Sharif Digital Repository

In the present study, the solubility of paracetamol in supercritical CO2 is measured at temperatures between 311 and 358 K and pressures between 95 and 265 bar. It was shown that the solubility of paracetamol through a static solubility measurement method was between 0.3055 × 10−6 to 16.3582 × 10−6 based on mole fraction. The obtained experimental solubility data revealed the direct effect of pressure on the paracetamol experimental data, while the temperature has a dual effect of both increasing and decreasing effect considering the shifting point known as crossover pressure which was measured to be around 110 bar for paracetamol. Besides, two theoretical approaches were applied to predict... 

An experimental investigation of the shock-buffet phenomenon subject to unsteady pitching supercritical airfoil around its quarter chord has been conducted in a transonic wind tunnel. The model was equipped with pressure taps connected to the fast response pressure-transducers. Measurements were conducted at different free-stream Mach number from 0.61 to 0.76. The principle goal of this investigation was to experimentally discuss the shock-buffet criterion over a SC(2)-0410 supercritical pitching related to the hysteresis loops of total drag and trailing edge pressure, the behaviour of the shock wave foot location, the pressure distribution over the upper surface, and by implementing the... 

A series of wind-tunnel tests were conducted on a Y-shaped diverterless supersonic inlet (DSI) in order to investigate its performance at various operating conditions. The present DSI was designed for a freestream Mach number of M∞ 1.65. The experiments were performed at supercritical, critical, and subcritical operating conditions and at 0 deg angle of attack and angle of side slip. The results showed that the present DSI had an acceptable performance at its design condition. A symmetric supersonic flow pattern was observed at both supercritical and critical operating conditions. At low subcritical operating conditions, the supersonic flow pattern remained symmetric too. However, at high... 

Infection is a disease that is mainly caused by different Gram-negative and Gram-positive bacteria. Treatment of infections requires a considerable amount of antibiotics, which can cause serious damage to the patient's body. Delivering the antibiotic only to the site of infection can prevent these destructive effects, such as the destruction of the normal intestinal flora. The drug delivery system through carriers will take antibiotics into a part of the body involved in the disease. Niosome nanoparticles, which have been made from non-ionic surfactants, have been emerging as ideal drug/antibiotics delivery vehicles. Recently, niosome formulations have been targeted to reduce toxicity and... 

Transcritical-CO2, supercritical-CO2, and organic Rankine cycles are numerically investigated and compared in simple Rankine, Rankine with internal heat exchanger, and regenerative Rankine configurations to assess their thermodynamic and thermoeconomic performance indicators. Subsequently, the systems are optimized using a multi-objective optimization method. Pareto optimal solutions are provided to present the trade-off between thermodynamic and thermoeconomic indicators. In addition, scatter plots of decision variables are presented to ascertain the optimal operating range of input variables. The results show that transcritical-CO2 systems can generate the highest power. The levelized cost... 

Experimental results of surface pressure distribution over a thin supercritical airfoil and its wake are presented. All tests were conducted at free stream Mach numbers ranging from 0.27 to 0.85 and at di erent angles of attacks in a transonic wind tunnel. The model was equipped with static pressure ori ces connected to high-frequency pressure transducers. The present paper evaluates variations of shock wave location with both Mach number and angle of attack variation, as well as its interaction with the boundary layer, leading to the bu et phenomenon. Note that, for this thin supercritical airfoil, there exist only a few experimental results regarding surface pressure distributions,... 

Characterization of the transcritical coaxial injectors, accounting for the geometrical features and thermodynamics nonlinearities, is of both practical and fundamental importance. In the present study, the interactions and effects of turbulent mixing and pseudo-boiling phenomena are investigated. To do this, the mixing dynamics of bi-shear jets injected under trans- and supercritical conditions has been investigated numerically using the large-eddy simulation technique. The numerical framework provides real-gas thermodynamics and transport properties, using the Peng-Robinson equation-of-state and Chung's models, respectively. The obtained flow quantities are in good agreement with the... 

The interactions and effects of turbulent mixing, pseudo-boiling phenomena, and chemical reaction heat release on the combustion of cryogenic liquid oxygen and gaseous hydrogen under supercritical pressure conditions are investigated using RANS simulations. Comparisons of the present numerical simulation results with available experimental data reveal a reasonably good prediction of a supercritical axial shear hydrogen-oxygen flame using the standard k-ε turbulence model and the eddy dissipation concept combustion model with a 23 reaction steps kinetics for H2-O2 reaction. The present simulation qualitatively reproduced oxygen injection and its reaction with the co-flowing hydrogen, which is... 

To study the gas injection scenario for successful implementation of enhanced oil recovery (EOR)processes, the prediction of interfacial tension (IFT)between injected gas and the crude oil is of paramount significance. In the present study, some intelligent methods were developed for determining IFT values between supercritical CO2 and normal alkanes. IFT was considered as a function of temperature, pressure, and molecular weight of normal alkanes. The developed methods were Multilayer perceptron (MLP), Genetic Algorithm Radial Basis Function (GA-RBF), and Conjugate Hybrid-PSO ANFIS (CHPSO-ANFIS). The average absolute percent relative errors (AAREs)for the stated techniques were found to be... 

In this article, the conjugate heat transfer of the methane coolant inside a rectangular channel is studied and the related Nusselt correlations are improved. The compressible methane flow enters the cooling channel at supercritical pressure and subcritical temperature. The coolant flow absorbs heat from the heated walls and exits the channel with a supercritical temperature. An in-house solver is developed employing Semi-Implicit Method for Pressure-Linked Equations-Consistent (SIMPLEC) algorithm accompanied by the appropriate thermodynamic and transport property relations for the supercritical conditions of the methane coolant. The solver is validated with the experimental data found in... 

Tributhyl phosphate (TBP) decomposition in supercritical water oxidation (SCWO) was performed with and without catalyst, at different temperatures ranging from 370 to 480 °C, and different reaction times. Ag2O, CuO, Fe2O3, MgO, and ZnO synthesized by supercritical water were examined in TBP decomposition as the catalyst. TBP structure decomposed under the non-catalytic reaction; nevertheless, the results indicated that the use of catalysts improved the reaction efficiency, which calculated based on total organic carbon (TOC) removal, by far. However, TOC removal using Fe2O3 was 20% higher than the non-catalytic reaction. Having the ability in completion of the redox cycle, iron oxide... 

Supercritical water was used for simultaneous fragmentation and reduction of graphene oxide (GO) sheets into water-dispersible graphene quantum dots (GQDs) with tunable sizes. Transmission electron microscopy (TEM) demonstrated that by increasing the temperature above the critical point of water, the average size and thickness of the GQDs were decreased and the size uniformity and production yield were increased. The results of thermal conductivity measurement of GQD nanofluids with different weight fractions indicated that the GQDs prepared at supercritical condition could enhance the thermal conductivity of water by 65% as compared to 35% for the GQDs synthesized at sub-critical... 

A shock control channel (SCC) is a flow control method introduced here to control the shock wave/boundarylayer interaction (SWBLI) in order to reduce the resulting wave drag in transonic flows. An SCC transfers an appropriate amount of mass and momentum from downstream of the shock wave location to its upstream to decrease the pressure gradient across the shock wave and as a result the shock-wave strength is reduced. Here, a multi-point optimization method under a constant-lift-coefficient constraint is used to find the optimum design of the SCC. This flow control method is implemented on a RAE-2822 supercritical airfoil for a wide range of off-design transonic Mach numbers. The RANS flow... 

In this study, the effect of moving pressure source and channel parameters on the generated waves in a channel was numerically investigated; draught, angle of attack, and profile shape as parameters of pressure source, and water depth and blockage factor as channel parameters for wave height. Firstly, the chosen Computational Fluid Dynamics (CFD) approach was validated with the experimental data over a range of speeds. Then, the CFD study was conducted for further investigations. It was shown that that by enlarging draught, angle of attack, and beam of the pressure source, the wave height generated would be increased. Channel study showed that it was possible to increase the wave height... 

This study investigates GH2/LOX coaxial jet flame at trans- and supercritical conditions using the Reynolds averaged Navier-Stokes approach. Four two-equation-turbulence models, three real equation of states, two chemical mechanisms, and three different chamber pressures are examined. Predictions show good agreement with measurements qualitatively and quantitatively. Based on the results, the predictions of the Soave-Redlich-Kwong equation of state (EOS) are closer to the experiment, while the Aungier-Redlich-Kwong EOS has more deviation than the others. Moreover, the k-ω shear stress transport model has better performance than the other turbulence models. It is also found that the flow... 

The effect of porosity in oscillating situations (to the authors' knowledge, for the first time) on a supercritical airfoil (SC0410) has been experimentally investigated. Tests have been carried out in an open circuit suction-type wind tunnel at a free stream Mach number of M = 0:80. Both static and dynamic (pitching) tests have been carried out on the mentioned airfoil. The oscillation frequency for the unsteady tests has been set to 3 and 6 Hz. The amplitude of frequency is ±1 deg. The effect of porosity has been surveyed on the magnitude of pressure fluctuations, phase shift, and lift coefficient loop. The investigations show that increasing porosity in the test section of transonic... 

Microalgae as a candidate for production of biodiesel, possesses a hard cell wall that prevents intracellular lipids leaving out from the cells. Direct or in situ supercritical transesterification has the potential for destruction of microalgae hard cell wall and conversion of extracted lipids to biodiesel that consequently reduces the total energy consumption. Response surface methodology combined with central composite design was applied to investigate process parameters including: Temperature, Time, Methanol-to-dry algae, Hexane-to-dry algae, and Moisture content. Thirty-two experiments were designed and performed in a batch reactor, and biodiesel efficiency between 0.44% and 99.32% was... 

In this study, the boundary layer velocity profile on the upper surface of a supercritical airfoil in a forced sinusoidal pitching motion was measured and experimentally investigated. Measurements were performed using a boundary layer rake, including total pressure tubes positioned at 25 % of the chord far from the leading edge on the upper surface. For static measurements, the effects of the angle of attack between −3° and 14° and free-stream velocity between 40 m/s and 70 m/s were investigated; for dynamic measurements, the effects of oscillation amplitude variation between ±3° and ±10°, reduced frequency from 0.007 to 0.0313, and mean angle of attack between −3° and 6° were studied during... 

Supercritical water reactor is one of the generation IV reactors which is basically a creative mixture of conventional PWRs and supercritical pressure steam boilers. Application of nanoparticles provides an effective way of improving heat transfer characteristics of conventional coolants; thus, utilization of a nanofluid coolant in the conceptual design of this reactors is quite reasonable and inevitable. Reactor coolant at supercritical pressure dose not experience any phase change and is heated up to 500 °C in three pass core design. In this paper, thermal–hydraulic analysis of applying a water base Al2O3 nanofluid with different nanoparticle mass fractions were investigated using a porous... 

Vacuum residue cracking has been successfully conducted under supercritical water condition in presence of various metal oxide nanocalysts, namely NiO, CuO, ZnO, Co2O3, and Cr2O3 synthesized at supercritical water. The cracking experiments were carried out at 450 °C. Three species of cracking: maltene, asphaltene, and coke were then weighed and their corresponding speciation was defined. Gas chromatography-mass spectrometry (GC–MS), nuclear magnetic resonance spectroscopy (NMR), thermogravimetric analysis (TGA), and elemental analysis (CHNS) tests were utilized to prove the performance of upgrading reactions. It was revealed that NiO showed the best performance among other catalyst, in which...