Sharif Digital Repository

Activities conducted in this study can be divided into two general sections: synthesis and analysis and identifies the properties. A geopolymeric cement production process includes two steps of thermal activation and alkaline activation. Geopolymers are cementitious materials synthesized by a polycondensation reaction between an aluminate and silicate. The geopolymeric structures of the products were investigated by Fourier transform infrared spectroscopy (FTIR), X-ray powder diffraction (XRD) and scanning electron microscopy (SEM). XRD results showed that there are no significant differences between the XRD patterns of geopolymers and metakaolin. The structure of the geopolymer is typically... 

Al2O3-SiC composite ceramics were prepared by pressureless sintering with and without the addition of MgO, TiO2 and Y2O3 as sintering aids. The effects of these compositional variables on final density and hardness were investigated. In the present article at first α-Al2O3 and β-SiC nano powders have been synthesized by sol-gel method separately by using AlCl 3, TEOS and saccharose as precursors. Pressureless sintering was carried out in nitrogen atmosphere at 1600 °C and 1630 °C. The addition of 5 vol.% SiC to Al2O3 hindered densification. In contrast, the addition of nano MgO and nano TiO2 to Al 2O3-5 vol.% SiC composites improved densification but Y2O3 did not have positive effect on... 

In this study, we have investigated the bioleaching potential of a native strain of Acidithiobacillus ferrooxidans isolated from zinc and lead sulfide mines under varied ambient conditions of growth and substrate consumption. The effects of intermittent irrigation, type of agglomeration, feed formulation in terms of acid, enriched salt solution, initial number of microorganism, and their interactions on the bioleaching of low-grade zinc sulfide ores (containing 5.78% zinc) on growth and biooxidation efficiency of the bacteria have been evaluated. Bioleaching capacities of the isolate were optimized by the utilization the Taguchi method (e-qualitic-4) for design of experiments. As a result,... 

Ceramic-matrix composites containing TiC-TiN have been used in a variety of application because of their superior properties such as high hardness, good wear resistance and high chemical stability. In this research, effect of coke and coke/calcium beds in synthesis of Al2O3-Ti(C, N) composites using alumino-carbothermic reduction ofTiO2 has been investigated. Al, TiO2 and active carbon with additives of extra carbon and NaCl and without additives, in separate procedures, have been mixed. Afterwards, mixtures were pressed and synthesized in 1200°C for 4hrs, in coke and coke/calcium beds, separately. Al2O3-Ti(C,N) composite was synthesized in ternary system of Al-TiO2-C with excess carbon and... 

Fluorine-doped tin oxide (FTO) nano-powders were synthesized by a gel combustion method. To analyse the effect of processing factors and their interactions and to achieve an equation for nano-powder particle size in terms of code factors, D-optimal factorial design was used. Stannous chloride penta-hydride, ammonium fluoride and citric acid were used to synthesize the FTO nano-powders. The structure, morphology and composition of the synthesized powders were characterized by X-ray diffraction, field emission scanning electron microscopy and X-ray photoelectron spectroscopy, respectively. The results revealed the formation of homogenous FTO nano-powders with an average particle size of 20 nm... 

In the present work, G-TiO2 and G-ODA-TiO2 hybrids were prepared by concurrent surface functionalization and reducing of graphene oxide (GO) using octadecylamine (ODA). The G-TiO2 and G-ODA-TiO2 powders were deposited on the copper surface by electrophoretic deposition (EPD) technique. The wettability of coatings revealed the preferable hydrophobic characteristic of G-ODA-TiO2 compared to G-TiO2 and bare copper with water contact angles of 130°, 101°, and 87°, respectively. The anti-corrosion performance of specimens in a 0.5 M H2SO4 solution was appraised by the potentiodynamic polarization (Tafel analysis), which clearly showed that G-TiO2 and G-ODA-TiO2 coatings can act as a great barrier... 

The purpose of this study is to determine the influence of nano-alumina particles on the self-flow characteristics of aluminaspinel self-flowing castables. for this reason, the self-flow characteristics such as; self-flow value and working time of the alumina-spinel castables with different amount of nano-alumina particles have been studied. Also, the mechanical properties and microstructure of these castables have been studied. for the study of nano-alumina (d50 =4 3 nm) addition on selfflow characteristics and other properties of these castables, reactive alumina is substituted by nano-alumina powder in 0-4 wt.% range. The results show that the nano-alumina particles have great effect on... 

Conductive self -electrical stimuli bioactive scaffolds could be used the potential for peripheral nerve regeneration with the maximum efficiency. To produce such conductive self-electrical stimuli bioactive scaffolds, chopped spun piezoelectric nanofibers of polyvinylidene fluoride/mesoporous silica nanoparticle (PVDF/MCM41) are prepared and incorporated in gellan/polyaniline/graphene (gellan/PAG) nanocomposites which have been previously prepared by incorporation of polyaniline/graphene (PAG) nanoparticles in gellan gel at 80 °C. Highly conductive binary doped polyaniline/graphene nanoparticles are prepared by chemical oxidative polymerization of aniline monomer using in-suite... 

In the present article, α-Al2O3 nano powder was synthesized by a simple aqueous sol-gel method by using AlCl3 as precursor. It was shown that the gel calcined at 1000°C, 1100 °Cand 1200 °Cresulted in the formation of a crystalline ?-Al2O3 nano powder. In continue TEOS and saccharose was used to prepare SiO2 xerogels containing carbon nano particles. The conversion of the gel to β-SiC nano powders was accomplished by carbothermal reduction at 1500°Cfor 1 h in argon atmosphere. In second pace alumina matrix composites with nano particles of 5 vol% SiC were prepared with the addition of TiO 2 as sintering aid and densified by pressureless sintering method at 1600°Cand 1630°C for 2 h in nitrogen... 

In the present study, an adaptive sliding mode control method was employed to control a fish robotic system using hardware in the loop methodology. Up to now, few researches have focused on autonomous control of fish robot in dynamic environments which may be the result of difficulties in modeling of hydrodynamic effects on fish robot. Therefore, following the introduction of the nonlinear model for the robot, elongated body theory, suggested by Lighthill, was used to analyze fish movements. Then, kinematics control to track desired trajectories was designed for under-actuated model of robot. Adaptive sliding mode controller, capable of adapting according to changes and uncertainties, was... 

In this study, we have theoretically investigated designing possibility of a seismometer using Fiber Bragg Grating (FBG) and Metal Bellows pairs attached on a mechanical system. This new seismometer can record earthquakes according to sensitivity of fiber optic to changes in physical parameters such as stress and strain. Firstly, in order to understand the quantity and quality of sensor performance, with a mathematically brief description, the effect of stress and strain on the FBG reflection spectrum is examined. FBG is an intrinsic sensing element which can be photoinscribed into a silica fiber. The basic principle of this operation commonly uses FBG based sensor system. The operation is... 

Nanocrystalline Y3-xMMxFe5O12 powders (MM denotes Misch-metal, x = 0.0, 0.25, 0.5, 0.75, and 1.0) were synthesized by a sol-gel combustion method. Magnetic properties and crystalline structures were investigated using X-ray diffraction (XRD), a vibrating sample magnetometer (VSM), and a scanning electron microscope. The XRD patterns showed that the single-phase garnet of Y3-xMMxFe5O12 was formed at x values ≤ 1.0. The saturation magnetization of powders increased with decreasing MM content and reached the maximum value at Y3 Fe5O12. The crystallite size of powders calcined at 800°C for 3 h was in the range of 38-53 nm. © 2008 American Ceramic Society  

The nitrate-citrate gel exhibits auto-catalytic behavior, which can be used to synthesize nanocrystalline YIG powders. In this study, yttrium iron garnet (Y3Fe5O12) nanocrystalline powders were prepared by a sol-gel auto-combustion process. The influence of metal nitrates to citric acid molar ratio (MN/CA) of the precursor solution on the combustion behavior and crystallite size of synthesized powders was investigated by scanning electron microscopy (SEM), thermal analyses (DTA/TGA) and X-ray diffraction (XRD). The results show that with increasing MN/CA value, the combustion rate increases and the single-phase YIG forms at a higher temperature. The crystallite size of the single phase YIG... 

The nitrate-citrate gels exhibit auto-catalytic behavior, which can be used to synthesize the nanocrystalline YIG powders. In this study yttrium iron garnet (Y3Fe5O12) nanocrystalline powders were prepared by a sol-gel auto-combustion process. The influence of pH value of the precursor solution on the combustion behavior and the garnet phase formation of synthesized powders were investigated by scanning electron microscopy (SEM), thermal analysis (DTA/TGA), infrared (IR) spectroscopy and X-ray diffraction technique (XRD). The results show that with increasing pH value, the combustion rate increases. The as-burnt powder prepared with pH 1 yielded a single phase YIG after calcination at 800... 

Washing the corpse and dressing the body prior to burial is an act of love and necessity in many religions. Applying robotics and automation technologies for the washing and preparation of a deceased Muslim in accordance with the Islamic Shari'at laws has been the challenging foundation of this research. With an increasing annual population growth resulting in an increase in the number of deaths (historically and/or immediately after a national disaster), automating part of this procedure to increase the speed of operation, reducing the health risks to the personnel of washing rooms "Ghassalkhaneh™ at the cemeteries and enhancing their quality of life have been the primary objectives of this... 

Despite brilliant properties of glass ionomer cement (GIC), its weak mechanical property poses an obstacle for its use in medical applications. The present research aims to formulate hydroxyapatite/yttria-stabilized zirconia (HA/YSZ) in the composition of GIC to enhance mechanical properties and to improve fluoride release of GIC. HA/YSZ was synthesized via a sol-gel method and characterized by applying X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), X-ray photo-emission spectroscopy (XPS) and simultaneous thermal analysis (STA) along with transmission electron microscopy (TEM) methods. The synthesized nanocomposite was mixed with GIC at a fixed composition of 5.... 

Hydroxyapatite (HAp) nanorods with uniform morphology and controllable size were successfully synthesized by precipitating Ca(NO3) 24H2O and (NH4)2HPO4 in the presence of cetyltrimethylammonium bromide (CTAB) and polyethylene glycol 400 (PEG 400) as cationic surfactant and non-ionic cosurfactant, respectively, under hydrothermal conditions. The effect of hydrothermal temperature on the composition, morphology and size of HAp particles was studied using X-ray diffraction (XRD), Fourier transform infrared spectrometry (FTIR) and scanning electron microscopy (SEM). Results revealed that the morphology and size of HAp particles can be effectively controlled by the presence of CTAB and PEG... 

Using a combined hydrothermal and sol–gel route, TiO2-capped ZnO nanoparticles with an average size of 60 nm were prepared. The titania shell was amorphous with a thickness of ~10 nm. Formation of Zn2TiO4 phase at higher calcination temperature was noticed. Effects of Ti/Zn molar ratio and coating time on the thickness of TiO2 shell and the photoactivity of the particles for decolorization of Methylene Blue (MB) under UV lamp irradiation (3 mW/cm2) were investigated. The nanoparticles were characterized by X-ray diffraction, transmission electron microscopy, fourier-transform infrared spectrometry (FTIR), diffuse reflectance spectroscopy (DLS), and atomic absorption spectroscopy. Analysis of... 

Using a combined hydrothermal and sol-gel route, TiO 2 -capped ZnO nanoparticles with an average size of 60 nm were prepared. The titania shell was amorphous with a thickness of ∼10 nm. Formation of Zn 2TiO 4 phase at higher calcination temperature was noticed. Effects of Ti/Zn molar ratio and coating time on the thickness of TiO 2 shell and the photoactivity of the particles for decolorization of Methylene Blue (MB) under UV lamp irradiation (3 mW/cm 2) were investigated. The nanoparticles were characterized by X-ray diffraction, transmission electron microscopy, fourier-transform infrared spectrometry (FTIR), diffuse reflectance spectroscopy (DLS), and atomic absorption spectroscopy.... 

Creating laser texture on dental implants is a novel method for accelerating osseointegration and prolongation of lifespan. The purpose of this research was twofold: (1) Creating intersecting lines pattern with different angles (0°, 15°, 30°, 45°, 60°, 75°, and 90°) on the surface of Ti6Al4V, using pulse Nd:YAG laser with a wavelength of 1064 nm and a pulse length of 170 ns and (2) comparing optical and SEM images, EDS analyses, contact angles (CAs), and surface free energies (FEs) for different intersecting lines angles. CA and FE depended on the intersecting lines angle according to Y = Y 0 + A sin (x B + C), where Y is the CA or FE; x is the intersecting lines angle; and Y0, A, B, and C...