Sharif Digital Repository

Finesmigration is a noticeable problem in petroleum-production engineering. Plugging of throats in porous media occurs because of detachment of fine particles from sand surfaces. Thus, the study of interactions between fines and pore surfaces and the investigation of governing forces are important factors to consider when describing the mechanism of the fines-release process. The main types of these forces are electric double-layer repulsion (DLR) and London-van der Waals attraction (LVA). It may be possible to alter these forces with nanoparticles (NPs) as surface coatings. In comparison with repulsion forces, NPs increase the effect of attraction forces. In this paper, we present new... 

This paper aims at investigating free vibrations and stability of double-walled carbon nanotube (DWCNT)-based spinning nanobearings. The so-called nanobearing consists of two coaxial carbon nanotubes (CNTs) where either of the two CNTs can be a rotor while the other takes the role of stator. Euler–Bernoulli beam model along with the Eringen’s nonlocal theory of elasticity are employed to obtain governing equations of transverse vibrations for the CNTs. The coupling of the two CNTs originates from the van-der-Waals (vdW) forcing present in the interface of the two CNTs. The coupling is taken into account as distributed spring foundation with an equivalent elastic stiffness. Based on the... 

The van der Walls interaction between a carbon nanotube sheet (CNTS) and a rare gas atom, is studied using both atomistic and continuum approaches. We present analytical expressions for the van der Waals energy of continuous nanotubes interacting with a rare gas atom. It is found that the continuum approach does not properly treat the effect of atomistic configurations on the energy surfaces. The energy barriers are small as compared to the thermal energy, which implies the free motion above the CNTS in heights about one nanometer. In contrast to the energy surface of a graphene sheet, the honeycomb lattice structure in the energy surface of a CNTS is imperceivable. Defects alter the energy... 

Due to the favorable properties of two-dimensional materials such as SnS2, with an energy gap in the visible light spectrum, and InSe, with high electron mobility, the combination of them can create a novel platform for electronic and optical devices. Herein, we study a tunable gain SnS2/InSe Van der Waals heterostructure photodetector. SnS2 crystals were synthesized by chemical vapor transport method and characterized using X-ray diffraction and Raman spectroscopy. The exfoliated SnS2 and InSe layers were transferred on the substrate. This photodetector presents photoresponsivity from 14 mA/W up to 740 mA/W and detectivity from 2.2 × 108 Jones up to 3.35 × 109 Jones by gate modulation from... 

Torsional buckling of carbon nanopeapods (carbon nanotubes filled with fullerenes) is studied using a continuum-based multi-layered shell model. The model takes into account non-bonded van der Waals interactions between nested fullerenes and the innermost layer of host nanotube. For nanopeapods with linearly arranged nested fullerenes, equivalent pressure distribution is proposed to model these interactions. Deriving explicit equations governing the torsional stability, it is concluded that the critical torsional load of a carbon nanopeapod is less than that of a carbon nanotube under otherwise identical geometric and mechanical conditions. Performing numerical calculations, it is also shown... 

In this paper, the effects of van der Waals and Casimir forces on the static deflection and pull-in instability of a micro/nano cantilever gyroscope with proof mass at its end are investigated. The micro/nano gyroscope is subjected to coupled bending motions which are related by base rotation and nonlinearities due to the geometry and the inertial terms. It is actuated and detected by capacitance plates which are placed on the proof mass. The extended Hamilton principle is used to find the equations governing the static behavior of the clamp-free micro/nano gyroscopes under electrostatic, Casimir and van der Waals forces. The equations of static motion are discritized by Galerkin's... 

In this paper, using the continuum approximation together with Lennard-Jones potential, a new semi-analytical expression is given to evaluate the van der Waals interaction between two single-walled carbon nanotubes. Based on this expression, two new formulations are also proposed to model multi-walled carbon nanotubes. In the first one, the interactions between each pair of shells from the inner and outer tubes are summed up over all of the pairs, whereas in the second formulation, a set of correction factors are applied to convert the results of double-walled carbon nanotubes to the correlated multi-walled ones. With respect to the present formulations, extensive studies on the variations... 

In this article, a Molecular Structural Mechanics/Finite Element (MSM/FE) multiscale modeling of carbon nanotube/polymer composites with viscoelastic (VE) polymer matrix is introduced. The nanotube is modeled at the atomistic scale using structural molecular mechanics. The matrix deformation is analyzed by nonlinear finite element method considering VE behavior. The nanotube and matrix are assumed to be bonded by van der Waals interactions based on the Lennard-Jones potential at the interface. Using the MSM/FE multiscale model, we investigate the effect of carbon nanotube (CNT) on the improvement of mechanical stability of the nanocomposite. Also, the buckling behavior of these... 

In this paper, the axial stability of single-walled carbon nanopeapods is studied based on an elastic continuum shell model. In order to model the non-bonded van der Waals interactions between host carbon nanotube and guest fullerenes, an equivalent pressure distribution is proposed and incorporated in the model. Deriving an explicit equation for the determination of critical axial load, it is concluded that the axial stability of a single-walled carbon nanopeapod is less than that of a carbon nanotube under otherwise identical conditions. In addition, it is shown that applying external pressure to the carbon nanopeapod decreases the axial compressive stability through reducing the critical... 

A novel molecularly imprinted xerogel (MIX) based on organically modified silica (ORMOSIL) was successfully prepared for on-line capillary microextraction (CME) coupled with high-performance liquid chromatography (HPLC). The sol-gel-based xerogel was prepared using only one precursor and exhibited extensive selectivity towards triazines along with significant thermal and chemical stability. Atrazine was selected as a model template molecule and 3-(trimethoxysilyl)propylmethacrylate (TMSPMA) as a precursor in which the propylmethacrylate moiety was responsible for van der Waals, dipole-dipole, and hydrogen-bond interactions with the template. This moiety plays a key role in creation of... 

Structural, microstructural and mechanical properties in roll bonding of AA5052 and polypropylene sheets have been evaluated in this study. The surface roughness of the AA5052 sheets, rolling temperature and the surface energy of polymer were selected as the bonding variables. The findings indicated that an increase in the surface energy of polypropylene by grafting maleic anhydride would result in higher bonding strength due to chemical interaction between the AA5052 and the maleic anhydride grafted polypropylene (PP-g-MAH). In fact, this reaction caused the formation of an interphase layer at the polymer side of the interface and the diffusion of aluminum into the PP-g-MAH layer. It was... 

Structural, microstructural and mechanical properties in roll bonding of AA5052 and polypropylene sheets have been evaluated in this study. The surface roughness of the AA5052 sheets, rolling temperature and the surface energy of polymer were selected as the bonding variables. The findings indicated that an increase in the surface energy of polypropylene by grafting maleic anhydride would result in higher bonding strength due to chemical interaction between the AA5052 and the maleic anhydride grafted polypropylene (PP-g-MAH). In fact, this reaction caused the formation of an interphase layer at the polymer side of the interface and the diffusion of aluminum into the PP-g-MAH layer. It was... 

In this paper, the polymer chain of rotator (PCOR) equation of state (EOS) was used together with an EOS/GE mixing rule (MHV1) and the Wilson's equation as an excess-Gibbs-energy model in the proposed approach to extend the capability and improve the accuracy of the PCOR EOS for predicting the Henry's constant of solutions containing polymers. The results of the proposed method compared with two equation of state (van der Waals and GC-Flory) and three activity coefficient models (UNIFAC, UNIFAC-FV and Entropic-FV) indicated that the PCOR EOS/Wilson's equation provided more accurate results. The interaction parameters of Wilson's equation were fitted with Henry's constant experimental data... 

Various models have been applied composed of the Peng-Robinson equation of state (PR-EoS) and the Soave-Redlich-Kwong equation of state (SRK-EoS) associated with three mixing rules including the following: Wong-Sandler (WS), van der Waals one (vdW1), and van der Waals two (vdW2) for phase behavior modeling of mixtures of supercritical CO2+different ionic liquids in vapor-liquid equilibrium (VLE) region. It has been found that the PR EoS implying the WS mixing rule can be used as a reliable thermodynamic model to perform a thermodynamic consistency test on the experimental data of phase behaviors of the supercritical CO2+ionic liquid systems (19 commonly-used ionic liquids have been studied).... 

A comparison of various hydrogen production processes indicates that the thermal decomposition of methane (TDM) provides an attractive option from both economical and technical points of view. The main problem for this process is the deposition of the nano-carbon particles on the reactor wall (or catalyst surface). This research concentrates on the numerical simulation of the TDM process without use of a catalyst to find a technique that decreases the carbon accumulation in a tubular reactor. In this model, the produced carbon particles are tracked with the Lagrangian method under thermophoretic, Brownian, van der Waals, Basset, drag, lift, gravity, pressure and virtual mass forces. In... 

This paper is devoted to investigate the nonlinear behaviors of a V-shaped microcantilever of an atomic force microscope (AFM) operating in its two major modes: amplitude modulation and frequency modulation. The nonlinear behavior of the AFM is due to the nonlinear nature of the AFM tip-sample interaction caused by the Van der Waals attraction/repulsion force. Considering the V-shaped microcantilever as a flexible continuous system, the resonant frequencies, mode shapes, governing nonlinear partial and ordinary differential equations (PDE and ODE) of motion, boundary conditions, frequency and time responses, potential function and phase-plane of the system are obtained analytically. The... 

The atomic force microscope (AFM) system has evolved into a useful tool for direct measurements of intermolecular forces with atomic-resolution characterization that can be employed in a broad spectrum of applications. In this paper, the nonlinear dynamical behavior of the AFM is studied. This is achieved by modeling the microcantilever as a single mode approximation (lumped-parameters model) and considering the interaction between the sample and cantilever in the form of van der Waals potential. The resultant nonlinear system is then analyzed using Melnikov method, which predicts the regions in which only periodic and quasi-periodic motions exist, and also predicts the regions that chaotic... 

In the analysis of micro structures, due to proximity of the elements Van der Waals forces plays an important role on the dynamics of the structure. In the modeling process a similar approach should be considered for the capillary effect caused by the moisture in the environment. Microplates and microbeams are used widely in the design and manufacturing of sensors and actuators. These structures are usually made of a cantilever beam or plate along with a fixed substrate. The cantilever beam usually deflects due to applied voltage. By increasing the voltage the pull-in phenomenon takes place. It is believed that the short contact time is one the important characteristic of any micro switches.... 

In this paper, nanoscale vibrational analysis of a multi-layered graphene sheet embedded in an elastic medium is investigated and the corresponding natural frequencies and the associated modes are determined. The modeling is based on the fact that the elastic moduli of a graphene sheet in two perpendicular orientations are different, so the plate is considered to be anisotropic. The graphene layers stacking at the top of each other bond with carbon-carbon van der Waals forces between two adjacent ones. Also, the whole multi-layered graphene sheet is influenced by polymer-carbon van der Waals forces from the surrounding elastic medium. © 2005 Elsevier Ltd. Al rights reserved  

In this paper, nanoscale modeling of a multi-shell fullerene embedded in an elastic medium and its application to vibrational analysis is investigated. The spherical layers of the multi-shell fullerene are concentrically nested, with carbon-carbon van der Waals interactions between them. Also, the whole multi-shell fullerene is influenced by polymer-carbon van der Waals forces from the surrounding elastic medium. The elasticity generated by the carbon-carbon bonds is assumed to be distributed isotropically over the fullerene surfaces. Following derivation of explicit equations for the motion of the multi-shell fullerene, vibrational behavior of a double-shell fullerene is analyzed and...