Sharif Digital Repository

The purpose of this study is to investigate separation performance of poly(ether-b-amide6) (Pebax1657)/glycerol triacetate (GTA) gel membranes for CO2 removal from H2, N2 and CH4. GTA as a low molecular weight and highly CO2-phill compound was added to membrane structure at various weight fractions, 20%, 40%, 60% and 80% of Pebax, to fabricate a new high solubility selective membrane with improved performance. Permeation of pure gases was studied at different temperatures from 25 to 65°C and pressures from 4 to 24bar and ideal selectivities were calculated. Results indicated enhancement in permeation for all tested gases. For example, at a pressure of 4bar and a temperature of 25°C, membrane... 

In this study, the properties of poly (vinyl alcohol)(PVA) films incorporated with Zataria multiflora essential oil (ZMO) as a potential antioxidant/antibacterial material was investigated. PVA films were prepared from PVA solutions (2% w/v) containing different concentrations of ZMO. Water solubility, moisture absorption, water swelling, and water vapor permeability for pure PVA films were 57 ± 1.1, 99 ± 3.2%, 337 ± 8%, and 0.453 ± 0.015 g mm/m2 h, respectively. Incorporation of ZMO into PVA films caused a significant decrease in water swelling and moisture absorption and increase in solubility and water vapor permeability. Tensile strength, elastic modulus, and elongation at break for pure... 

In this work, examinations on the microstructure and mechanical properties of plain carbon steel and AISI 430 ferritic stainless steel dissimilar welds are carried out. Welding is conducted in both autogenous and using ER309L austenitic filler rod conditions through gas tungsten arc welding process. The results indicate that fully-ferritic and duplex ferritic-martensitic microstructures are formed for autogenous and filler-added welds, respectively. Carbide precipitation and formation of martensite at ferrite grain boundaries (intergranular martensite) as well as grain growth occur in the heat affected zone (HAZ) of AISI 430 steel. It is found that weld heat input can strongly affect grain... 

A totally computerized image processing program package is developed to analyze the SEM images of membrane surface and cross-section. Pore size distribution and porosity of the fabricated membranes are determined using the proposed image processing procedure. Furthermore, effect of coagulation bath temperature on the morphology and mechanical properties (such as tensile strength, strain break, tensile energy absorbent, and tensile stiffness) of Polysulfone (PSf) membranes are investigated. The results reveal that the mechanical properties are higher when N-methyl-2-pyrrolidone (NMP) is used as solvent. Also, an increase in the coagulation bath temperature caused a monotonous increase in the... 

In this study, biodegradation of corn starch/glycerol/Na-MMT nanocomposites by soil burial tests were carried out for up to 6 months. Films were prepared by casting method according to central composite design and response surface methodology was applied for analysis of the results. The effects of formulation on the water solubility, contact angle and tensile strength of starch films were investigated. Increasing in Na-MMT content decreased biodegradability; while presence of glycerol, increased it. The effect of nanoparticles content might have been attributed to interactions between starch and Na-MMT that further prevented enzymatic attack on the biopolymer. In addition, the films with... 

Self-compacting concrete (SCC) is a highly-workable concrete that without any vibration or impact and under its own weight fills the formwork, and it also passes easily through small spaces between rebars. In this paper, the effect of steel fibers on rheological properties, compressive strength, splitting tensile strength, flexural strength, and flexural toughness of SCC specimens, using four different steel fiber volume fractions (0.5%, 1%, 1.5%, and 2%), were investigated. Two mix designs with strengths of 40 MPa (medium strength) and 60 MPa (high strength) were considered. Rheological properties were determined through slump flow time and diameter, L-box, and V-funnel flow time tests.... 

Plane strain compression (PSC) test was used to study the flow stress of ultrafine grained commercially pure aluminum at large strains. AA 1050 sheets were processed by various Accumulative Roll-Bonding (ARB) cycles up to 10 cycles as the initial specimens for the test. An approach was developed to measure the coefficient of friction and to suppress its effect on the results. It is shown that as a result of having an anisotropy parameter (R-value) of less than one, Von-Mises tensile strengths are significantly higher than PSC strengths. Comparing these strengths, the R-value as an average anisotropy parameter of rolling and transverse directions is estimated for the ARBed sheets, where it is... 

Nano-biocomposites are a new class of hybrid materials composed of nano-sized filler (nanofiller) incorporated into a bio-based matrix. Such an association between eco-friendly biopolymers and nano-objects, with the aim to obtain synergic effects, is one of the most innovating routes to enhance the properties of these bio-matrices. In recent years, there has been an increasing interest in Starch as an inexpensive and renewable source has been used as a filler for environmentally friendly plastics for about two decades. However, the poor mechanical properties of starch based biopolymers, leads to use of nanoparticles as reinforcing materials. In the present study, the influence of a... 

Polyvinyl alcohol (PVA) thin films were reinforced by glutaraldehyde and multiwalled carbon nanotubes (MWCNTs) and then mechanical, water solubility, water swelling, water uptake, water vapor permeability, and antibacterial properties of the films were examined. Cross-linking by glutaraldehyde or incorporation of MWCNT caused a significant increase in tensile strength, decrease in elongation at break, and increase in Young's modulus of the PVA films, while MWCNTs were more effective rather than that of glutaraldehyde. Cross-linking by glutaraldehyde or incorporation of MWCNT caused a significant decrease in water solubility, water swelling and water uptake, with a similar manner.... 

Despite brilliant properties of glass ionomer cement (GIC), its weak mechanical property poses an obstacle for its use in medical applications. The present research aims to formulate hydroxyapatite/yttria-stabilized zirconia (HA/YSZ) in the composition of GIC to enhance mechanical properties and to improve fluoride release of GIC. HA/YSZ was synthesized via a sol-gel method and characterized by applying X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), X-ray photo-emission spectroscopy (XPS) and simultaneous thermal analysis (STA) along with transmission electron microscopy (TEM) methods. The synthesized nanocomposite was mixed with GIC at a fixed composition of 5.... 

The details of the Element Free Galerkin (EFG) method are presented with the method being applied to a study on hydraulic fracturing initiation and propagation process in a saturated porous medium using coupled hydro-mechanical numerical modelling. In this EFG method, interpolation (approximation) is based on nodes without using elements and hence an arbitrary discrete fracture path can be modelled.The numerical approach is based upon solving two governing partial differential equations of equilibrium and continuity of pore water simultaneously. Displacement increment and pore water pressure increment are discretized using the same EFG shape functions. An incremental constrained Galerkin... 

Highly cold worked (HCW) low carbon steel sheets with cellular structure in the range of 200 to 300 nm are fabricated via constrained groove pressing process. Joining of the sheets is carried out by resistance spot welding process at different welding currents and times. Thereafter, failure behavior of these welded samples during tensile-shear test is investigated. Considered concepts include; failure load, fusion zone size, failure mode, ultimate shear stress, failure absorbed energy, and fracture surface. The results show that HCW low carbon steel spot welds have higher failure peak load with respect to the as-received one at different welding currents and times. Also, current limits for... 

The present study investigated the effects of initial Hydrogen level and cooling rate on ultimate tensile strength of commercial Al-A319 alloys. Three hydrogen levels (0.01, 0.2, and 0.41 mL/100 grams of melt) and five cooling rate were studied. Total of 45 tensile test bars was prepared (three hydrogen levels × five cooling rate × three repeats). The UTS of the samples was determined though uniaxial tension tests. Furthermore, the microstructures of the samples were studied by standard metallographic technique and image analysis software. Finally the relationship between UTS and microstructurai features—SDAS and fraction of porosity (Fp%)—of the alloys was investigated.Results of tensile... 

In this research, the effects of crosslinking agent and clay content on the morphology, barrier and mechanical properties of ethylene vinyl acetate-organoclay nanocomposites prepared by solution method were studied. Dicumyl peroxide has been used as crosslinking agent. The morphology of the prepared nanocomposites was investigated using wide-angle X-ray diffraction and transmission electron microscopy. Wide-angle X-ray diffraction and transmission electron microscopyindicated that the prepared nanocomposites had predominantly intercalated morphologies. The obtained results of permeability tests showed that the permeability of ethylene vinyl acetate films dramatically decreases with addition... 

A modified method of severe plastic defomation (SPD) entitled constrained groove pressing-cross route (CGP-CR) was introduced for imposing a high magnitude of equivalent strain of about 2.32 per pass on the sheet form samples. The major benefit of this improved route compared to previous common route was the more homogeneity of strain in the rolling (RD) and transverse (TD) directions of sheets. In this study, low carbon steel samples were used for examination of evolutions in microstructure and mechanical properties during SPD via CGP-CR process. Mechanical properties improvement were measured by tensile and macro hardness tests. The results indicate that CGP-CR process can effectively... 

The effects of melt quality and the placement of a filter in the filling system on Weibull distributions of tensile strength and elongation of Al-7%Si-Mg alloy castings were investigated. Three different combinations of melt quality and filtering were used: (a) unstirred, with filter in the filling system, (b) stirred to produce and entrain surface oxide films with no filter in the filling system to emulate poor initial melt preparation and melt handling, and (c) stirred and with a filter placed in the filling system. The results showed that the highest elongation and tensile strength values were obtained from the unstirred, filtered condition and lowest values were from stirred and... 

This work was carried out to investigate the effect of different Ti concentrations as a modifying agent on the microstructure and tensile properties of an in-situ Al-15 pctMg2Si composite. Cast, modified, homogenized small ingots were extruded at 753 K (480°C) at the extrusion ratio of 18:1 and ram speed of 1 mm/s. Various techniques including metallography, tensile testing, scanning electron microscopy were used to characterize the mechanical behavior, microstructural observations, fracture mechanisms of this composite. The results showed that 0.5 pctTi addition and homogenizing treatment were highly effective in modifying Mg2Si particles. The results also exhibited that the addition of Ti... 

By utilizing the fourth-, sixth-, eighth-, and tenth-order elastic moduli tensors of graphene a highly nonlinear constitutive model for it is proposed. Subsequently, an accurate analytical formulation, describing the entire tensile behavior of single-walled carbon nanotubes (SWCNTs) from their initial unloaded states through their ideal strengths, is made possible. The angle of twist which is a critical parameter that varies with the tensile loading is also calculated within the current framework. The estimated value of the theoretical strength of SWCNTs with different chiralities and radii as well as that of graphene ranges from 0.39 to 0.44 TPa. Some peculiarities associated with chirality... 

In the present study, the dissimilar aluminum alloys of 5083-H12 and 6061-T6 were joined by friction stir welding (FSW). Then, the design of experiments (DOE), the Box-Benken method, and the response surface methodology (RSM) were used to optimize the effective parameters of the FSW process. The optimized parameters that led to the maximum tensile strength in dissimilar friction stir welded sheets were determined. The predicted results were then compared with those measured experimentally. The results show that there is good agreement between the predicted and measured amounts. By applying the limit dome height (LDH) test, the formability of friction stir welded sheets was studied. During... 

The unique properties of NiTi alloy, such as its shape memory effect, super-elasticity and biocompatibility, make it ideal material for various applications such as aerospace, micro-electronics and medical device. In order to meet the requirement of increasing applications, great attention has been given to joining of this material to itself and to other materials during past few years. Laser welding has been known as a suitable joining technique for NiTi shape memory alloy. Hence, in this work, a comparative study on laser welding of NiTi wire to itself and to AISI 304 austenitic stainless steel wire has been made. Microstructures, mechanical properties and fracture morphologies of the...