Loading...
Search for: ghorbanzadeh--maryam
0.128 seconds

    Carbon dioxide reforming of methane by pulsed glow discharge at atmospheric pressure: the effect of pulse compression

    , Article Journal of Applied Physics ; Volume 101, Issue 12 , 2007 ; 00218979 (ISSN) Ghorbanzadeh, A. M ; Modarresi, H ; Sharif University of Technology
    2007
    Abstract
    Methane reforming by carbon dioxide in pulsed glow discharge at atmospheric pressure is examined. The plasma pulse is compressed to less than 50 ns. This compression enables one to work at higher frequencies, over 3 kHz, without glow-arc transition. The main products of the reaction are synthetic gases (H2, CO) and C2 hydrocarbons. Approximately 42% of plasma energy goes to the chemical dissociation, when the reactant ratio is C O2 C H4 =1. At this point, the energy expense is less than 3.8 eV per converted molecule while reactant conversions are relatively high reaching to 55% (C H4) and 42% (C O2). The reactor energy performance even gets better at higher C O2 C H4 ratios. While energy... 

    Solution Combustion Synthesis of Spinel-type (Cu,Co) 3O4 Nanopowder

    , M.Sc. Thesis Sharif University of Technology Ghorbanzadeh, Milad (Author) ; Yoozbashizadeh, Hossein (Supervisor)
    Abstract
    In this study, nano-powders of copper-cobalt spinel (CuCo2O4) were fabricated by solution combustion synthesis (SCS) of Cu and Co nitrates with urea, glycine,acid citric and alanine. The method involved exothermic decomposition of viscous liquid nitrates and the fuel. Products which were synthesized by using this fuels contained less impurity constituents. Duo to low purity, other factors which have influence on synthesis process investigated and observed that pH have key role on process. X-ray diffraction (XRD) patterns gave crystal structure and the existing phases. Particle size distribution and morphology changes were studied by dynamic light scattering (DLS) and field emission scanning... 

    Application of sol-gel technique to synthesis of copper-cobalt spinel on the ferritic stainless steel used for solid oxide fuel cell interconnects

    , Article Journal of Power Sources ; Vol. 266, issue , 2014 , pp. 79-87 ; ISSN: 03787753 Paknahad, P ; Askari, M ; Ghorbanzadeh, M ; Sharif University of Technology
    2014
    Abstract
    The conductive CuCo2O4 spinel coating is applied on the surface of the AISI 430 ferritic stainless steel by the dip-coating sol-gel process and it is evaluated in terms of the microstructure, oxidation resistance and electrical conductivity. The results show that the CuCO2O 4 coating forms a double-layer scale consisting of a Cr, Fe-rich subscale and Cu-Co spinel top layer after 500 h in air at 800 °C. This scale is protective, acts as an effective barrier against Cr migration into the outer oxide layer and alleviates the cathode Cr-poisoning. The oxidation resistance is significantly enhanced by the protective coating with a parabolic rate constant of 5.8 × 10-13 gr2 cm-4 s -1, meanwhile... 

    Characterization of nanocrystalline CuCo2O4 spinel prepared by sol–gel technique applicable to the SOFC interconnect coating

    , Article Applied Physics A: Materials Science and Processing ; Volume 119, Issue 2 , May , 2015 , Pages 727-734 ; 09478396 (ISSN) Paknahad, P ; Askari, M ; Ghorbanzadeh, M ; Sharif University of Technology
    Springer Verlag  2015
    Abstract
    CuCo2O4 spinel nanopowders were synthesized by sol–gel method. The optimal values of pH and molar ratio of citric acid to metal ions (RC), and the influence of the calcination temperature and time were investigated. As-prepared materials were characterized by XRD, TGA, DSC, FE-SEM and electrical and coefficient of thermal expansion (CTE) measurements. It was found that pH = 4.5 and RC = 1 are the optimum conditions to produce pure CuCo2O4 nanopowders. The electrical conductivity was increased remarkably from 15.2 to 27.5 S cm−1 with an increase in temperature from 500 to 800 °C. Over the temperature range of 25–800 °C, the CTE of... 

    Assessment of Performance Based Behavior of of the Rock Mass Abutment Anchorage System during Construction of Karun IV Bridge by Numerical Methods

    , M.Sc. Thesis Sharif University of Technology Ghorbanzadeh, Alireza (Author) ; Sadaghiani, Mohammad Hossein (Supervisor)
    Abstract
    Three dimensional analyses have been carried out for predicting the behavior of the jointed rock slope of the abutments of the bridge which is proposed to be constructed across the river Karun4 in Iran using 3DEC. The rock overall slope angle is approximately 60 to 70 degrees, composed of highly jointed rock mass and the joint spacing and orientation are varying at different locations. Since 3DEC is a three-dimensional numerical code, utilizes a Lagrangian calculation scheme to model large movements and deformations of a blocky system, allows for modeling of large movements and rotations, and including complete detachment of rigid or deformable discrete blocks has been utilized for the... 

    Methane conversion to hydrogen and higher hydrocarbons by double pulsed glow discharge

    , Article Plasma Chemistry and Plasma Processing ; Volume 25, Issue 1 , 2005 , Pages 19-29 ; 02724324 (ISSN) Ghorbanzadeh, A. M ; Matin, N. S ; Sharif University of Technology
    2005
    Abstract
    Pulsed atmospheric glow plasma, sustained by corona discharge, was utilized to convert methane. Analysis by gas chromatography showed that hydrogen and C2-products are the main constituents of outlet mixture while C 2+-products with small concentrations were also detected. The chemical energy efficiency turned out to be about 9% for the best result obtained by this type of reactor. It has been shown that more improvement of energy efficiency is possible by increasing ' the pulse repetition rate  

    Efficient methane conversion to hydrogen and hydrocarbons by combination of corona and glow discharge

    , Article Czechoslovak Journal of Physics ; Volume 54, Issue SUPPL. 3 , 2004 , Pages C990-C994 ; 00114626 (ISSN) Ghorbanzadeh, A. M ; Matin, N. S ; Sharif University of Technology
    Kluwer Academic Publishers  2004
    Abstract
    In this study we offer a new type of plasma which consists of double, corona and glow, discharge to convert natural gas, the main part of which is methane. The most important future of this type of plasma is the steady increase of overall chemical energy efficiency by enhancement of repetition rate. At repetition rate of R = 80 Hz, the energy efficiency of 5.5% was increased to 10% at R = 330 Hz and more improvement was yet expected at higher repetition rates. Easy control of selectivity of products that were hydrogen, acetylene, ethylene, ethane and hydrocarbons with up to 5 carbons, was also possible by repetition rate  

    3d Design of a Microfluidic Chip for Anticancer Drugs Screening

    , M.Sc. Thesis Sharif University of Technology Hashemi, Maryam Sadat (Author) ; Mashayekhan, Shohreh (Supervisor) ; Saadatmand, Maryam (Supervisor)
    Abstract
    Nowadays, advanced and inexpensive pre-clinical methods for investigating the effects of anti-cancer drugs are expanding. One of the latest three-dimensional laboratory modeling for evaluating the effects of drugs is the use of tumor-on-chip technology, which actually models the physiological system of the body through three-dimensional scaffolds, multicellular cultures, and shaped vascular systems. In this study, three-dimensional culture of cancer cells was performed in the form of spheroids. A chip of U-shaped microstructures with and without gaps was used to trap cells and form cancer spheroids. We simulated the simultaneous effect of drug and oxygen concentration distribution inside the... 

    Configuration of Steel Catenary Risers for the Caspian Sea Deepwater Environment

    , M.Sc. Thesis Sharif University of Technology Ghorbanzadeh, Mohammad (Author) ; Golafshani, Ali Akbar (Supervisor)
    Abstract
    Marine risers are tubular components, which are used to transfer fluids between seabed and floating platform. They may have a great share in cost of oil and gas production systems. One of the risers used in deep-water, is Steel Catenary Riser which is an economic alternative. However, amongst issues in designing this type of risers, high stress level in floating platform connection point and seabed touch- down zone is notable which is created due to platform movements, currents and wave loading and finally, leads to fatigue life reduction. Using buoyancy modules which are attached to risers is one of stress levels reduction solutions in hotspot points. In this study, considering the Caspian... 

    An investigation of crystallization kinetics of the Na3MnCO3PO4 cathode material, synthesized by the hydrothermal method

    , Article Materials Chemistry and Physics ; Volume 214 , 2018 , Pages 73-79 ; 02540584 (ISSN) Hassanzadeh, N ; Sadrnezhaad, S. K ; Ghorbanzadeh, M ; Sharif University of Technology
    Elsevier Ltd  2018
    Abstract
    Na3MnCO3PO4 (NMCP) is produced by hydrothermal synthesis for rechargeable sodium-ion battery (SIB) cathode. Mechanism of formation of NMCP was investigated by measuring the influence of time and temperature on the rate of production of the NMCP crystallites. X-ray diffraction analysis of the synthesized samples showed that MnCO3 first formed as an intermediate phase. Na3MnCO3PO4 was, however, the last phase retained after 24 h of the hydrothermal process at 120 °C. Sigmoidal shape of the crystallization curves followed the Avrami–Erofeev model which described the chemical kinetics of the Na3MnCO3PO4 formation. Respective apparent activation energies of 29.10 for nucleation and 73.91 kJ/mol... 

    High energy efficiency in syngas and hydrocarbon production from dissociation of CH4-CO2 mixture in a non-equilibrium pulsed plasma

    , Article Journal of Physics D: Applied Physics ; Volume 38, Issue 20 , 2005 , Pages 3804-3811 ; 00223727 (ISSN) Ghorbanzadeh, A. M ; Norouzi, S ; Mohammadi, T ; Sharif University of Technology
    2005
    Abstract
    The efficient production of syngas from a CH4+CO2 mixture in an atmospheric pulsed glow discharge, sustained by corona pre-ionization, has been investigated. The products were mainly syngas (CO, H2) and hydrocarbons up to C4, with acetylene having the highest selectivity. The energy efficiency was within 15-40% for different experimental conditions, which demonstrates a comprehensive improvement relative to the achievements of other types of non-equilibrium plasma. These values are, however, comparable with the efficiencies obtained by gliding arc plasmas but this plasma operates at near room temperature. Furthermore, it has been shown that the energy efficiency is increased by decreasing... 

    Improvement of the electrochemical performance of a nickel rich LiNi0.5Co0.2Mn0.3O2 cathode material by reduced graphene oxide/SiO2 nanoparticle double-layer coating

    , Article New Journal of Chemistry ; Volume 43, Issue 6 , 2019 , Pages 2766-2775 ; 11440546 (ISSN) Razmjoo Khollari, M. A ; Paknahad, P ; Ghorbanzadeh, M ; Sharif University of Technology
    Royal Society of Chemistry  2019
    Abstract
    Due to its high discharge capacity, low cost, and good safety, LiNi0.5Co0.2Mn0.3O2 (NCM 523) is regarded as a promising cathode material for the next-generation of lithium-ion batteries. However, poor cycling stability and rate capability are the main disadvantages of the NCM 523 cathode material. In this work, SiO2 single layer-coated and reduced graphene oxide (outer)/SiO2 (inner) double layer-coated NCM 523 have been prepared by a facile wet chemical method. Field emission scanning electron microscopy (FESEM), energy dispersive X-ray (EDX) analysis, transmission electron microscopy (TEM), Raman spectroscopy and Fourier transform infrared (FTIR) spectroscopy results confirm that NCM 523... 

    Model Checking of Stochastic Activity Networks

    , M.Sc. Thesis Sharif University of Technology Maryam Bagheri (Author) ; Movaghar, Ali (Supervisor)
    Abstract
    Modeling and performance evaluation of the real time distributed systems is a significant problem. Stochastic activity network is one of the high level models used for this purpose. This network is an extension of generalized stochastic Petri net which is more powerful and flexible than other Petri net extensions. Checking the satisfiability of properties such as performance, dependability and user's expected properties is considerable in these models. Thus, using the approaches and generating modeling and model checking tools with the mentioned purpose is attractive. A model checker automatically checks the correctness of the system behaviors as properties against the model by getting the... 

    Fabrication of Thick Scaffold with Microfluidic Channels by Bioprinter

    , M.Sc. Thesis Sharif University of Technology Khalighi, Sadaf (Author) ; Saadatmand, Maryam (Supervisor)
    Abstract
    Cardiovascular diseases are among the leading causes of death worldwide. For instance, in 2015, almost 31% of the world’s mortality rate was due to these causes. One of these diseases is cardiac coronary vessels’ occlusion which leads to the insufficient blood supply to the heart tissue and cardiomyocytes death after Myocardial Infarction (MI). After MI, a hierarchy of events in the heart tissue changes heart muscle and forms cardiac fibrosis. This fibrotic tissue does not have the native one’s properties and function, so it will cause cardiac arrest and patient death. Therefore, it is obvious that vascular network plays a crucial role in the heart function. The importance of cardiac... 

    Robust Estimation and Control of a Planet Lander

    , M.Sc. Thesis Sharif University of Technology Ahmadvand, Reza (Author) ; Kiani, Maryam (Supervisor)
    Abstract
    This study has focused on the important problem of landing on a planet as an important current and future space mission. In this regard, dynamics modeling and integrated state estimation and control problems have been investigated in different views. To this aim, first a novel concurrent representation for translational and rotational kinematics has been developed based on the extension of modified Rodrigues parameters to dual space. This parameter set, called dual modified Rodrigues parameters (DMRP), is then utilized to establish an integrated roto-translational dynamic. The proposed DMRP-based kinematics and dynamics have been verified via comparison to traditional methods of... 

    Optimal Control of Unknown Interconnected Systems via Distributed Learning

    , M.Sc. Thesis Sharif University of Technology Farjadnasab, Milad (Author) ; Babazadeh, Maryam (Supervisor)
    Abstract
    This thesis addresses the problem of optimal distributed control of unknown interconnected systems. In order to deal with this problem, a data-driven learning framework for finding the optimal centralized and the suboptimal distributed controllers has been developed via convex optimization.First of all, the linear quadratic regulation (LQR) problem is formulated into a nonconvex optimization problem. Using Lagrangian duality theories, a semidefinite program is then developed that requires information about the system dynamics. It is shown that the optimal solution to this problem is independent of the initial conditions and represents the Q-function, an important concept in reinforcement... 

    Utilizing Gaussian Processes to Learn Dynamics of Unknown Torques Acting on a Spacecraft

    , M.Sc. Thesis Sharif University of Technology Baradaran, Behdad (Author) ; Kiani, Maryam (Supervisor)
    Abstract
    Accurate and fast attitude estimation of a rigid body plays an essential role in the performance of a vehicle’s control system, especially aerospace vehicles. Ample works have been done to increase the accuracy and speed of the attitude estimation process, but all have been developed according to a model-based approach. This approach assumes that the torques acting on the body have a known dynamical model that is used for the attitude estimation. The purpose of the present research is to estimate the attitude via a model-free approach, i. e. dynamics of the torques acting on the body are no longer assumed to be known, and its learning is the next step. Thus, the problem formulation of this... 

    Stabilization and Pole-Placement by Structurally-Constrained Controllers: A Graph-Theoretic Approach

    , M.Sc. Thesis Sharif University of Technology Moushaee, Pegah (Author) ; Babazadeh, Maryam (Supervisor)
    Abstract
    This thesis presents a new approach to design structural output feedback controllers with stabilization and pole-placement at desired points on the S plane. It is assumed that the linear time-invariant system has no fixed mode corresponding to the specified control structure, outside the desired region of the closed-loop poles, such that the structural controller design problem is theoretically feasible. To this end, the structural output controller design problem is first transformed into a structurally equivalent problem based on the solution of a set of discrete linear programs. Then, by using the resultant structure, a new method is proposed for designing static and dynamic control loops... 

    Fabrication the Hydrogel Microfibers Using Bioprinter with Application in Cardiovascular Model

    , M.Sc. Thesis Sharif University of Technology Heidari, Faranak (Author) ; Saadatmand, Maryam (Supervisor)
    Abstract
    Cardiovascular disease (CVD) currently remains a considerable challenge for clinical treatments. CVDs account for N17.5 million deaths per year and will predictably increase to 23.6 million by 2030. The main purpose is to create human model systems to study the effect of disease mutations or drug treatment on the heart. In addition, engineered cardiac tissues are considered promising candidates to be transplanted to improve the function of diseased hearts. For engineered active tissues/organs, 3D bioprinting can fabricate complex tissue architecture with a spatiotemporal distribution of bioactive substances (cells, growth factors, and others) to better guide tissue regeneration. However,... 

    Design of Microfluidic Chip for 3D Cell Culture

    , M.Sc. Thesis Sharif University of Technology Ghobadi, Faezeh (Author) ; Saadatmand, Maryam (Supervisor)
    Abstract
    Understanding biological systems requires extensive knowledge of individual parameters, and to study the processes of cell differentiation and cell behavior, a suitable environment must be created with the physiological conditions of the human body. For this purpose, with the knowledge of microfluidics, a microenvironment can be provided to study the behavior of cells on a small scale. The use of bone tissue model microfluidic chips is an alternative and new method in which it is possible to study the behavior of cells to differentiate into bone and to examine the toxicity of drugs, which in itself can help in the effective and successful treatment of these cases show. Therefore, in this...