Sharif Digital Repository

In this work, sulfonated polycarbonate (SPC ) membranes with different acid contents have been prepared by conducting sulfonation reaction at room temperature using Chlorosulfonic acid (CSA) as sulfonating agent at different concentration of acid in reacting solution. The SPC membranes were obtained by casting from 10% solution of SPC in chloroform at room temperature. The prepared membranes were characterized using Ion exchange capacity (IEC), and degree of sulfonation (DS), Fourier Transform Infrared (FTIR), NMR spectra, Thermal Gravimetric Analysis (TGA) and Water uptake. The obtained results showed that with increaseing in Chlorosulfonic acid content in sulfonation reaction IEC and DS of... 

To study the interaction between energy sector and the Iranian economy, an energy-economy model has been developed which itself is a part of an integrated model of Energy Planning Support System (EPSS). The model is a dynamic computable general equilibrium (DCGE) model which evaluates the medium to long-term economic developments through investment decisions. Four groups of economic agents have been considered: households, firms, governments and foreign sectors. The economic behavior of each agent along with the institutional links among them has been modeled based on neoclassical theory of general equilibrium. Therefore, the model simulates the working of a market economy and solves for a... 

For policy and decision makers, controlling pollution emissions are a real challenge. The best way to collect fiscal resources, optimal distribution of them to developing businesses in optimal energy production and reducing emissions, are important issues to be decided. Finding a monetary value emissions imposing to community is a key point to find out how they are affecting the whole economy and this will help decision makers to conduct better road maps and policies. Many different approaches and methodologies are used in literature to find appropriate answers to above mentioned questions and phenomena, in this research, integrated assessment modeling methodology is used, an economical... 

The main subject of this thesis is to improve conventional CFD algorithms applied in numerical simulation of inviscid unsteady flows around moving boundaries with large relative motions, on unstructured grids. All challenges in this regard are reviewed, and appropriate efficient schemes are introduced to address them. A new scheme is presented for valid grid generation during grid movement and is implemented for 2D and 3D problems. Customary three dimensional convergence acceleration techniques such as implicit time stepping and multigriding have been applied. For implicit solution of the flow equations a new algorithm is used. Via a special renumbering algorithm, the approximate... 

Nowadays, enterprise storage systems are widely used in data centers such as databases, servers, and bank institutes. Due to mechanical activity of disk drives, these systems are one of the most power consumptive components in data centers. Prefetching and RAID, which are employed to enhance performance, are widely used in data storage systems. These two methods, however, impose significant energy overhead to the system due to the increased disk activity. In this thesis, we first elaborate shortcomings of prefetching and RAID methods. Then, we propose a new energy efficient and RAID-compatible prefetching method (LPTAP), which aims at improving performance and energy consumption. To evaluate... 

In this dissertation we study the derivation of the second law of thermodynamics from an underlying physics. After discussing different methods for this derivation, we conclude that the only way to fulfill this, is to use a probabilistic mechanics which has probability as an inherent concept in itself, not as a supplementary one like statistical mechanics. This mechanics in contrary to the Newtonian mechanics, should be indeterministic  

In railway transportation network, there are spots that we have to intersect with highway network. These intersections break into two branches named grade crossing and unlevel crossing depend on their structure. Grade crossings from the view of protection are grouped into protected crossings and unprotected crossings. Protected crossings depend on their traffic control devices are categorized into active crossings and passive crossings.There are many factors that influence highway-railroad grade crossing design. Some of these factors can vary widely by drivers' behavior. These factors have been developed in models by AASHTO and its publications and shaped like we have them today. In order to... 

In this thesis, a control method to cope with the fault in the two-satellite two-tether satellite systems has been proposed to avoid failing the mission in the case one tether is torn. A new model for the tethered satellite system with two tethers has been developed to show the effects of tethers’ tension forces in the attitude dynamics. One of the main features of this model is the ability of changing the tethers’ connection points to the co-satellite for attitude control purposes. As a result, tethers’ tension forces are used as control actions to reduce the fuel consumption. The introduced coupled tethered satellite system has been controlled using the model predictive control method.... 

Investigation of the consistency between physical theories has always resulted in the advancement of physics. Meanwhile, study of the consistency between quantum mechanics and thermodynamics has led to the development of a branch in theoretical physics called quantum thermodynamics. In addition to the consistency problem,employing other features of quantum mechanics such as coherency and entanglement, to enhance thermodynamic processes is another ongoing subject of research. In order to study the thermodynamics of quantum systems, we use the first law of thermodynamics to present a derivation of quantum potential. Quantum potential is a term in the equations of motion of a quantum system of... 

In this thesis, a new approach is proposed for two-level optimal control of large-scale nonlinear systems. In this approach, by defining some parameters as coordination parameters the overall system is decomposed into several interactive subsystems, where the optimization problem redefines for each one of them. The obtained sub-problems which are in the form of standard optimal control problems with lower dimension are solved in the first level. To obtain the overall optimal solution, coordination of the first level solutions is performed in the second level. For solving the first level problems, the indirect gradient and Newton methods are used. The gradient method is applied in the first... 

One of usual criterion which detrimines how much two polynomials are close to each other is smallness of the norm of vector that is formed from subtraction of their corresponding coefficients. Using this criterion, in this dissertation we become involved in investigation of two similar problems. First one is determination of the closest non-Hurwitz polynomial to a Hurwitz one. During this activity, the robustness margin of Hurwitz polynomial whose coefficients are subject to uncertainty is determined. The second problem is determination of the closest Hurwitz polynomial to another polynomial which is not Hurwitz. Unlike to the first problem, this problem is extremely hard. The solution of...