Sharif Digital Repository

In this paper, the impacts of Maxwell nanoliquid transmission, rectangular with titanium oxide nanoparticles are explored over the triangular, chamfer blades. The innovation of this paper is the use of the number of chamfers, rectangular, and triangular blades at the top and bottom of a stretched plate to study physical nanofluid parameters such as temperature and the effects of magnetism. Also, by determining the appropriate height and length for the blades, we achieve the best optimization of temperature and velocity of nanofluid between the plate and the blades, which improves heat transfer and with a more and better effect of magnetic effects. The finite element method is utilized for... 

The most common reasons for hard-tissue implant failure are structural loosening and prosthetic infections. Hence, in this study, to overcome the first problem, different bioinspired coatings, including dual acid-etched, anodic TiO2 nanotubes array, anodic hierarchical titanium oxide (HO), micro- and nanostructured hydroxyapatite (HA) layers, and HA/chitosan (HA/CS) nanocomposite, were applied to the titanium alloy surfaces. X-ray diffraction and FTIR analysis demonstrated that the in situ HA/CS nanocomposite formed successfully. The MTT assay showed that all samples had excellent cell viability, with cell proliferation rates ranging from 120% to 150% after 10 days. The HO coating... 

Modification of orthopedic implant surfaces through advanced nanoscale coating methods has made a major breakthrough in maximizing implantation success. Adjustable drug release and biocompatibility are among the most momentous features since they can significantly prevent the implantation failure. In this study, the potential of silk fibroin (SF) nanofibers fabricated via electrospinning, along with titanium oxide nanotube arrays (TNTs) formed through anodization, were exploited to produce a cyto-biocompatible, well-controlled drug delivery system. Highly-ordered TNTs were formed in an organic electrolyte solution within 2 h at the voltage of 60 V under temperature controlling (16 °C).... 

Growing demands for clean and renewable energy technologies have sparked broad research on the development of highly efficient and stable non-noble metal electrocatalysts for oxygen evolution reaction (OER). In this regard, in the present work a three-dimensional Fe2TiO5/nitrogen-doped graphene (denoted as 3D FTO/NG) hybrid electrocatalyst was synthesized via a facile in-situ process using a hydrothermal method. Structural characterization of the prepared nanocomposite is performed by various techniques e.g. field emission scanning electron microscopy (FE-SEM), atomic force microscopy (AFM) analysis, Fourier transform infrared spectra (FT-IR), X-ray photoelectron spectroscopy spectra (XPS),... 

In this research, we investigate the effect of alkali metal cations including Li, Na and Cs in hydrothermal solution on the morphology, stability, and photoactivity of nanostructured TiO2 nanoflakes as a photoanode. The TiO2 nanoflakes are formed through hydrothermal treatment of Ti foil in 1.0 M LiOH, NaOH or CsOH at 100 °C for 3 h. By subsequent thermal reduction of the structure in an optimized Ar/H2 environment, conductive TiO2 nanoflakes were formed. The reduction treatment remarkably improves the photocurrent density of the TiO2 nanoflakes and has the highest impact on the sample treated in the NaOH alkali solution. For the nanoflakes produced in NaOH alkali solution, the bandgap is... 

Anti-reflection and self-cleaning coatings on the glass substrate are used to improve the performance of solar systems. TiO2 are one of the most used semiconductors for this application. In this research meso-porous TiO2 coatings (that synthesized by the sol-gel process) with the various extent of porosity (using different concentrations of Pluronic F127, as pore-forming agent) have been investigated. The coating's thickness and porosity and anti-reflective properties were studied by FE-SEM and UV/VIS spectrometer (transmission spectra test), respectively. It was found that the use of F127 leads to the formation of pores smaller than 30 nm and increases the surface roughness from 1.5 (for... 

Two main origins of failure for hard tissue replacements are structural loosening and prosthetic implant infections (PIIs). Bioinspired multifunctional TiO2 hierarchical micro/nanostructures of conical-shaped TiO2 (CTO), regular TiO2 nanotubes (RTO) and irregular TiO2 nanotubes (ITO) with tunable improved cell growth and inhibited bacteria adhesion were synthesized. CTO and ITO samples indicated superhydrophilicity with contact angles of less than 5°. The MTT assay demonstrated excellent biological performance for RTO and CTO sample with 98.1% and 103.1% of cell viability, respectively. The bridging force for osteoblast cell attachment onto the synthesized porous coatings was presented as a... 

In this study, apatite formation ability on TiO2 nanotubes (TNTs) synthesized by anodizing process were compared with TNTs decorated by MnO nanoparticles. The MnO nanoparticles used for decoration process were fabricated via thermal decomposition method. At first, it was strived to find the optimal condition of anodizing process and the effect of applied voltages (15 V, 20 V, and 25 V) and process times (15 min, 20 min, and 25 min) on the diameter of the synthesized TNTs was investigated. Results of microscopic characterizations showed that the completely uniform structure of nanotubes with a diameter in the range of about 100–130 nm was achieved after 20 min of anodizing process at an... 

Although morphological disorder of nanotube structure is further down than the nanoparticular electrode, its density of traps are the hindering effects in the charge transport. In this study, crack-free TiO2 nanotube membranes, which obtained through a re-anodizing process, are fixed on transparent fluorine–tin-oxide glass by applying a few drops of Titanium Isopropoxide without needing the TiO2 powder paste. Front-side illuminated dye sensitized solar cells fabricated by undoped, N-doped and blue TiO2 nanotube membranes are investigated. The electrical characteristics of TiO2 nanotube based dye sensitized solar cells are followed by theoretical analysis using simple one-diode model.... 

Abstract: Nickel–titanium (NiTi) nanoparticles are ultrafine smart materials manifesting shape memory effect at very small scales. We have produced NiTi nanoparticles surrounded by an amorphous carbon shell using an innovative spark discharge system. The resulting nanoparticles were studied using various characterization methods to systematically study their size, morphology, size distribution, composition, structure, and thermal behavior. Field-emission scanning electron microscopy and dynamic light-scattering results indicated that the average size of the produced nanoparticles was about 13 nm. High-resolution transmission electron microscopy, energy-dispersive spectroscopy (EDS), and... 

Titanium dioxide is prepared by sol gel method from titanium tetraisopropoxide (TTIP) as precursor and likewise zinc oxide is prepared by sol gel method from zinc acetate dehydrate (ZAD) as precursor. The composite sols are prepared in three different molar ratios 90TiO2:10ZnO, 70TiO2:30ZnO and 50TiO2:50ZnO. Thin film deposition is carried out by dip coating technique. Crystal structure, surface morphology and photocatalytic activity of the prepared nanocomposite thin films are investigated. The antibacterial activity of the prepared nanocomposite thin film against E-coli ATCC 25922 bacteria is examined by placing the thin film in standard aqueous E-coli medium under UV light for 1, 2, 3 and... 

Reactive friction stir processing (RFSP) has been employed to modify the surface properties of AA5052 Al-Mg alloy through grain refinement and the distribution of ultrafine hard nanoparticles (2 to 6% volume fractions of 50 nm titanium dioxide). The heat generated induced solid state reactions between the metal matrix and the reinforcement to form Al3Ti/MgO inclusions. The role of grain refinement and distributed hard nanoparticles on the tribological behavior of the alloy under dry sliding wear condition was evaluated. The wear rates and friction coefficient as well as macro- and micro-features of the worn surfaces indicate that the wear mechanism (at 3–7 kgf and 0.5 m/s) is abrasive. The... 

Energy and environment crises motivated scientists to develop sustainable, renewable, and clean energy resources mainly based on solar hydrogen. For this purpose, one main challenge is the low cost flexible substrates for designing earth abundant efficient cocatalysts to reduce required water oxidation overpotential. Here, a systematic morphological and electrochemical study has been reported for cobalt oxide/hydroxide nanoflakes simply electrodeposited on four different commercially available substrates, titanium, copper sheet, steel mesh, and nickel foam. Remarkable dependence between the used substrate, morphology, and electrocatalytic properties of nanoflakes introduced flexible porous... 

An aluminum-magnesium alloy was friction-stir processed in the presence of TiO2 nanoparticles which were pre-placed in a groove on the surface to produce a composite. Field emission-scanning and transmission electron microscopy studies show that solid state chemical reactions occur between the Al-Mg matrix and the ceramic particles upon the severe plastic deformation process. The microstructure of the aluminum alloy consists of a coarse grain structure, large complex (Fe,Mn,Cr)3SiAl12 particles, and small Mg2Si precipitates. After friction stir processing, a deformed grain structure containing rod-like Al-Fe-Mn-Si precipitates is attained, along... 

The ion exchange process is a promising method for lithium extraction from brine and seawater having low concentrations of this element. To achieve this goal, it is vital to use an effective adsorbent with maximum lithium adsorption potential together with a stable structure during extraction and insertion of the ions. In this study, titanium dioxide and then lithium titanate spinel with nanotube morphology was synthesized via a simple two-step hydrothermal process. The produced Li4Ti5O12 spinel ternary oxide nanotube with about 70 nm diameter was then treated with dilute acidic solution in order to prepare an adsorbent suitable for lithium adsorption from local brine. Morphological and... 

Nanoparticles for biomedical use must be cytocompatible with the biological environment that they are exposed to. Current research has focused on the surface functionalization of nanoparticles by using proteins, polymers, thiols and other organic compounds. Here we show that inorganic nanoparticles such as titanium oxide can be coated by pyrolytic carbon (PyC) and that the coating has cytocompatible properties. Pyrolization and condensation of methane formed a thin layer of pyrolytic carbon on the titanium oxide core. The formation of the PyC shell retards coalescence and sintering of the ceramic phase. Our MTT assay shows that the PyC-coated particles are cytocompatible at employed doses  

In this paper, the effect of different parameters on the thermal operation of a Closed Loop Pulsating Heat Pipe (CLPHP) has been investigated. These parameters include the working fluid, the inclination angle, the filling ratio, and the input heat flux. The effect of nanoparticle mass concentrations has been analyzed as well. It was observed that the CLPHP can decrease thermal resistance up to 11.5 times compared to the same empty copper tube with thermal resistance of 9.4 K/W. Optimum thermal operation for a system with the water-silver nanofluid was achieved at conditions of the 50% filling ratio with thermal resistance of 0.9 K/W, and for the water-titanium oxide system, the optimal... 

TiO2 a nanotube array was prepared using an anodization process. The process proceeded in a two-electrode cell containing of platinum sheet as the cathode electrode. Two phosphate-base electrolyte solutions containing different amounts of HF and NH4F were prepared. Different concentration of fluorine ions were examined in respected electrolytes. Current transient techniques were used to produce the TiO2 nanotubes at constant voltage of 18-25V. It was revealed that anodization at 18-22V, in so-called electrolytes would end up to nano-tubular structure. However the tubular structure prepared at 20V and from phosphate electrolyte containing of 0.5 wt% NH4F as well as 0.5 wt% HF, was recognized... 

Very recently, we fabricated (WO3)x-(TiO 2)1-x layers via micro-arc oxidation process under different applied voltages. Morphological and topographical studies, accomplished by SEM and AFM techniques, revealed that the pores size as well as the surface roughness increased with the voltage. Phase structure and chemical composition of the layers were also investigated by XRD and XPS and the results showed the grown layers consisted of titanium and tungsten oxides. It was found that WO3 dispersed in the TiO2 matrix and also doped into the TiO2 lattice. In addition, optical properties of the synthesized layers were studied employing a UV-vis spectrophotometer. Band gap energy of the layers was... 

Barium strontium titanate (BST) was prepared via the simple sol-gel method by using tetrabutyl ti-tanate, ethanol, citric acid and ethylene glycol as starting materials. Thermogravimetry and differential thermal analysis were used to examine the behaviour of the xerogel. The particle size of BST was approximately 21 nm, as calculated by the X-ray diffraction and confirmed by transition electron microscopy for the calcination temperature of 750 °C. It was found that the particles of BST powders calcined at 750 °C were smaller and more homogeneous and uniform than those obtained at 800 °C