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    Preparation and Characterization of Ternary Mixed Oxide Containing IrO2,RuO2,TiO2 on Platinum Coated Titanium Anode

    , M.Sc. Thesis Sharif University of Technology Ali Asghari, Sepideh (Author) ; Ghorbani, Mohammad (Supervisor) ; Davami, Parviz (Supervisor)
    Abstract
    Ruthenium based-oxide coatings on Titanium anodes are widely used as DSA (Dimensionally Stable Anode) for chlorine and chlorate production. Coatings consisting of composition of highly conductive oxide of noble metals (Ru, Ir and Pt) make them as long lasting anodes in chlor-alkali technology.In this work, a newly anode by a ternary coating of IrO2, RuO2, and TiO2 on the Pt-coated Ti was developed through thermal decomposition of iridium and titanium and ruthenium inorganic salts dissolved in n-pentane. The effect of deposition parameters such as current density, time, different condition of baking, heating, mole ratio and pulling up the samples was investigated to find out reasonable...