Sharif Digital Repository

Comprehensive two-dimensional gas chromatography and flame ionization detection combined with unfolded-partial least squares is proposed as a simple, fast and reliable method to assess the quality of gasoline and to detect its potential adulterants. The data for the calibration set are first baseline corrected using a two-dimensional asymmetric least squares algorithm. The number of significant partial least squares components to build the model is determined using the minimum value of root-mean square error of leave-one out cross validation, which was 4. In this regard, blends of gasoline with kerosene, white spirit and paint thinner as frequently used adulterants are used to make... 

The Ghotbi-Vera hard sphere equation of state as the reference system, coupled with the mean spherical approximation, (GV-MSA), has been used to accurately correlate the mean ionic activity coefficients of aqueous solutions of single 1:1 electrolytes. The new equation of state considers the ions to be hard spheres in Kelvin tetrakaidekahedron cells. The mean ionic activity coefficients of the electrolytes can be correlated with constant diameter of anions, equal to the crystallographic Pauling diameter and with a concentration dependent relation for the cations. In comparison to their crystallographic Pauling diameters, the new model for the mean ionic activity coefficient produces realistic... 

The non-primitive mean spherical approximation (NP-MSA) based models were used to correlate the individual and the mean ionic activity coefficients of the symmetric and asymmetric aqueous electrolyte solutions. The results of the models for the mean ionic activity coefficients were directly used to calculate the osmotic coefficient for the electrolyte solutions studied in this work. In the NP-MSA models, the Ghotbi-Vera and the Boublik-Mansoori-Carnahan-Starling- Leland hard sphere equation of state as the reference system coupled with the non-primitive mean spherical approximation model (NP-GV-MSA and NP-BMCSL-MSA models, respectively). In correlating the mean ionic activity coefficients of... 

Graceful labeling is one of the best known labeling methods of graphs. Despite the large number of papers published on the subject of graph labeling, there are few particular techniques to be used by researchers to gracefully label graphs. In this paper, first a new approach based on the mathematical programming technique is presented to model the graceful labeling problem. Then a “branching method” is developed to solve the problem for special classes of graphs. Computational results show the efficiency of the proposed algorithm for different classes of graphs. One of the interesting results of our model is in the class of trees. The largest tree known to be graceful has at most 27 vertices... 

Graceful labeling is one of the best known labeling methods of graphs. Despite the large number of papers published on the subject of graph labeling, there are few particular techniques to be used by researchers to gracefully label graphs. In this paper, first a new approach based on the mathematical programming technique is presented to model the graceful labeling problem. Then a “branching method” is developed to solve the problem for special classes of graphs. Computational results show the efficiency of the proposed algorithm for different classes of graphs. One of the interesting results of our model is in the class of trees. The largest tree known to be graceful has at most 27 vertices... 

Petroleum monoaromatics including benzene, toluene, ethylbenzene, and xylenes (BTEX) are among the notorious volatile organic compounds that contaminate water and soil. In this study, a surfactant- modified natural zeolite and its relevant granulated nanozeolites were evaluated as potential adsorbents for removal of petroleum monoaromatics from aqueous solutions. All experiments performed in batch mode at constant temperature of 20°C and pH of 6.8 for 48 h. The results revealed that the amount of BTEX uptake on granulated zeolites nanoparticles were remarkably higher than the parent micron size natural zeolite (in the order of four times). The isotherms data were analyzed using five models... 

In this study a more precise formulation of electrical capacitance for a cylindrical capacitive sensor is reported. By using different theoretical models such as Coulomb law, Gauss law and Laplace equation the electrical capacitance is calculated. Based on the given models the relation between the capacitance and the geometrical parameters (e.g., cylindrical length) is formulated and by using suitable software capacitance variation is computed and compared for different methods. In Coulomb method, the electrical potential is first solved numerically by using Mathematica and then the electrical capacitance is computed. It is found that the active capacitor length is crucial parameter in the... 

A new approach for attaining numerical solution to sinusoidal steady-state Maxwell's equations is developed. This approach is based on Yee's method, and can be applied on unstructured grids. A problem is solved by the method and the results show good agreement with the available analytical solution. This method can be improved to be applicable for general unsteady problems. © 2018 Sharif University of Technology. All rights reserved  

Usage of masonry system in many regions of the world like the Eastern Mediterranean, the Middle East, India, and China is still significantly high, despite their highly energy and intensive emission. Most of the failures in this system are caused by low ductility of cement mortars. This type of failure could be seen in masonry structures in areas in east Iran after Kermanshah earthquake in 2017. The present study investigates the shear bond characteristics of structures constructed by masonry using green materials. “Taftan” natural pozzolan and two types of rice husk ash (RHA) were used in mix design of used mortars as green materials. In this investigation, a modified direct shear test... 

In this paper, the transient motion of a three unit intelligent Pipe Inspection Gauge (PIG) while moving across anomalies and bends inside gas/oil pipeline has been investigated. The pipeline fluid has been considered as isothermal and compressible. In addition, the pipeline itself has also been considered to be flexible. The fluid continuity and momentum equations along with the 3D multi body dynamic equations of motion of the pig comprise a system of coupled dynamic differential equations which have been solved numerically. Pig's position and velocity profiles as well as upstream and downstream fluid's pressure waves are presented as simulation results which provide a better understanding... 

We study critical properties of the continuous Abelian sandpile model with anisotropies in toppling rules that produce ordered patterns on it. Also, we consider the continuous directed sandpile model perturbed by a weak quenched randomness, study critical behavior of the model using perturbative conformal field theory, and show that the model has a random fixed point. © 2009 The American Physical Society