Sharif Digital Repository

Electrodeposition of composite coatings containing nano particles is very important because this technique is simple and economic. In this research, in order to produce a coating with high hardness and wear resistance, Ni-Co/WC nano composite was co-deposited. Watt’s based bath containing cobalt and tungsten carbide was used and parameters such as preparation of solution, concentration of ingredients and current density were controlled and adjusted. Surface morphology, microstructure and mechanical properties of coatings were studied by SEM and AFM microscopes. Mechanism of electrodeposition was investigated by cyclic voltametry, cronoamperometry and cronopotentiometry techniques and... 

WC-Co hardmetals that are produced through powder metallurgy rout are vastely used as wear resistant parts. In these materials hard particles of wolfram carbide are embodied in a cobalt binder. Because of their high hardness and adequate toughness, hardmetals have found wide range of applications in cutting tool industry. During the last decades a number of researches have been carried out to improve their mechanical and wear properties by different binders and carbide particle sizes. Because of high hardness, Tungsten carbide has a good wear resistant. It has very low thermal expansion coefficient and high wetting ability with molten metals. Unlike high hardness, it has limited toughness.... 

In this research a copper- Tungsten carbided nanocomposite coating prepared by electrodeposition from a sulfate bath in order to increase the hardness and erosion resistance of cooper without loosing cooper's specific physical properties as like as electrical and thermal conductivity. Various parameters were evaluated for finding significant factors in electrodeposition of Cu-Co/WC composite. Current density and concentration of WC and SDS were selected as affective factors. The morphology and structure were characterized by XRD and SEM. The mechanical properties of the coatings, such as hardness, wear resistance and surface roughness were studied with Vickers hardness indentation; pin on... 

Nuclear power is a prominent alternative of fossil fuels that can effectively solve global warming, acid rains and other consequences of air pollutions, caused by combustion. Despite such obvious advantage, this highly compact form of energy suffers from a big problem corresponding to its nuclear waste. Graphene oxide (GO), a lamellar material with wide range of surface functional groups such as epoxy (C-O-C), hydroxyl, and carboxyl offers large surface area as well as high sorption capacity for the metallic cations. This thesis study presents a supercritical, and co-precipitation synthesis of magnetite- graphene oxide (M-GO) in which Fe3O4 nanoparticles are simultaneously formed, surface... 

The Iranian Nuclear waste management Company is responsible for the safe disposal of the low-level radioactive waste resulting from the various processes of the nuclear fuel cycle and other radioactive-related activities. The safety assessment of waste disposal requires the measurement of transport parameters of radioactive nuclides in the soil around the disposal site.In this project, concentration profiles within a column which filled with Anarak Radioactive Waste Disposal Site soil were obtained using collimated gamma scanning method. Concentration profiles were measured at two different times (69 and 138 hours after injection). Then, using STANDMOD software, the equilibrium... 

In this study graphene and graphene adsorbent for the Co2+ ion were created from sodium phenoxide and calcium phenoxide, respectively, using the chemical vapor deposition method, and their chemical, physical, and morphological properties were investigated using FT-IR, UV, XRD, Raman, TEM, FE-SEM, and XPS. The results suggest that the optimum reaction condition for synthesizing mono-layer and multi-layer graphene is the 750 °C temperature for 30 min. The Co2+ adsorbing properties of the synthesized graphene adsorbent from calcium phenoxide was investigated. The investigation of solvation properties suggests insolubility above 650 °C and the kinetic data suggest the rapidness of the Co2+... 

Nuclear waste management in Iran is the responsibility of the Nuclear Waste Company. The waste company is obliged to bury waste with a certain level of radioactivity, resulting from various processes of the nuclear fuel cycle or other processes such as research projects and medical centers, after the necessary measures, finally at the Anarak landfill site. To evaluate the safety of the site, it is necessary to study the parameters of radioactive nucleation in the soil. Humic substances from natural substances in the soil affect the transport of radioactive nuclei. In this project, to study the effects of the presence of humic acid, the soil of Anarak residue in three weight percent... 

Considering the operation of the current nuclear reactors and the country's policy to achieve 10,000 megawatts of nuclear power in the horizon of 1420, as well as the construction of research reactors, we will face a huge amount of radioactive waste in the coming years. Meanwhile, spent ion exchange resins constitute a large amount of low and intermediate level (LILW) solid radioactive waste produced from the nuclear industry. Therefore, appropriate precautionary measures should be taken for the immobilization and disposal of these radioactive wastes in order to ensure the sustainable development of the nuclear industry and the protection of the environment and human health. In this study,...