contact angle measurements demonstrated significant increase of liquid phase contact angle as a result of chemical treatment with SurfaPore M nanofluid. The characteristics of SurfaPore M adsorption on sandstone rock are quantified through kinetic... 

    Experimental study of dynamic imbibition during water flooding of naturally fractured reservoirs

    , Article Journal of Petroleum Science and Engineering ; Volume 174 , 2019 , Pages 1-13 ; 09204105 (ISSN) Harimi, B ; Masihi, M ; Mirzaei Paiaman, A ; Hamidpour, E ; Sharif University of Technology
    Elsevier B.V  2019
    Abstract
    Capillary imbibition is an important recovery mechanism in naturally fractured reservoirs when water-filled fractures surround water-wet matrix blocks. A large amount of studies of imbibition process is simply total or partial immersion of nonwetting phase saturated rock in aqueous wetting phase. However, water advance in fractures during water flooding or water encroachment from an active aquifer introduces time dependent boundary conditions where invariant exposure of rock surface to water is not representative. In this work, a laboratory simulated matrix-fracture system was used to investigate different aspects of imbibition in the presence of fracture fluid flow (namely dynamic... 

    Wettability alteration in carbonates during "Smart Waterflood": Underling mechanisms and the effect of individual ions

    , Article Colloids and Surfaces A: Physicochemical and Engineering Aspects ; Volume 487 , 2015 , Pages 142-153 ; 09277757 (ISSN) Rashid, S ; Mousapour, M. S ; Ayatollahi, S ; Vossoughi, M ; Beigy, A. H ; Sharif University of Technology
    Elsevier  2015
    Abstract
    There are increasing evidences that adjusting the chemistry of the injecting water improves the oil recovery efficiency. However, the underlying mechanisms for this technique which is referred to as "smart waterflood" have not yet been thoroughly understood. It is needed to explore the role of individual ions through set of different tests, to find the right mechanisms behind "smart waterflood". This study is focused on the fluid/solid (carbonate) interactions through systematic wettability measurement. Contact angle measurements accompanied by spontaneous imbibition tests were employed to determine the role of individual monovalent and divalent ions in wettability alteration process by... 

    Experimental study of some important factors on nonwetting phase recovery by cocurrent spontaneous imbibition

    , Article Journal of Natural Gas Science and Engineering ; 2015 ; 18755100 (ISSN) Hamidpour, E ; Mirzaei Paiaman, A ; Masihi, M ; Harimi, B ; Sharif University of Technology
    Elsevier  2015
    Abstract
    Spontaneous imbibition, defined as the displacement of nonwetting phase by wetting phase in porous media by action of capillary forces, is important in many applications within earth sciences and in particular in naturally fractured oil and gas reservoirs. Hence, it is critical to investigate the various aspects of this process to correctly model the fractured reservoir behavior. In this study, twenty four experiments were conducted to study the effect of rock properties, lithology of porous medium, brine viscosity and boundary conditions on displacement rate and final recovery by cocurrent spontaneous imbibition (COCSI) in brine-oil systems. The results can be extended to brine-gas systems,... 

    Numerical modeling of water oil two-phase flow during counter-current spontaneous imbibition in porous media at pore-scale

    , Article Petroleum Science and Technology ; Volume 38, Issue 24 , October , 2020 , Pages 1040-1053 Jafari, I ; Rokhforouz, M. R ; Sharif University of Technology
    Bellwether Publishing, Ltd  2020
    Abstract
    In this work, phase-field method is used to develop a numerical model to simulate two-phase flow through a heterogeneous fractured porous medium. Various sensitivity analyses were performed to assess the impact of wettability, fracture aperture, interfacial tension, and water injection velocity on the displacement process. It was observed that the water mass imbibed into the matrix block varies linearly with time before the water front meets the outlet, known as “filling fracture” regime, which is captured for the first time in a numerical study. It is revealed that increasing the fracture aperture reduces water breakthrough time and oil recovery. © 2020 Taylor & Francis Group, LLC  

    Phase-field simulation of counter-current spontaneous imbibition in a fractured heterogeneous porous medium

    , Article Physics of Fluids ; Volume 29, Issue 6 , 2017 ; 10706631 (ISSN) Rokhforouz, M. R ; Akhlaghi Amiri, A ; Sharif University of Technology
    American Institute of Physics Inc  2017
    Abstract
    Spontaneous imbibition is well-known to be one of the most effective processes of oil recovery in fractured reservoirs. However, the detailed pore-scale mechanisms of the counter-current imbibition process and the effects of different fluid/rock parameters on this phenomenon have not yet been deeply addressed. Thiswork presents the results of a newpore-level numerical study of counter-current spontaneous imbibition, using coupled Cahn-Hilliard phase field and Navier-Stokes equations, solved by a finite element method. A 2D fractured medium was constructed consisting of a nonhomogeneous porous matrix, in which the grains were represented by an equilateral triangular array of circles with... 

    An approach for the estimation of dynamic imbibition capillary pressure curves

    , Article Energy Sources, Part A: Recovery, Utilization and Environmental Effects ; Vol. 36, issue. 9 , Dec , 2010 , p. 1007-1017 ; ISSN: 15567036 Shojaadini Ardakany, M ; Shadizadeh, S.R ; Masihi, M ; Kharrat, R ; Ghazanfari, M. H ; Sharif University of Technology
    Abstract
    Capillary pressure is one of the most important parameters for reservoir engineering studies. Although different experimental methods are devised to measure capillary pressure, these methods do not represent the physics of fluid flow, which happens at reservoir conditions. Thus, it is attempted to extract the capillary pressure from spontaneous imbibition data, the common mechanism of oil production in water wet porous media. In this work, a new approach is developed to obtain the imbibition capillary pressure curve by using spontaneous water imbibition data in oil-water-rock systems. Comparison of calculated imbibition capillary pressure curves by the new approach with experimental values... 

    Index for characterizing wettability of reservoir rocks based on spontaneous imbibition recovery data

    , Article Energy and Fuels ; Vol. 27, issue. 12 , November , 2013 , p. 7360-7368 ; ISSN: 08870624 Mirzaei-Paiaman, A ; Masihi, M ; Standnes, D. C ; Sharif University of Technology
    Abstract
    An index for characterizing wettability of reservoir rocks is presented using slope analysis of spontaneous imbibition recovery data. The slope analysis is performed using the known exact analytical solution to infinite acting period of counter-current spontaneous imbibition. The proposed theoretically based wettability index offers some advantages over existing methods: (1) it is a better measure of the spontaneous imbibition potential of rock (because the magnitude is directly proportional to the imbibition rate); (2) there is no need for forced displacement data; (3) there is no need for waiting until the spontaneous imbibition process ceases completely; and (4) the data needed to run the... 

    Scaling equations for oil/gas recovery from fractured porous media by counter-current spontaneous imbibition: From development to application

    , Article Energy and Fuels ; Vol. 27, issue. 8 , July , 2013 , p. 4662-4676 ; ISSN: 08870624 Mirzaei-Paiaman, A ; Masihi, M ; Sharif University of Technology
    Abstract
    Spontaneous imbibition, the capillary-driven process of displacing the nonwetting phase by the wetting phase in porous media, is of great importance in oil/gas recovery from matrix blocks of fractured reservoirs. The question of how properly scaling up the recovery by counter-current spontaneous imbibition has been the subject of extensive research over decades, and numerous scaling equations have been proposed. As a convention, the scaling equations are usually defined analytically by relating the early time squared recovery to squared pore volume. We show this convention does not apply to common scaling practices and, if used, causes nontrivial scatter in the scaling plots. We explain that...