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The polysaccharide, kappa-carrageenan (κC) was chemically modified to achieve a novel superabsorbent hydrogel via graft copolymerization of methacrylamide (MAM) onto the substrate followed by alkaline hydrolysis. Ammonium persulfate (APS) and N,N′-methylene bisacrylamide (MBA) were used as a free-radical initiator and a crosslinker, respectively. The saponification reaction was carried out using sodium hydroxide aqueous solution. Either κC-g-PMAM or hydrolyzed κC-g-PMAM (PMAM: polymethacrylamide) was characterized by FT-IR spectroscopy. The effect of grafting variables (i.e. concentration of MBA, MAM, and APS) and alkaline hydrolysis conditions (i.e. NaOH concentration, hydrolysis time and... 

In this study, a series of highly swelling hydrogels based on sodium alginate (NaAlg) and polymethacrylamide (PMAM) was prepared through free radical polymerization. The graft copolymerization reaction was performed in a homogeneous medium and in the presence of ammonium persulfate (APS) as an initiator andN,N′-methylenebisacrylamide (MBA) as a crosslinker. The crosslinked graft copolymer, alginate-graft-polymethacrylamide (Alg-g-PMAM), was then partially hydrolyzed by NaOH solution to yield a hydrogel, hydrolyzed alginate-graft-polymethacrylamide (H-Alg-g-PMAM). During alkaline hydrolysis, the carboxamide groups of Alg-g-PMAM were converted into hydrophilic carboxylate anions. Either the... 

Some new relations have been established between Wiener indices, stability numbers and clique numbers for several classes of composite graphs that arise via graph products. For three of considered operations we show that they make a multiplicative pair with the clique number  

The energy of a graph G, E(G), is defined as the sum of absolute values of the eigenvalues of its adjacency matrix. In Akbari and Hosseinzadeh (2020) [3] it was conjectured that for every graph G with maximum degree Δ(G) and minimum degree δ(G) whose adjacency matrix is non-singular, E(G)≥Δ(G)+δ(G) and the equality holds if and only if G is a complete graph. Let G be a connected graph with the edge set E(G). In this paper, first we show that E(L(G))≥|E(G)|+Δ(G)−5, where L(G) denotes the line graph of G. Next, using this result, we prove the validity of the conjecture for the line of each connected graph of order at least 7. © 2021 Elsevier Inc  

The Internet of Things (IoT) presents a new paradigm of the future internet that intends to provide interactive communication between various processing object via heterogeneous networks. The routing protocol in the IoT environment is Routing Protocol for Low-Power and Lossy Networks (RPL). The current RPL specification defines primary security modes; therefore it is vulnerable to topological attacks. In this paper the RPL routing mechanism, its topological vulnerabilities and two important topological attacks namely version number attack and rank spoofing attack are analyzed. To counter the mentioned attacks, a lightweight Identity Based Offline–Online Signature based scheme is proposed.... 

The Publisher regrets an incorrect figure was placed in the pdf version of the article. © 2018 Springer Science+Business Media, LLC, part of Springer Nature  

The Internet of Things (IoT) presents a new paradigm of the future Internet that intends to provide interactive communication between various processing objects via heterogeneous networks. The IPv6 over Low power Wireless Personal Area Networks (6LoWPAN) is an IPv6 adaptation sub-layer and provides the requirements of IP connectivity between resource-constrained devices in lossy, low power networks. Since the size of a packet in the IPv6 is larger than the size of a frame in the IEEE 802.15.4, the 6LoWPAN adaptation layer performs packet fragmentation. In this paper, first, the 6LoWPAN fragmentation mechanism in terms of security issues is analyzed and then, fragment duplication attack which... 

Information-centric network (ICN) has become a basic research topic with regard to the future architecture of the Internet. Storage and routing data is an important feature of ICN, as it improves network performance and content distribution. One of the challenges in this type of network is the routing problem. The objective of this paper is to propose a routing algorithm in the named data network. Owing to the impressive results presented by the enhanced heuristic methods, tabu search has been selected to develop the proposed algorithm. This work has been carried out in five major steps, Creating the initial solution, The mechanisms of generating a neighborhood, Evaluating the neighbor... 

To synthesize a novel biopolymer-based superabsorbent hydrogel, 2-acrylamido-2-methylpropanesulfonic acid (AMPS) was grafted onto kappa-carrageenan (KC) backbones. The graft copolymerization reaction was carried out in a homogeneous medium and in the presence of ammonium persulfate (APS) as an initiator, N,N,N',N'-tetramethyl ethylenediamine (TMEDA) as an accelerator, and N,N'-methylene bisacrylamide (MBA) as a crosslinker. A proposed mechanism for KC-g-AMPS formation was suggested and the hydrogel structure was confirmed using FTIR spectroscopy. The affecting variables on swelling capacity, i.e., the initiator, the crosslinker, and the monomer concentration, as well as reaction temperature,... 

Let G be a graph. An edge orientation of G is called smooth if the in-degree and the out-degree of every vertex differ by at most one. In this paper, we show that if G is a 2-edge-connected non-bipartite graph with δ(G)≥3, then G has a smooth primitive orientation. Among other results, using the spectral radius of digraphs, we show that if D1 is a primitive regular orientation and D2 is a non-regular orientation of a given graph, then for sufficiently large t, the number of closed walks of length t in D1 is more than the number of closed walks of length t in D2. © 2016 Elsevier Inc  

The singular values of a matrix A are defined as the square roots of the eigenvalues of A⁎A, and the energy of A denoted by E(A) is the sum of its singular values. The energy of a graph G, E(G), is defined as the sum of absolute values of the eigenvalues of its adjacency matrix. In this paper, we prove that if A is a Hermitian matrix with the block form A=(BDD⁎C), then E(A)≥2E(D). Also, we show that if G is a graph and H is a spanning subgraph of G such that E(H) is an edge cut of G, then E(H)≤E(G), i.e., adding any number of edges to each part of a bipartite graph does not decrease its energy. Let G be a connected graph of order n and size m with the adjacency matrix A. It is well-known... 

A novel kappa-carrageenan (C)-based superabsorbing hydrogel was synthesized through graft copolymerization of acrylamide (AAm) onto a C substrate in the presence of a crosslinking agent. The crosslinked C-poly(AAm) polymer graft was partially hydrolyzed in alkaline medium to yield a superabsorbent resin, H-carragPAM. The resin structure was confirmed using FTIR spectroscopy. The variables of graft copolymerization (monomer, initiator, polysaccharide and crosslinker concentration, reaction temperature and time as well as stirrer speed) that affected on the ultimate water-swelling capacity were optimized. The time-temperature variation of the copolymerization was investigated in terms of the... 

A graph is called equimatchable if all of its maximal matchings have the same size. Kawarabayashi, Plummer, and Saito showed that the only connected equimatchable 3-regular graphs are K4 and K3, 3. We extend this result by showing that for an odd positive integer r, if G is a connected equimatchable r-regular graph, then G ϵ {Kr+1, Kr,r}. Also it is proved that for an even r, a connected triangle-free equimatchable r-regular graph is isomorphic to one of the graphs C5, C7, and Kr,r. © 2017 Wiley Periodicals, Inc  

Femtocell has appeared as a solution to increase both the coverage and the capacity of cellular networks. However, interference problem between the macrocell and the femtocell must be solved before any deployment. Since femtocells are deployed by home users in random locations, decentralised interference management schemes remain worth of investigation. In this study, the author deal with the problem of aggregate interference modelling and static resource allocation in orthogonal frequency division multiple access (OFDMA)-based two-tier femtocell networks for both closed and open access femtocells. It is assumed that for macrocell users (MUs), spectrum allocation is accomplished through... 

A novel, polysaccharide-based, superabsorbent hydrogel was synthesized through crosslinking graft copolymerization of methacrylic acid (MAA) onto kappa-carrageenan (κC), using ammonium persulfate (APS) as a free radical initiator in the presence of methylenebisacrylamide (MBA) as a crosslinker. A proposed mechanism for κC-g-polymethacrylic acid (κC-g-PMAA) formation was suggested and the hydrogel structure was confirmed using FTIR spectroscopy. The effect of grafting variables, including MBA, MAA, and APS concentration, was systematically optimized to achieve a hydrogel with the maximum possible swelling capacity. The swelling kinetics in distilled water and various salt solutions were... 

A novel biopolymer-based superabsorbent hydrogel was synthesized through chemically crosslinking graft copolymerization of acrylic acid (AA) onto kappa-carrageenan (κC), in the presence of a crosslinking agent and a free radical initiator. A proposed mechanism for κC-g-polyacrylic acid was suggested and the affecting variables onto graft polymerization (i.e. the crosslinker, the monomer and the initiator concentration, the neutralization percent and reaction temperature) were systematically optimized to achieve a hydrogel with swelling capacity as high as possible. Maximum water absorbency of the optimized final product was found to be 789 g/g. The swelling capacity of the synthesized... 

Different ways have been presented to prevent elastic buckling of steel shear walls. One of these solutions is corrugated shear wall. In this type of wall, shear buckling strength increases without increasing the thickness of the panel. Numerical modeling results indicate that, always, shear buckling strength of corrugated panels is more than the flat panels and with the right choice of the geometric parameters of corrugated panels; without increasing the thickness of the panel, we can improve buckling strength significantly. In the trapezoidal corrugated panels, reducing the width of the subpanels do not always increase buckling strength of the panel, but it changes the panel buckling shape... 

A novel pH-responsive superabsorbing hydrogel based on κ-carrageenan (κC) was prepared through polyacrylamide crosslinking grafting followed by alkaline hydrolysis. The hydrogel structure was confirmed using FT-IR spectroscopy. The hydrolysis conditions were systematically optimized to obtain a hydrogel with maximum swelling capacity. Thus, the reaction variables, including the hydrolysis time and temperature, concentration of sodium hydroxide, amount of hydrogel hydrolyzed and post-neutralization pH, were optimized. The swelling measurements of the hydrogels were conducted in 0.15 M aqueous solutions of LiCl, NaCl, KCl, CaCl2 and AlCl3. As observed for the hydrolyzed hydrogel (H-carragPAM),... 

Let G be a graph. The first and second Zagreb index of G is defined as M1(G)= Σ degG(V)2 and M2(G)= Σ degG(u)degG(V) respectively. In this paper we compute Zagreb indices of chain graphs  

Hexyltriphenylphosphonium bromide (HTPB) is used as an efficient ionic liquid catalyst in the chemoselective addition of malononitrile to carbonyl group moiety of chalcones through the three-component reaction of aryl aldehydes, acetophenone derivatves, and malononitrile to produce (E)-2-(1,3-diarylallylidene)malononitriles at ambient temperature. The method is simple, solvent-free, environmentally friendly, and gives excellent yields in a short reaction times. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim