Sharif Digital Repository

The preparation of high aspect-ratio TiO2 nanotubes and their photocatalytic activity were demonstrated in this study. The high aspect-ratio TiO2 nanotube thin films were produced by electrochemical anodic oxidation of Ti in chloride-containing electrolytes. Nanotubes were doped with different concentrations of ZnO particles through anodization. The catalytic behavior was evaluated under batch reactor with photo-degradation test of Red Dye. The experimental results collectively demonstrate the successful ZnO doping of the resultant nanotube layers with significant abundant OH groups on their increased surfaces. The nanotubes doped with high content combined with an anatase as a two phase... 

We report the effect of the geometric parameters on transparency and conductivity in a metallic nanowire mesh as a transparent electrode. Today, indium tin oxide and fluorine-doped tin oxide are used as the transparent electrode for displays and solar cells. Still, there is a definite need for their replacement due to drawbacks such as brittleness, scarcity, and adverse environmental effects. Metallic nanowire mesh is likely the best replacement option, but the main issue is how to find the optimal structure and how to get the best performance. Since the interaction of light with nanowire mesh is complicated, there is no straightforward rule with a simple analytical solution. We developed a... 

A heat-transfer model was formulated to determine the distribution of temperature within a bioheap of chalcopyrite of Sarcheshmeh copper mine. Bioleaching employs mixed mesophilic and thermophilic microbes for Cu extraction. Thermophiles are better than mesophiles to dissolve CuFeS2. The solution irrigation and aeration rates were taken into account as the main operational factors. The model was validated by comparing the temperature profiles of test columns with those of bioheap. The model was used to find the optimal ratio of irrigation to aeration. It was found that when the solution was fed at a flow rate of 5 kg/m2 h and air was blown at a flow rate of 7.5 kg/m2 h, the transition from a... 

High-temperature (1200-1350°C) corrosion of fused-cast ZrO2-Al2O3-SiO2 (ZAS) refractory contacting lead silicate glass melt (LSG) containing 68.5wt% PbO was investigated by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), differential scanning calorimetry (DSC), x-ray diffraction (XRD), thickness measurement and Archimedes density measurement. ZAS durability was improved by baddeliyete content and deteriorated with open porosity proportion, corundum percentage and eutectic mixture presence. Diffusion of lead resulted in fusion-temperature lowering of the glassy layers embedded within the ZAS particles. Heating caused viscosity drop across the interface, loosening the... 

Transparent Conductive Electrode (TCE), as an essential part of the optoelectronic devices, has become popular owing to its unique properties such as high optical transmittance and conductivity. Among utilized materials for fabrication of TCE, copper nanofibers (NFs)-network have been attracting much attention due to its extraordinary properties such as low sheet resistance, the scalable manufacturing and low-cost fabrication method. However, many challenges exist in the way of multi-step fabrication of network to increase the NFs continuity and consequently, improvement of their electrical conductivity as TCE. Herein, we report a deep investigation of the effective parameters on diameter... 

Transparent Conductive Electrode (TCE), as an essential part of the optoelectronic devices, has become popular owing to its unique properties such as high optical transmittance and conductivity. Among utilized materials for fabrication of TCE, copper nanofibers (NFs)-network have been attracting much attention due to its extraordinary properties such as low sheet resistance, the scalable manufacturing and low-cost fabrication method. However, many challenges exist in the way of multi-step fabrication of network to increase the NFs continuity and consequently, improvement of their electrical conductivity as TCE. Herein, we report a deep investigation of the effective parameters on diameter... 

Effects of pH, D2EHPA, Cyanex® 272 and Cyanex® 302 on extraction of zinc, manganese and cobalt from a Zn-Mn-Co-Cd-Ni containing solution at the room temperature was comprehensively investigated. Addition of Cyanex® 302 indicated a left-shifting-effect on the extraction curve of zinc, a right-shifting-effect on the extraction curve of manganese and no effect on the extraction of cobalt. Addition of Cyanex® 272 shifted all three curves to the right. Therefore, the most suitable extractant for separation of zinc from manganese was therefore 0.3-0.3 mixture of D2EHPA and Cyanex® 302, and that for separation of manganese from cobalt was pure D2EHPA. The stoichiometric coefficient for the... 

Copper-succinate-layered hydroxide (CSLH), a new nanohybrid material, was synthesized as an inorganic-organic nanohybrid, in which organic moiety was intercalated between the layers of a single cation layered material, copper hydroxide nitrate. Microporous scaffold carbon material was obtained by thermal decomposition of the nanohybrid at 500°C under argon atmosphere followed by acid washing process. Furthermore, the heat-treated product of the nanohybrid at 600°C was ultrafine mesoporous metallic copper particles. The results of this study confirmed the great potential of CSLH to produce the carbon material with large surface area (580m2/g) and high pore volume copper powder (2.04cm3/g)  

Undoped and copper doped nanostructured zinc oxides were synthesized by using a series of synthetic layered material, undoped and copper doped zinc hydroxide nitrates at various molar percentages of copper (2-10) within the layers as precursors. The layered materials were heat-treated at 500 °C to produce zinc oxide nanostructures with crystallite sizes in the range of 23-35 nm. Optical studies of the nanostructured copper doped zinc oxides showed the decrease in band gap with increasing content of the doping agent, copper  

In this paper, CuInSe 2 (CIS) nanostructures have been synthesized via a solvothermal method using diethyamine as a solvent. Various morphologies of CuInSe 2 were obtained from the reaction of cupric chloride, indium chloride and selenium powder by changing the solvothermal conditions. The effect of the experimental parameters such as reaction time, temperature and concentration of the selenium powder were studied. The crystalline structures and morphologies of the products were characterized by means of X- ray diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM) techniques, respectively. The results show that the morphology and dimensions of the CIS nanostructures... 

In this study, an equiatomic mixture of Ni and Ti powders has been mechanically milled for 180 h in a planetary mill in order to study the product phase of milling process. Miedema's semi empirical method has been used in order to calculate the energy of solid solution and amorphous phases and the effect of defects like dislocations and grain boundaries have been considered in this thermodynamic approach. The results showed that amorphous phase is more stable than solid solution after mechanical milling process. It seems these results are in contrast with Mousavi et al. [1] results but there are some points that we should consider in this approach. Applying of common tangent rule and... 

Electrochemical potential noise analysis was used to investigate corrosion behavior of copper electrodes in presence of 0.001, 0.005, 0.01 and 0.02 M benzotriazole (BTA) inhibitor. Energy distribution of the potential noise was obtained from wavelet transformation using the 4th order Daubechies pattern. Two lowest frequencies were added-up and fitted to the impulse response of the first order circuit to achieve the time-constant vs. concentration (T-C) diagram. T-C diagram can be used either as a conventional diagram of inhibition efficiency or a tool for evaluation of the surface film dielectric constant. The assumptions made in this treatment were confirmed by EIS method. © 2009 Elsevier... 

Hot corrosion is a serious problem in gas turbines due to poor quality fuels which contain Na, V, S and Cl. To resolve the problem, Cr-aluminide was coated on IN-738LC superalloy with a two steps pack cementation process. Oxidation behavior and near-surface microstructure of the coating showed consecutive increase in destruction by exposition to Na2SO4, 75Na2SO4 + 25 V2O5 and 70Na2SO4 + 25 V2O5 + 5NaCl (wt.%). Kinetic studies indicated parabolic corrosion rate in salt-less samples due to diffusion. Similar expression for salt-covered samples was assessed for oxide dissolution. Plate-like, broken-plate-like and cauliflower-like morphologies attributed to the corrosion products were observed... 

This work describes coating of NiCoCrAlY on IN-738LC superalloy by high-velocity oxygen fuel (HVOF) process. Properties of the coatings are significantly influenced by oxygen/fuel ratio and other spraying parameters. The effect of oxygen/fuel ratio on the oxidation behavior, bond strength, hardness, roughness and microstructure including porosity, inclusion formation and unmelted particles are discussed here. The porosity and inclusion in C1 coating are maximal. C2 coating with oxygen/fuel ratio of 2 has the highest bond strength and the lowest unmelted particles. C3 coating with the lowest total porosity and inclusion has the minimal roughness and the highest oxidation resistance and... 

Abstract: This work describes coating of NiCoCrAlY on IN-738LC superalloy by high-velocity oxygen fuel (HVOF) process. Properties of the coatings are significantly influenced by oxygen/fuel ratio and other spraying parameters. The effect of oxygen/fuel ratio on the oxidation behavior, bond strength, hardness, roughness and microstructure including porosity, inclusion formation and unmelted particles are discussed here. The porosity and inclusion in C1 coating are maximal. C2 coating with oxygen/fuel ratio of 2 has the highest bond strength and the lowest unmelted particles. C3 coating with the lowest total porosity and inclusion has the minimal roughness and the highest oxidation resistance... 

The unique properties of NiTi alloy, such as its shape memory effect, super-elasticity and biocompatibility, make it ideal material for various applications such as aerospace, micro-electronics and medical device. In order to meet the requirement of increasing applications, great attention has been given to joining of this material to itself and to other materials during past few years. Laser welding has been known as a suitable joining technique for NiTi shape memory alloy. Hence, in this work, a comparative study on laser welding of NiTi wire to itself and to AISI 304 austenitic stainless steel wire has been made. Microstructures, mechanical properties and fracture morphologies of the... 

A novel nanocomposite of ZnO-PbO with flower-like nanostructure was fabricated from zinc acetate and lead nitrate as principle raw materials via an in situ process. The novelty of this study consists in the use of a common approach for fabricating of ZnO and PbO nanoparticles simultaneously. From these experiments the conclusion might be drawn that Zn(NH4) 2 4+ ions and Pb(OH)2 act as precursors for the nucleation and growth of ZnO and PbO respectively under microwave irradiation. The precursors formation were carried at two stages: reaction between zinc ions and lead nitrate with ammonium ion and hydroxide sodium respectively. The average crystalline size of Zno and PbO has been analysed by... 

Composite aluminum-SiC foam was manufactured by injection of air and addition of reinforcement particles into the liquid aluminum. Microstructure and mechanical properties of the Al/SiC foams were investigated by scanning electron microscopy and compression tests. Results showed that both the cell size and the wall thickness augmented with increasing of the SiC reinforcement particles; while SiC particles resulted in the reduction of the plateau border length. With more SiC particles, plateau stress became larger; but maximum plateau strain became smaller. The stress-strain curves exhibited serrations in the plateau region due to addition of the SiC particles  

The current study was carried out to investigate the kinetics of reactions for the pressure oxidative leaching of a molybdenite concentrate in less than one hour. The effects of oxygen pressure, stirring speed, pulp density, acid concentration and temperature on the leaching rate of the molybdenum were studied. It was found that about 85% of molybdenite was oxidized to molybdic oxide precipitate with remaining molybdenum dissolved in the leaching liquor. Analysis of experimental data showed that the reaction is chemically controlled with activation energy of 68.8 kJ/mol. Furthermore SEM images showed no significant boundary diffusion layer and it was noted that the molybdic oxide... 

Electrophoretic technique was used to deposit micro- and nano-sized aluminum nitride coatings on stainless steel surfaces by using a well-dispersed stable suspension produced by addition of AlN powder plus a small amount of iodine to ethanol. Parabolic regime governed the deposition. Electrophoretic deposition for 240 s at 100 V resulted in formation of a uniformly dense film on the top, but a porous inhomogeneous layer at the bottom. This was attributed to fast deposition of coarse particles and/or agglomerates at large electric fields. After drying, micro-sized particles led to a uniform crack-free interface while nano-particles resulted in fragmented non-cohesive layers. Weight loss...