Sharif Digital Repository

Aluminum sulfate is widely used in water treatment as a polyelectrolyte. Its dissolution and recrystallization into nanoparticles directly affects the working conditions. This study concerns determination of the metastable zone and induction time in nucleation of aluminum sulfate nanoparticles in aqueous media and in presence of acetone as anti-solvent. Later the effect of SDS on the metastable zone and induction time are also studied.. The study also shows if the presence of anti-solvents and surface active agents can vary this phenomenon. The study also adds to our understanding of the media in creation and stabilization of nanoparticles. This project has a special focus on the changes... 

Surface Active Agents/surfactant have a strong tendency to adsorb at the interface between two immiscible fluids, due to the existence of hydrophobic portions in their molecules’ structure. Accumulation of these molecules on the liquid interface changes the intermolecular forces and causes the interfacial tension to decrease. Production of drops of the same size at a specified rate and controlling their movement’s speed are among the most important factors effective in the efficiency of processes associated with liquid drops, which could profoundly be influenced by the presence of a small amount of a surface active agent. In this study, the effects of surface active agents on the growth,... 

In this research, the characteristics of non-Newtonian, shear-thinning drop formation containing surfactant from a needle are investigated experimentally. The ambient fluid is air and all experiments have been conducted in a constant flow rate of drop phase fluid. Images of forming drop are taken using a high-speed camera and by processing them, important parameters in drop formation such as length of drop, minimum neck thickness, formation time and the size of satellite drops have been studied. Three non-Newtonian and three Newtonian fluids are considered in a way that the initial viscosity of non-Newtonian fluids would be equal to the viscosity of their corresponding Newtonian fluids.... 

The drop motion in fluid and the mass transfer is one of the most interesting and favorite topics that has attracted the attention of many researchers. Knowing the functions of the factors affecting the deformation and the process of mass transfer and the effects of the addition of the surfactant, improve the efficiency of the related industrial processes.In this regard, the present study examines how the shape and speed of a moving Newtonian drop in a Newtonian fluid, the mass transfer of soluble material from inside the drop to the surrounding fluid and also the study of the effect of surfactant on the dynamics of moving droplet is studied numerically. During the drop movement, the... 

Surfactants are materials that reduces surface tension, and this property has provided a wide range of applications for them. Most of the surfactants reduce surface tensions at the interface of two fluids. The pharmaceutical and food industries, detergents, cosmetics, agricultural pesticides, dye production and oil extraction are among these applications.In this study, the formation of droplets in the presence of three types of surfactants SDS, CTAB and Tween 20 has been investigated. To evaluate the droplet behavior in the presence of specific surfactants, various parameters such as formation time of the droplet, the diameter and length of the droplet formed, the diameter and length of the... 

Improving efficiency of heat exchangers has always been an important concern for the industry. Pulsating heat pipes are novel and efficient technology in the field of heat transfer. Pulsating heat pipes are widely used in solar water heaters, solar desalination systems, air conditioning systems, cooling of electronical boards, etc. these applications explain the necessity of performing this study in our country. In this research, thermal performance of open loop pulsating heat pipes using two operating fluids (ferrofluid with surfactant and aluminum microfluid) is experimentally investigated. Start-up and steady thermal performance of pulsating heat pipes charged with these two operating... 

Application of nanotechnology in the field of heat transfer has increased recently. The need to increase heat transfer rate yet decrease the size of cooling equipment, brought about lots of attention to thermal properties of Nanofluids. Nanofluid is the suspension of nanometer-sized solid particles in base liquid. Research on convective heat transfer of nanofluids which is only two decades old, shows great potential in increasing heat transfer rate. Although there is a remarkable research on thermal conductivity of Nanofluids, negligible research was conducted on combined Nanofluids . Developed Theory for thermal conductivity of combined nanofluid can be used to modeling the thermal... 

The purpose of this research is producing one phase silica superhydrophobic coating by sol-gel method and drying temperature less than 200 degrees. For preparing micrometer and nanometer scaled hierarchical structure based on silica, TEOS precursor and Fumed Silica nanoparticles were used by density of 43/30 cc/lit and 6/52 gr/lit in order to provide desired roughness in the range of 40 nm. Moreover, HMDS surface modifying agent was used for reducing the surface energy of coating, which is not a danger to the environment in comparison to the same substances. The best Contact Angle is 155 degree and the best Sliding Angle is less than 5 degree. For instance, it was created with the... 

The aim of this research is to study the effect of surfactant type and the concentration reactants on the size, shape and magnetic properties of iron-gold core-shell magnetic nanoparticles (NPs) useable for biomedical application. The reverse micelle procedure was employed to synthesize iron NPs using two surfactants of CTAB and SDS. A gold shell with a thickness in the range of 10 to 40 nm was induced by reverse micelle method in order to prevent oxidation of the iron core. The size and morphology of NPs were studied by transition electron microscopy (TEM). It was found that the size of NPs increases by the increasing the reactants concentration while the morphology of the NPs was not... 

A biocompatible ferrofluid have been prepared by co-precipitation of FeCl2.4H2O and FeCl3.6H2O under ultrasonic irradiation and with NaOH as alkaline agent. Also cystein was used as capping agent in the solution. Magnetic properties of the produced ferrofluid then determined by VSM test and magnetite nanoparticles were characterized by XRD and TEM techniques. Results indicate the presence of a biocompatible superparamagnetic ferrofluid including magnetite nanoparticles with particle size ranging under 15 nm. The effect of ultrasonic irradiation on presence of a sharp particle size distribution then denoted by comparing the condition with production without ultrasonic irradiation  

During all operations in hydrocarbon reservoirs, there is a possibility of formation damage. These damages can reduce the production of fluids from reservoir. One of the major damages that can seriously affect the performance of a reservoir is the damage caused by drilling fluid. The main purpose of this research is to study the main mechanisms of formation damages when using oil-based drilling fluids and fixing or preventing these damages. Once the mechanisms are identified, it is tried to cure the damages but without acid-washing. The alternative method is surfactant-washing which is a surfactant-brine injection. This injection has been done for the first time. This study helps to industry... 

Recent studies have shown that the injection of low-salinity water would enhance the oil recovery factor for both the core scale and the field test. The evidence obtained from laboratory studies showed that the control of salinity and the composition of injected water has successfully affected the oil release, hence enhancing the oil recovery efficiency. In this method, by changing the type and amount of dissolved ions in the injected water, the water/oil/rock interactions are altered. Based on this, extensive studies have been focused on the mechanisms for the trapped oil release at the pore scale. Several mechanisms have been proposed to explain this phenomenon, which can be divided... 

Enhanced Oil Recovery (EOR) techniques have become of the main priorities of the oil industry during the high oil price era. It is interesting to note that the common method to increase production from reservoirs is the water injection method, which recovers a very low amount of oil from the oil-wet matrices due to the lack of water imbibition. Previous studies have shown that changing the wettability of rock would critically increase the oil recovery efficiency. This could be achieved by the low-salinity water injection method. In recent years, extensive studies have been conducted on this technique to evaluate its effectiveness for various types of oil reservoirs. Simultaneous injection... 

One of the best stimulation methods for oil and gas wells is matrix acidizing in order to increase the near wellbore permeability. in acidizing, good acid coverage in different layers is one the main goals. so, various methods have been presented. important part in using these methods is to not damage formation and economic matters. modern methods utilize VES acids for this purpose. viscoelastic characteristics of these materials by formation of miscellaneous, increases the apparent viscosity by a large degree. for this reason, VES fluids can be used to improve acid divergence in acid injection operation. acid system based on viscoelastic surfactants that is changed to gel instantly, can be... 

Many of oil reservoirs in Iran that are fractured, do not have high Recovery Factor (RF), therefor Enhanced Oil Recovery (EOR) methods are exerted in them. In fractured reservoirs, due to high capillary pressure in matrix and low amount of it in fracture, the wetting phase tends to imbibe to the matrix from the fracture. Altering the wettability of reservoir rock from Oil-Wet (OW) to Water-Wet (WW) enables the injected water to imbibe to matrix and sweep its oil. Also reducing oil/water IFT turns oil to small droplets, helps them to pass narrow pores and be produced. In one of the new EOR methods called chemical EOR, chemical additives are injected to the reservoirs along with water to... 

Acidizing operation is performed in oil and gas reservoirs with the aim of overcoming formation damages, increasing permeability and reducing skin factor. In carbonate reservoir, the hydrochloric acid increases the permeability of the areas around the well to a more than its initial value by dissolving part of the formation minerals. Considering that most of Iran's oil and gas reservoirs are in the category of carbonate reservoirs, it is important to study the reaction kinetics of carbonate minerals and acids used in acidizing operation. The complex and multifactorial nature of the acidizing operation in the reservoirs has made it very difficult to design a successful and optimal operation.... 

Well stimulation techniques are used to increase the productivity of oil and gas wells. One of the effective well stimulation methods, is matrix acidizing. During matrix acidizing, acidic solution is injected into the formation at pressure below the formation fracture pressure. Most of the time, acid needs to be reached to low permeability layers for more efficient damage removal. Divertors are used for diverting acid from high permeability to low permeability layers.Successful performance of a viscoelastic acid during an acid job, is highly dependent on the surfactant rheological properties. For a betaine viscoelastic surfactant, we have studied the effect of different parameters on the... 

In this work, an improved model for simulating carbonate core acidizing, with the ability of correctly modeling fluid diversion in dual-core experiments is created based on an existing two-scale continuum model. The improvements are applied on the momentum transfer equation, continuity equation, pore-scale structure-property relations and fluid rheology model. Also a more realistic injection scenario and geometry configuration are presented for simulating the diversion experiments. The Darcy-Brinkman-Stokes equation is implemented instead of Darcy’s equation and the continuity equation is modified by adding the mass source term. A global rheology model is developed capable of capturing exact... 

Heterogeneity is the major cause of the uneven acid distribution in carbonate acidizing. Traditional acidizing involves the injection of mineral acids, such as hydrochloric acid into the formation, which the bulk of the acidic solution permeates into the high-permeable layers and the low-permeability layers remain unreacted. So far, many chemical and mechanical techniques have been used to avoid the uneven distribution of acid. Using surfactant-based viscoelastic acids is one of the effective chemical method to divert acid to low-permeable zones. The unique feature of these acids is increasing viscosity of acidic solution as the pH increases. In this study, a two-scale continuum model... 

The present study has been performed for better understanding about the dynamic behavior of fluid interfaces in presence of surfactants, nanoparticles and their interactions in gas-liquid dispersion systems. One of the main purposes of this work is to investigate the influence of surface modified nanoparticles on the dynamic behavior of gas-liquid interfaces. For this purpose, the rising bubble experiment was used as one of the most conventional procedures. Local velocities of bubbles rising in nanoparticle solutions were determined experimentally. Influences of silica nanoparticles which were modified via three approaches were investigated in these experiments. Heat treatment was applied to...