Sharif Digital Repository

In this research, the effect of various surface treatments including laser processing, grit blasting and anodizing on chemical structure, surface topography, and bioactivity of Ti-6Al-4V was investigated. Six groups of samples were prepared by a combination of two alternative laser processes, grit blasting and anodizing. Selected samples were first evaluated using microanalysis techniques and contact roughness testing and were then exposed to in vitro environment. Scanning electron microscopy was used to characterize the corresponding final surface morphologies. Weight measurement and atomic absorption tests were employed for determination of bioactivity limits of different surface... 

In the present research, the introduction of multi-walled carbon nanotubes (MWCNTs) into the hydroxyapatite (HA) matrix and dip coating of nanocomposite on titanium alloy (Ti-6Al-4V) plate was conducted in order to improve the performance of the HA-coated implant via the sol-gel method. The structural characterization and electron microscopy results confirmed well crystallized HA-MWCNT coating and homogenous dispersion of carbon nanotubes in the ceramic matrix at temperatures as low as 500 C. The evaluation of the mechanical properties of HA and HA/MWCNT composite coatings with different weight percentages of MWCNTs showed that the addition of low concentrations of MWCNTs (0.5 and 1 wt.%)... 

This study was undertaken to investigate the influence of Al-5Ti-1B master alloy and modified strain-induced melt activation process on the structural characteristics, mechanical properties and dry sliding wear behavior of Al-12Zn-3Mg-2.5Cu aluminum alloy. The optimum amount of Ti containing master alloy for proper grain refining was selected as 2. wt.%. The alloy was produced by modified strain-induced melt activation (SIMA) process. Reheating condition to obtain a fine globular microstructure was optimized. The optimum temperature and time in strain-induced melt activation process are 575. °C and 20. min, respectively. T6 heat treatment was applied for all specimens before tensile testing.... 

Mechanical alloying and sintering were used to fabricate nanostructured Ti6Al4V scaffolds of highly controllable pore geometry and fully interconnected porous network. Elemental powders were milled for different periods of time (10, 20, 30, 40 and 60 h), mixed with 40-60 vol.-% of 200-400 μm cuboidal NaCl, compacted at 500-600 MPa and sintered according to single or double stage heat treatment regimes at 790 and 950°C under vacuum. After sintering, the samples were soaked in distilled water to washout the NaCl. Foamy microstructures were obtained showing well shaped biopores and fragmentary embedded micropores. The shape of initial NaCl was copied into the biopores which had highly... 

The low erosion resistance of titanium and its alloys has prevented their widespread application as joint implants. In addition, one essential requirement for the implants to bond with the living bone is the formation of a bone-like apatite on their surfaces in the host body. To enhance the erosion resistance of the surface, a diffused layer of TiB2 was formed at 1000uC on the commercial pure titanium. Hydroxyapatite was then coated on the boronised titanium by means of dip coating in a sol-gel solution. In order to confirm the biocompatibility of the specimens, they were soaked in a simulated body fluid for several days. The surface morphology of the specimens after exposure was studied by... 

Titanium alloys, in particular Ti6Al4V, are increasingly used recently due to high strength-to-weight ratio, biocompatibility and robust mechanical-properties at high temperatures. However, Ti6Al4V have poor machinability because of their poor thermal conductivity and high reactivity. Usually in conventional grinding (CG) of these alloys, surface burning is unavoidable. Ultrasonic assisted grinding (UAG) is an efficient method for overcoming the poor machinability of such materials. In this research, effect of imposed vibration on grinding of Ti6Al4V is studied. Obtained results show forces and surface roughness are reduced 18% and 12% by UAG comparing to CG respectively. It also results in... 

The deformation behavior of a 49.8 Ni-50.2 Ti (at pct) alloy was investigated using the hot compression test in the temperature range of 700 °C-1100 °C, and strain rate of 0.001 s-1 to 1 s-1. The hot tensile test of the alloy was also considered to assist explaining the related deformation mechanism within the same temperature range and the strain rate of 0.1 s-1. The processing map of the alloy was developed to evaluate the efficiency of hot deformation and to identify the instability regions of the flow. The peak efficiency of 24-28% was achieved at temperature range of 900 °C-1000 °C, and strain rates higher than 0.01 s -1 in the processing map. The hot ductility and the deformation... 

The hot workability of a wrought 49.8 Ni-50.2 Ti (at pct) alloy was assessed using the hot compression tests in temperature range of 700-1000°C, strain rate of 0.001-1s-1, and the total strain of 0.7. The constitutive equations of Arrhenius-type hyperbolic-sine function was used to describe the flow stress as a function of strain rate and temperature. The preferable regions for hot workability of the alloy were achieved at Z (Zener-Holloman parameter) values of about 109-1013 corresponding to the peak efficiency of 20-30% in the processing map. However, a narrow area in the processing map including the deformation temperature of 1000°C and strain rate of 1s-1 is inconsistent with the related... 

A multilayer back propagation learning algorithm was used as an artificial neural network tool to predict the mechanical properties of porous NiTi shape memory alloys fabricated by press/sintering of the mixed powders. Effects of green porosity, sintering time and the ratio of the average Ti to Ni particle sizes on properties of the product were investigated. Hardness and tensile strength of the compacts were determined by hardness Rockwell B method and shear punch test. Three-fourths of 36 pairs of experimental data were used for training the network within the toolbox of the MATLAB software. Porosity, sintering time and particle size ratios were defined as the input variables of the model.... 

In the present work, high-energy mechanical alloying (MA) was employed to synthesize a nanostructured magnesium-based composite for hydrogen storage. The preparation of the composite material with composition of MgH2-5 at% (TiCr1.2Fe0.6) was performed by co-milling of commercial available MgH2 powder with the body-centered cubic (bcc) alloy either in the form of Ti-Cr-Fe powder mixture with the proper mass fraction (sample A) or prealloyed TiCr1.2Fe0.6 powder (sample B). The prealloyed powder with an average crystallite size of 14 nm and particle size of 384 nm was prepared by the mechanical alloying process. It is shown that the addition of the Ti-based bcc alloy to magnesium hydride yields... 

To improve the hydrogen kinetics of magnesium hydride, TiCr 1.2Fe0.6 alloy was prepared by vacuum arc remelting (VAR) and the alloy was co-milled with MgH2 to process nanostructured MgH2-5 at.% TiCr1.2Fe0.6 powder. The hydrogen desorption properties of the composite powder were studied and compared with pure magnesium hydride. X-ray diffraction (XRD) analysis showed that the composite powder prepared by VAR/mechanical alloying (MA) procedure consisted of β-MgH2, γ-MgH2, bcc Ti-Cr-Fe alloy, and small amount of MgO. The average size of particles and their grain structure after 4 h MA were determined by a laser particle size analyzer and XRD method and found to be 194 nm and 11 nm,... 

A fine-grained Al-Mg/Al3Ti nanocomposite was fabricated by friction stir processing (FSP) of an aluminum-magnesium (AA5052) alloy with pre-placed titanium powder in the stirred zone. Microstructural evolutions and formation of intermetallic phases were analyzed by optical and electron microscopic techniques across the thickness section of the processed sheets. The microstructure of the nanocomposite consisted of a fine-grained aluminum matrix (1.5 μm), un-reacted titanium particles (<40 μm) and reinforcement particles of Al3Ti (<100 nm) and Mg2Si (<100 nm). Detailed microstructural analysis indicated solid-state interfacial reactions between the aluminum... 

Nickel-titanium (NiTi) shape memory alloys have been widely used as implant materials, due to their superior shape memory properties and similar mechanical behavior to bone tissue. The presence of nickel on the surface of nickel-titanium alloy and release of this ion in the body environment will result in some allergic reactions. In current study, we used shot pinning process to produce nanocrystalline nickel-titanium alloy with increased corrosion resistance. Field emission scanning electron microscopy (FE-SEM), x-ray diffraction (XRD) analysis, and atomic force microscopy were employed to investigate the surface features of samples. The quantitative chemical analysis of NiTi and modified... 

Friction stir welding (FSW) parameters, such as tool material, tool geometry, tilt angle, tool rotational speed, welding speed, and axial force play a major role in the weld quality of titanium alloys. Because of excessive erosion, tool material and geometry play the main roles in FSW of titanium alloys. Therefore, in the present work for the first time, tool material and geometry, tool tilt angle, cooling system and shielding gas effects on macrostructure, microstructure, and mechanical properties of pure titanium weld joint were investigated. Result of this research shows that Ti can be joined by the FSW, using a tool with a shoulder made of tungsten (W) and simple pin made of tungsten... 

The present paper deals with different effects of homogenization time and cooling environment on Ni-42.5wt%Ti-7.5wt%Cu alloy. The alloy was prepared by vacuum arc melting. Afterwards, three homogenization times (half, one and two hour) and three cooling environments (water, air and furnace) at 1373 K were selected. Optical and Scanning Electron Microscopic methods, EDX, DSC and hardness tests have been used to evaluate the microstructure, transformation temperatures and hardness. Results indicate that specimens that were cooled in air are super-saturated. Also, the microstructure from furnace cooling has many disparities with the other cooling environments' microstructure and two types of... 

The main challenges of biological implants are suitable strength, adhesion, biocompatibility and corrosion resistance. This paper discusses fabrication, characterization and electrochemical investigation of anodized Ti6Al4V without and with a hydroxyapatite (HA) layer, HA/TiO2 nanoparticles (NPs) and HA/TiO2 nanotubes (HA/anodized). X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and energy dispersive spectroscopy (EDS) were used to characterize and compare properties of different samples. Dense HA with uniform distribution and 12.8 ± 2 MPa adhesive strength enhanced to 19.2 ± 4 MPa by the addition of TiO2 nanoparticles and enhanced to 23.1 ± 4 MPa by the... 

In this work, improvement in fretting fatigue life of AL7075-T6 has been investigated by titanium surface coating using ion-beam-enhanced deposition (IBED) technique and shot peening. From the experiments, the following conclusions were derived: (i) Shot peening increased the fretting fatigue life up to 350%. (ii) Titanium coating increased the fatigue life up to 100% with respect to virgin specimens for low working stresses, while it reduced the fatigue life at higher working stresses significantly. (iii) Titanium coating+shot peening increased the fatigue life up to 130% with respect to the virgin specimens for low working stresses, while it reduced the fatigue life at higher working... 

Porous NiTi-shape memory alloy (SMA) is a promising biomaterial with desirable mechanical property and appropriate biocompatibility for human implant manufacturing. In this research, porous NiTi-SMAs have been successfully produced by using thermohydrogen process (THP). This process has capability of production of homogenous structures, appropriate pore-size distributions and short sintering times. The THP-SMA samples produced in this research have a low Young's modulus (19.8 GPa) and a high tensile strength of 255 MPa. These properties are close to those of the natural bone and can meet the mechanical property demands of the hard-tissue implants for heavy load-bearing applications. The...