Sharif Digital Repository

Seawater, which has been frequently applied in cooling and injection water systems, imposes severe pitting corrosion to mild steel. Addition of green and sustainable inhibitors based on renewable sources is one of the promising methodologies for restricting metal corrosion in chloride-containing electrolytes. In this study, for the first time, from both theoretical and experimental faces, the role of Juglans regia green fruit shell (JRS) extract as a sustainable potent corrosion inhibitor for mild steel was studied. The chemical structure of the JRS extract was deliberated by Fourier transform infrared spectroscopy (FT-IR). By electrochemical techniques including polarization, EIS and... 

Pulse-potential coelectrodeposition of reduced graphene oxide/zinc (rGO-Zn) nanocomposite coating is directly controlled upon a steel substrate from a one-pot aqueous mixture containing [GO-/Zn2+]δ+ nanoclusters. GO nanosheets are synthesized by modified Hummer's approach while Zn cations are produced in the solution and deposited on GO nanosheets using anodic dissolution technique. Eventually, nanoclusters are reduced to rGO-Zn film through an electrochemical process. Chemical composition, surface morphology, and corrosion resistance of the thin film are characterized. Results show that the corrosion resistance of rGO-Zn coating is approximately 10 times more than the bare steel. © 2018 S.... 

In this study, effects of dried saffron purple petals (SPP) powder were examined on the rheological, fluid loss, and corrosion inhibition properties of bentonite-based drilling fluids. Drilling fluids containing different amounts of the SPP powder were prepared and their rheological behavior was investigated via the rotary viscometry and rheometric mechanical spectroscopy (RMS). Rotary viscometer results were fitted with Power-law, Bingham plastic, and Herschel-Bulkley models and the obtained data were compared with that of the base mud. All models fitted the rotary viscometer data with the determination coefficients higher than 0.93. The presence of 3 wt% of the SSP in the fluid... 

One of the main concerns in cladding Inconel 625 superalloy on desired substrates is deterioration of corrosion resistance due to cladding process. The present study aims to compare the effect of fusion cladding and explosive cladding procedures on corrosion behavior of Inconel 625 cladding on plain carbon steel as substrate. Also, an attempt has been made to investigate the role of load ratio and numbers of fusion layers in corrosion behavior of explosive and fusion cladding Inconel 625 respectively. In all cases, the cyclic polarization as an electrochemical method has been applied to assess the corrosion behavior. According to the obtained results, both cladding methods aggravate the... 

Transient liquid phase bonding of AISI 304 was carried out in a vacuum furnace using a Ni-based interlayer. The effect of bonding time on microstructure and mechanical properties of joints made at temperature of 1150 ⁰C was investigated. The results showed that isothermal solidification was completed within 20 min and the eutectic phase disappeared across the joint region. The joints with complete isothermal solidification were homogenized for 180 min at a temperature of 950 ⁰C. The shear test results showed that the average shear strength of the homogenized samples was about 83% of that of the base metal at the same heat treatment cycle. Corrosion behavior of the TLP-bonded samples and the... 

Tolyltriazole (TTA) is a well-defined corrosion inhibitor for copper and copper alloys. However, there is little literature about its corrosion inhibition performance for mild steels in corrosive environments. This paper studied the electrochemical behavior of TTA in 0.5 M HCl solutions. Also, the morphology and nature of TTA layers on the steel surface were investigated. Electrochemical results showed that TTA is an excellent corrosion inhibitor for mild steel in acidic media with an efficiency of 91% for 0.07 M concentration. The results also indicated that TTA is a mixed-type inhibitor. XRD analysis revealed that the inhibition mechanism of TTA is based on the formation of an organic film... 

TiO 2 -rGO nanocomposite coatings were obtained by electrophoretic deposition (EPD) technique of TiO 2 nanoparticles and graphene oxide (GO) on stainless steel substrate. First, GO particles were synthesized using a modified Hummers' method. GO was reduced electrochemically to form a coating in the presence of nano-sized TiO 2 particles. The influences of different parameters such as GO concentration, coupling co-electro-deposition parameters (electrophoretic duration and voltage) on thickness, surface morphology and, corrosion behavior of the as-synthesized TiO 2 -rGO nanocomposite coatings were systematically surveyed. The morphology and microstructure were investigated by field emission... 

Corrosion of steel rebars in concrete can reduce the durability of concrete structures in coastal environments. The corrosion rate of these concrete structures can be reduced by using suitable concrete additives and coating on rebars. This paper investigates the corrosion resistance of steel rebars by the addition of pozzolanic materials including fly ash, silica fume, polypropylene fibers, and industrial 2-dimethylaminoethanol (FerroGard 901) inhibitors to the concrete mixture. Three different types of rebars including mild steel rebar st37, and two stainless steel reinforcements, AISI 304 and AISI 316, were used. Various types of primer and coating including alkyd based primer, hot-dip... 

Designing a novel epoxy composite system with dual self-healing/barrier anti-corrosion functions using graphene oxide (GO) nano-platforms decorated by polypyrrole (PPy) nanoparticles doped with zinc metal ions is the major objective of this research attempt. GO-PPy-Zn nanoplatform was fabricated via one-pot polymerization of pyrrole monomers on GO and two direct/indirect methods of zinc doping. In order to verify the PPy nanoparticles synthesis on GO sheets several analyses such as UV–visible, XPS, HR-TEM and FE-SEM were performed. The epoxy nanocomposite coatings containing GO-PPy and GO-PPy-Zn nanoplatforms were fabricated and applied on carbon steel. The nanocomposite coatings... 

Bipolar Plates (BPPs) are the most crucial component of the Polymer Electrolyte Membrane (PEM) fuel cell system. To improve fuel cell stack performance and lifetime, corrosion resistance and Interfacial Contact Resistance (ICR) enhancement are two essential factors for metallic BPPs. One of the most effective methods to achieve this purpose is adding a thin solid film of conductive coating on the surfaces of these plates. In the present study, 410 Stainless Steel (SS) was selected as a metallic bipolar plate. The coating process was performed using titanium nitride and chromium nitride by the Cathodic Arc Evaporation (CAE) method. The main focus of this study was to select the best coating... 

Reinforced concrete slabs are common structural elements that could be exposed to impact loading. Although use of reinforced concrete slabs and utilization of Fiber Reinforced Polymer (FRP) as alternative to traditional steel reinforcement slabs are growing, but the influence of various parameters on their response under impact loads is not properly evaluated. This study investigated the effect of rebar's material, amount and arrangement of reinforcements, concrete strength and slab thickness on dynamic behavior of reinforced concrete slabs using both laboratory experiments and numerical simulations. Performance of fifteen 1000 × 1000 mm concrete slabs, including two 75 mm thick plain slabs,... 

The effect of some inhibitors consisting of sodium nitrite (NaNO 2), sodium nitrate (NaNO 3), sodium molybdate (Na 2MoO 4), and sodium silicate (Na 2SiO 3) on the corrosion behavior of aluminum alloy 3303 (UNS A93303) in a water and ethylene glycol (C 2H 6O 2) mixture was investigated. In the first part, the tests were established without any galvanic coupling. In the second part, the tests were established with galvanic connections between the aluminum alloy and mild steel, stainless steel, copper, brass, and solder. Results show that the best corrosion inhibitor in both situations is sodium nitrate, according to its abilities to reduce corrosion rate, passivate the aluminum surface, and... 

In this research, the ZnOG hybrid thin film was produced via solgel method. The surface morphology, band gap and photoactive properties of the films were studied by means of SEM, UV–Vis and photoluminescence analysis. In addition, the ability of the thin film in photocathodic protection of carbon steel (CS) and 304 stainless steel in 3.5 wt.% NaCl and Na2S solutions under dark and UV illumination was investigated by polarization test as well as OCP and current measurements during coupling of steels with ZnOG photoanode. The mix band gap is reduced to the orders of 1.17 eV through hybridization of ZnO with graphene oxide. In both NaCl and Na2S solutions, the ZnOG thin film could effectively... 

Effects of post weld heat treatment (PWHT) on mechanical properties and corrosion behavior of NiTi shape memory wire, laser welded to the 304 stainless steel wire were investigated. The results showed that PWHT at 200 °C increased corrosion resistance and tensile strength of the joint up to ~1.8 times that of the as-weld joint, with no heat treatment. On the contrary, precipitation of neoteric intermetallic compounds like Fe2Ti, Cr2Ti, FeNi, Ni3Ti, and Ti2Ni in the welded region deteriorated these properties, when PWHT was conducted at 400 °C. Due to the vital effects of the PWHT performed after the laser welding, careful control of the PWHT temperature was found to be a prerequisite for... 

In this work, we synthesized carbon hollow spheres (CHSs) using the silica templating method, encapsulated 2-mercaptobenzimidazole (MBI) inhibitor in the CHSs and evaluated their corrosion inhibition performance upon exposure of mild steel to a saline solution containing the released inhibitor. The effects of silica template surface modification on the CHS structure was evaluated, while the structure and morphology of the synthesized CHS was analyzed using field emission scanning electron microscope (FE-SEM), transmission electron microscope (TEM), Raman spectroscopy and X-ray diffraction (XRD) spectroscopy. Furthermore, thermogravimetric analysis (TGA), energy-dispersive X-ray spectroscopy... 

Electrophoretic technique was used to deposit micro- and nano-sized aluminum nitride coatings on stainless steel surfaces by using a well-dispersed stable suspension produced by addition of AlN powder plus a small amount of iodine to ethanol. Parabolic regime governed the deposition. Electrophoretic deposition for 240 s at 100 V resulted in formation of a uniformly dense film on the top, but a porous inhomogeneous layer at the bottom. This was attributed to fast deposition of coarse particles and/or agglomerates at large electric fields. After drying, micro-sized particles led to a uniform crack-free interface while nano-particles resulted in fragmented non-cohesive layers. Weight loss... 

A gas turbine which output 18MW power exploded after 3h of ordinary operation and after 4,785 starts. The turbine's rotor had undergone repair after 77,000 operating hours. A piece was cut from the failed marriage bolt and tested using atomic absorption spectrometry in order to know the grade of the alloy. It was found that the marriage bolt is made from ASTM A193 B16 steel which is suitable. Hardness and microhardness measurement was also determined and showed that it was within the range of the specified hardness for ASTM A193 B16 steel. The marriage bolt's mechanical properties also meet technical specifications and showed that it contained anti-corrosion properties. Visual examination... 

AISI 304 stainless steel is very widely used for industrial applications due to its good integrated performance and corrosion resistance. However, shot peening (SP) is known as one of the effectual surface treatments processes to provide superior properties in metallic materials. In the present study, a comprehensive study on SP of AISI 304 steel including 42 different SP treatments with a wide range of Almen intensities of 14–36 A and various coverage of 100–2000% was carried out. Varieties of experiments were accomplished for the investigation of the microstructure, grain size, surface topography, hardness and residual stresses as well as axial fatigue behavior. After experimental... 

AISI 304 stainless steel is very widely used for industrial applications due to its good integrated performance and corrosion resistance. However, shot peening (SP) is known as one of the effectual surface treatments processes to provide superior properties in metallic materials. In the present study, a comprehensive study on SP of AISI 304 steel including 42 different SP treatments with a wide range of Almen intensities of 14–36 A and various coverage of 100–2000% was carried out. Varieties of experiments were accomplished for the investigation of the microstructure, grain size, surface topography, hardness and residual stresses as well as axial fatigue behavior. After experimental... 

A new Zinc phosphating bath, which produces coatings at relatively lower temperatures within a reasonable time by using of chemical accelerators has been devised. Improvement of the bath performance by the addition of divalent cations like calcium, nickel has been studied. Bath formulation and operating conditions have been optimized by coating weight determinations. Stable samples of phosphating formulations with and without calcium and nickel salts were prepared and the structure and morphology of the phosphate coatings were determined by using X-ray diffraction (XRD) techniques, scanning electron microscopy. ASTMB117 salt spray test and electrochemical impedance spectroscopy (EIS) were...