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    Selecting a Surfactant for Wettability Alteration In Iranian Carbonate Reservoirs

    , M.Sc. Thesis Sharif University of Technology Zangeneh Var, Alireza (Author) ; Bastani, Daruoosh (Supervisor) ; Badakhshan, Amir (Supervisor)
    Abstract
    Fractured carbonate reservoirs are mostly oil-wet to intermediate-wet. Due to the negative capillary pressure of the matrix poor spontaneous imbibition of reservoir brine occurs in such reservoirs, and water flooding leads into early break through due to the high conductivity of the fracture network. Some surfactants have the ability to change the wettability of rock matrix toward water-wet state by adsorbing onto the rock surface. The phenomenon can result in spontaneous imbibition improvement and thereby increasing water flooding efficiency and recovery from fractured carbonate reservoirs. In this thesis the effect of some surfactants on the wettability of Iranian carbonate reservoir rocks... 

    Simulator Development for 3-Dimensional 2-Phase Flow in Heterogeneous Porous Media Using Green Element Method

    , M.Sc. Thesis Sharif University of Technology Bagherinezhad, Abolfazl (Author) ; Pishvaie, Mahmoud Reza (Supervisor) ; Jamshidi, Saeed (Supervisor)
    Abstract
    In this study, the green element method is used to model petroleum problems such as oil production due to expansion mechanism, one and two dimensional spontaneous imbibition and water flooding. Despite of boundary element method that its applications in reservoir engineering are limited to simulation of single phase fluid flow in homogenous media, green element method can solve multi-phase flow in heterogamous media. In this thesis, by this method the governing partial differential equation for these processes are modeled and then solved. In one dimensional medium, green element method can successfully simulate the oil production from heterogamous reservoir due to expansion mechanism. The... 

    Simulation of Spontaneous Capilary Imbibition and Gravity Effects on Oil Recovery in Naturally Fractured Reservoirs  

    , M.Sc. Thesis Sharif University of Technology Bassirian, Mostaafa (Author) ; Jamshidi, Saeed (Supervisor) ; Bozorgmehri, Ramin (Supervisor)
    Abstract
    Oil reservoirs, have integrated identity; that is they consist of different parameters such as wettablity, initial water saturation, capillary and gravity forces, etc. which are related to each other and affect ultimate recovery simultaneously. In fractured reservoirs, other parameters such as fractures and complex geological structures are also considered  among  important  parameters  which  affect  ultimate  recovery.  Due  to  large  amount  of reserves,  fractured  reservoirs  are  subject  to  different  studies  and  simulations.  In  this  research, different  parameters  which  affect  ultimate  recovery  in  fractured  reservoirs,  are  studied  and simulated. Different  studies ... 

    Experimental Investigation of Mechanism of Wettability Alteration Induced By Hot Water and Steam Injection

    , M.Sc. Thesis Sharif University of Technology Salehi, Afshin (Author) ; Masihi, Mohsen (Supervisor)
    Abstract
    One of the most important production mechanisms of fractured reservoirs is wettability alteration. Since most fractured reservoirs are carbonate, and thus are often oil-wet; production of these reservoirs is facing their special challenges. Since most of our country reservoirs are fractured carbonate type, determination of the exact mechanisms of their production is necessary. Thermal EOR methods traditionally have been welcomed by big oil companies. Also, these methods of enhanced oil recovery techniques, have a much greater share in the production history of all EOR methods, rather than other EOR methods. Exponentially decreasing of oil viscosity on heating, is the main reason for using... 

    Experimental Investigation of Surface Properties and Wettability Using Super Gas Wetting Surface Modified Multi-Nano-Composites

    , M.Sc. Thesis Sharif University of Technology Shayesteh, Mohammad (Author) ; Ghazanfari, Mohammad Hossein (Supervisor) ; Fakhroueian, Zahra (Supervisor)
    Abstract
    Recently, the researchers try to identify the application of nanofluids for wettability alteration. Changing the wettability of reservoirs, which gas injects to them, to gas wet can lead to enhanced oil recovery. Although several studies have been conducted to introduce proper nanofluids for altering the wettability of reservoirs to gas wet, there is not enough study to investigate the application of nanocomposites for wettability alteration of carbonate reservoirs. In this study, 20 nanoparticles with different compositional structures were synthesized, and then various nanofluids were prepared for the experimental survey. Also, the potential of these nanofluids for wettability alteration... 

    Investigation of Low Salinity Waterflooding Predictive Capability and the Development of a Tool for Screening Candidates

    , M.Sc. Thesis Sharif University of Technology Golmohammadi, Meysam (Author) ; Mahani, Hassan (Supervisor) ; Ayatollahi, Shahab (Supervisor)
    Abstract
    Among different enhanced oil recovery (EOR) methods, low salinity waterflooding (LSWF) has been attractive to researchers because of its relative simplicity and lower environmental problems compared to other conventional EOR methods. Numerous researchers have attempted to find the main cause of the low salinity effect (LSE). According to previous studies, several experimental techniques have been proposed for predicting LSE and screening potential field candidates. However, there is a lack of a systematic investigation of all (or even some of) the methods to compare and determine their LSE predictive capability. Predictive capability development is essential because it saves costs and time... 

    An approach for the estimation of dynamic imbibition capillary pressure curves

    , Article Energy Sources, Part A: Recovery, Utilization and Environmental Effects ; Vol. 36, issue. 9 , Dec , 2010 , p. 1007-1017 ; ISSN: 15567036 Shojaadini Ardakany, M ; Shadizadeh, S.R ; Masihi, M ; Kharrat, R ; Ghazanfari, M. H ; Sharif University of Technology
    Abstract
    Capillary pressure is one of the most important parameters for reservoir engineering studies. Although different experimental methods are devised to measure capillary pressure, these methods do not represent the physics of fluid flow, which happens at reservoir conditions. Thus, it is attempted to extract the capillary pressure from spontaneous imbibition data, the common mechanism of oil production in water wet porous media. In this work, a new approach is developed to obtain the imbibition capillary pressure curve by using spontaneous water imbibition data in oil-water-rock systems. Comparison of calculated imbibition capillary pressure curves by the new approach with experimental values... 

    Index for characterizing wettability of reservoir rocks based on spontaneous imbibition recovery data

    , Article Energy and Fuels ; Vol. 27, issue. 12 , November , 2013 , p. 7360-7368 ; ISSN: 08870624 Mirzaei-Paiaman, A ; Masihi, M ; Standnes, D. C ; Sharif University of Technology
    Abstract
    An index for characterizing wettability of reservoir rocks is presented using slope analysis of spontaneous imbibition recovery data. The slope analysis is performed using the known exact analytical solution to infinite acting period of counter-current spontaneous imbibition. The proposed theoretically based wettability index offers some advantages over existing methods: (1) it is a better measure of the spontaneous imbibition potential of rock (because the magnitude is directly proportional to the imbibition rate); (2) there is no need for forced displacement data; (3) there is no need for waiting until the spontaneous imbibition process ceases completely; and (4) the data needed to run the... 

    Scaling equations for oil/gas recovery from fractured porous media by counter-current spontaneous imbibition: From development to application

    , Article Energy and Fuels ; Vol. 27, issue. 8 , July , 2013 , p. 4662-4676 ; ISSN: 08870624 Mirzaei-Paiaman, A ; Masihi, M ; Sharif University of Technology
    Abstract
    Spontaneous imbibition, the capillary-driven process of displacing the nonwetting phase by the wetting phase in porous media, is of great importance in oil/gas recovery from matrix blocks of fractured reservoirs. The question of how properly scaling up the recovery by counter-current spontaneous imbibition has been the subject of extensive research over decades, and numerous scaling equations have been proposed. As a convention, the scaling equations are usually defined analytically by relating the early time squared recovery to squared pore volume. We show this convention does not apply to common scaling practices and, if used, causes nontrivial scatter in the scaling plots. We explain that... 

    Study on non-equilibrium effects during spontaneous imbibition

    , Article Energy and Fuels ; Vol. 25, issue. 7 , June , 2011 , p. 3053-3059 ; ISSN: 08870624 Mirzaei-Paiaman, A ; Masihi, M ; Standnes, D. C ; Sharif University of Technology
    Abstract
    Spontaneous imbibition of water into the matrix blocks because of capillary forces is an important recovery mechanism for oil recovery from naturally fractured reservoirs. In modeling this process, it has been assumed classically that local equilibrium is reached and, therefore, capillary pressure and relative permeability functions are only a function of water saturation, resulting in the appearance of the self-similarity condition. In some works published in the last 2 decades, it has, however, been claimed that local equilibrium is not reached in porous media, and therefore, opposite the classical local-equilibrium/self-similar approach, non-equilibrium effects should be taken into... 

    Applying a robust solution based on expert systems and GA evolutionary algorithm for prognosticating residual gas saturation in water drive gas reservoirs

    , Article Journal of Natural Gas Science and Engineering ; Vol. 21, issue , November , 2014 , p. 79-94 Tatar, A ; Yassin, M. R ; Rezaee, M ; Aghajafari, A. H ; Shokrollahi, A ; Sharif University of Technology
    Abstract
    In strong water drive gas reservoirs (WDGRs), the water encroachment in the gas zone has adverse effects on the gas mobility and causes considerable volume of gas to be trapped behind water front; therefore estimation of residual gas saturation after water influx is an important parameter in estimation of gas reservoirs with strong aquifer support. It is difficult to achieve a thorough and exact understanding of water drive gas reservoirs. It depends on several parameters of petrophysical and operational features. In majority of the previous studies about residual gas saturation, the correlations were depended on petrophysical properties such as porosity, permeability, and initial gas... 

    A new approach to counter-current spontaneous imbibition simulation using Green element method

    , Article Journal of Petroleum Science and Engineering ; Vol. 119, issue , 2014 , p. 163-168 Bagherinezhad, A ; Pishvaie, M. R ; Sharif University of Technology
    Abstract
    This paper develops a two dimensional Green element simulator based on a "compatibility-equation" algorithm for simulation of counter-current spontaneous imbibition (COUCSI) process. The Green element method is a novel computational approach based on the boundary integral theory, which is regarded as a hybrid combination of both boundary and finite element methods. The superiority of the Green element method in modeling of two phase water/oil flow is at the core of this paper. The developed simulator within the context of this proposition is explored to predict the oil recovery from a one dimensional single matrix block. The results are then compared with the experimental data, and they... 

    Index for characterizing wettability of reservoir rocks based on spontaneous imbibition recovery data

    , Article Energy and Fuels ; Volume 27, Issue 12 , November , 2013 , Pages 7360-7368 ; 08870624 (ISSN) Mirzaei Paiaman, A ; Masihi, M ; Standnes, D. C ; Sharif University of Technology
    2013
    Abstract
    An index for characterizing wettability of reservoir rocks is presented using slope analysis of spontaneous imbibition recovery data. The slope analysis is performed using the known exact analytical solution to infinite acting period of counter-current spontaneous imbibition. The proposed theoretically based wettability index offers some advantages over existing methods: (1) it is a better measure of the spontaneous imbibition potential of rock (because the magnitude is directly proportional to the imbibition rate); (2) there is no need for forced displacement data; (3) there is no need for waiting until the spontaneous imbibition process ceases completely; and (4) the data needed to run the... 

    The impact of surfactants on wettability change and level of water imbibition in relation to EOR in carbonate reservoirs

    , Article Petroleum Science and Technology ; Volume 31, Issue 20 , 2013 , Pages 2098-2109 ; 10916466 (ISSN) Zangeneh Var, A ; Bastani, D ; Badakhshan, A ; Sharif University of Technology
    2013

    Scaling equations for oil/gas recovery from fractured porous media by counter-current spontaneous imbibition: From development to application

    , Article Energy and Fuels ; Volume 27, Issue 8 , 2013 , Pages 4662-4676 ; 08870624 (ISSN) Mirzaei Paiaman, A ; Masihi, M ; Sharif University of Technology
    2013
    Abstract
    Spontaneous imbibition, the capillary-driven process of displacing the nonwetting phase by the wetting phase in porous media, is of great importance in oil/gas recovery from matrix blocks of fractured reservoirs. The question of how properly scaling up the recovery by counter-current spontaneous imbibition has been the subject of extensive research over decades, and numerous scaling equations have been proposed. As a convention, the scaling equations are usually defined analytically by relating the early time squared recovery to squared pore volume. We show this convention does not apply to common scaling practices and, if used, causes nontrivial scatter in the scaling plots. We explain that... 

    Study on non-equilibrium effects during spontaneous imbibition

    , Article Energy and Fuels ; Volume 25, Issue 7 , June , 2011 , Pages 3053-3059 ; 08870624 (ISSN) Mirzaei Paiaman, A ; Masihi, M ; Standnes, D. C ; Sharif University of Technology
    2011
    Abstract
    Spontaneous imbibition of water into the matrix blocks because of capillary forces is an important recovery mechanism for oil recovery from naturally fractured reservoirs. In modeling this process, it has been assumed classically that local equilibrium is reached and, therefore, capillary pressure and relative permeability functions are only a function of water saturation, resulting in the appearance of the self-similarity condition. In some works published in the last 2 decades, it has, however, been claimed that local equilibrium is not reached in porous media, and therefore, opposite the classical local-equilibrium/self-similar approach, non-equilibrium effects should be taken into... 

    Wettability alteration in carbonates during "Smart Waterflood": Underling mechanisms and the effect of individual ions

    , Article Colloids and Surfaces A: Physicochemical and Engineering Aspects ; Volume 487 , 2015 , Pages 142-153 ; 09277757 (ISSN) Rashid, S ; Mousapour, M. S ; Ayatollahi, S ; Vossoughi, M ; Beigy, A. H ; Sharif University of Technology
    Elsevier  2015
    Abstract
    There are increasing evidences that adjusting the chemistry of the injecting water improves the oil recovery efficiency. However, the underlying mechanisms for this technique which is referred to as "smart waterflood" have not yet been thoroughly understood. It is needed to explore the role of individual ions through set of different tests, to find the right mechanisms behind "smart waterflood". This study is focused on the fluid/solid (carbonate) interactions through systematic wettability measurement. Contact angle measurements accompanied by spontaneous imbibition tests were employed to determine the role of individual monovalent and divalent ions in wettability alteration process by... 

    Experimental study of some important factors on nonwetting phase recovery by cocurrent spontaneous imbibition

    , Article Journal of Natural Gas Science and Engineering ; 2015 ; 18755100 (ISSN) Hamidpour, E ; Mirzaei Paiaman, A ; Masihi, M ; Harimi, B ; Sharif University of Technology
    Elsevier  2015
    Abstract
    Spontaneous imbibition, defined as the displacement of nonwetting phase by wetting phase in porous media by action of capillary forces, is important in many applications within earth sciences and in particular in naturally fractured oil and gas reservoirs. Hence, it is critical to investigate the various aspects of this process to correctly model the fractured reservoir behavior. In this study, twenty four experiments were conducted to study the effect of rock properties, lithology of porous medium, brine viscosity and boundary conditions on displacement rate and final recovery by cocurrent spontaneous imbibition (COCSI) in brine-oil systems. The results can be extended to brine-gas systems,... 

    Experimental study of the chemical stimulation of Iranian fractured carbonate reservoir rocks as an EOR potential, the impact on spontaneous imbibition and capillary pressure

    , Article Scientia Iranica ; Volume 17, Issue 1 C , 2010 , Pages 37-45 ; 10263098 (ISSN) Zangeneh Var, A. R ; Bastani, D ; Badakhshan, A ; Sharif University of Technology
    2010
    Abstract
    Beside their worldwide abundance, oil recovery from fractured carbonate reservoirs is commonly low. Such reservoirs are usually oil-wet, thus, waterflooding leads into early breakthrough and low recovery due to the high conductivity of the fracture network, negative capillary pressure of the matrix and, consequently, the poor spontaneous imbibitions of water from fractures into the matrix during the course of waterflooding. In such problematic reservoirs, changing the wettability of the matrix toward water-wetness can improve spontaneous imbibition by changing the sign and, thus, the direction of capillary forces, resulting in an improvement of waterflood efficiency and, consequently, oil... 

    Green element solution of one-dimensional counter-current spontaneous imbibition in water wet porous media

    , Article Journal of Petroleum Science and Engineering ; Volume 70, Issue 3-4 , 2010 , Pages 302-307 ; 09204105 (ISSN) Biniaz Delijani, E ; Pishvaie, M. R ; Sharif University of Technology
    Abstract
    A Green Element numerical formulation is used to solve the time-dependent nonlinear one-dimensional counter-current spontaneous imbibition diffusion equation in which water enters a water wet rock spontaneously while oil escapes by flowing in the opposite direction. The Green Element Method (GEM) is an element by element approach of the boundary element method. In this new method, by generating large sparse global matrices and yet taking advantage of properties of Green's function, solution of more complicated physical problem is achievable while at the same time much less computational effort is needed rather than boundary element method (BEM). By discretizing both the boundary and problem...