Sharif Digital Repository

Tehran air quality is facing a real crisis. Reports of pertinent organizations show air quality is deteriorating in recent years and unhealthy days are increasing. As a result, study and planning in order to change this trend and moving toward improving air quality is a necessity. On the other hand, in order to make proper decisions and choosing effective approaches considering cost-effective attribute and legal, temporal and budget restrictions, selecting the right tool is essential. Air quality models are the tools which in a cost saving manner and reasonable time can provide the required results for researchers, decision makers and legislators. An applicable model correspondent with urban... 

Nowadays capacitive deionization (CDI) has attracted a lot of attention for water treatment. CDI is an emerging water treatment technology that uses electrophoretic driving forces for desalination of water. During the CDI process, ions are adsorbed onto the surface of electrodes by applying a low voltage electric field (DC<2V). In addition, the regeneration of the electrodes contains desorption of the electrosorbed ions from the surface of the electrodes to the water in the absence of the applied electric field. In the mechanism of CDI, separation and accumulation of ions in the electric field are the main processes and no additional chemicals are required in this technology. Therein,... 

In this research, carbon nanotubes (CNTs) and CNT coated by titanium dioxide (TiO2) were used as adsorbents for desulfurization. Photocatalytic oxidation by titanium dioxide Degussa P-25 nanoparticles (as photocatalyst) immobilized on a porous and low-density support called “perlite” and CNT/TiO2 was perused. TiO2-coatings were prepared by liquid phase deposition method.This is a wet process for the formation of metal oxide thin films on substrates. The coating of nanotubes with TiO2 was confirmed by IR and EDAX and morphological properties were observed by SEM analysis.The physical properties of adsorbents were determine using BET.Dibenzothiophene (DBT)dissolved in acetonitrile was used as... 

In this study, static recrystallization (Rex) of a low carbon steel after cold rolling has bees simulated under non-isothermal condition by employing cellular automata (CA) method. Symmetric cold rolling and asymmetric cold rolling (ASR) which was arisen by inequality of friction coefficient have been applied as primary cold deformation. Residual stress and strain field after deformation, and temperature rate and distribution of specimens during annealing has been evaluated by employing two different models based on finite element method. Initial microstructure has been developed by haphazardly distribution of grains and topological adjustments were imposed on it. Results of FEM models were... 

Today the water crisis affects billions around the world.According to existance of large amount of salty water on the earth, it seems one of the best soloution is desalination of salty water.There are methods for removing ions from water such as thermal methods, membrane methods , chemical methods and capacitive deionization.Capacitive deionization is based on the deviation of ions in the electric field.CDI system contains of two conductive porous electrodes that an elecric field is applied between them.While the brine pass through the space between the elecrodes the ions are absorbed by elecrodes. After a while the electrodes get saturated so a reverse potential is needed to regenerate the... 

The application of biocatalysts in organic reactions refers to the use of enzymes, purified or crude, to increase the reaction rate. The usage of biocatalysts in organic reactions have many advantages, including biocompatibility, ease of separation, high yield, reusability without losing activity, high selectivity, and the use of water as the solvent. Furthermore, the carbon–carbon bond formation is one of the most important reactions in the synthesis of organic compounds, drugs, and biomolecules. Using enzymes in organic reactions can provide insightful information about the enzymes catalytic activities and paves the way for systematic investigation of their mechanisms. The enzymes... 

Two-dimensional nanostructures can significantly absorb solar irradiation, due to diverse energy levels, large effective surfaces, layered and porous structures with adjustable physical and chemical properties. Mono and multilayers of graphene, as the first isolated 2D materials with special band-structure of a zero-band gap, along with impressive optical properties, tunable light interaction, and adjustable optical properties by chemical doping or structural defects, have great potential for the next generation of nanophotonic devices. So, graphene is an appropriate candidate for absorption, frequent reflection, and energy conversion of electromagnetic waves at the frequency range of the... 

Polymer blending has an important role in preparation of materials with suitable properties without synthesizing new polymers. One of these blends is polypropylene (PP)/ polyethylene (PE). PE is added for improving the impact strength and toughness of PP. For improvementof the properties, a compatibilizer is used due to incompatibility of the PP/PE blend. Improving the impact properties is usually related to the reduction in stiffness. Considering the importance of stiffness in many industrial applications, mineral fillers are employed for increasing the stiffness. In this research, the goal has been to manufacture polypropylene-based ternary composite(Polypropylene/ Polyethylene/Nanometric... 

For the sake of decrease in energy and force of earthquake, seismic isolators are used. Regular seismic isolators are too heavy and damaged by chemical materials, therefore in this research a new approach is used that steel shim plates replaced by carbon and polyamide fibers. The aim of this research is to obtain the dynamic and mechanical properties of carbon and polyamide fiber reinforced isolators in comparison with steel reinforced isolators. In this approach, firstly some specimens have been designed and manufactured, then compresional and cyclic shear tests were carried out on them. All three type isolators are cylindrical and have identical diameter and height. The steel, carbon fiber... 

Core-shell structures of Ag@Pt nanoparticles (NPs) dispersed on Carbon Vulcan XC-72, Multiwalled carbon nanotube and reduced graphene oxide (rGO) support containing different Ag:Pt mass ratios and applied to the oxygen reduction reaction (ORR) in a proton exchange membrane fuel cell (PEMFC) were synthesized by the ultrasonic and reduction treatment method. The morphology of as-prepared catalysts characterized by the high resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD) and induced coupled plasma atomic emission spectroscopy (ICP-OES). The ORR activities and stabilities of catalysts were studied through electrochemical measurements utilizing the Cyclic Voltammetry... 

The aim of this study was to compare the effect of different cooling conditions (dry, flood, mql) on machined surface parameters (smoothness and protrusion of fibers) and tool erosion in carbon fiber reinforced plastic composite materials (CFRP) in the presence of ultrasonic vibrations or without it. Is. Today, carbon fiber reinforced plastic composite materials or CFRP have become one of the most widely used materials in industry due to their strength and light properties. For example, these materials have been used in the manufacture of products from commercial aircraft to shoes, tennis rackets, golf clubs, fishing rods, etc. The combination of carbon fibers woven with resin in alternating... 

According to the literature survey, the thermal decomposition of ammonium uranyl carbonate (AUC) is affected by different factors such as its purity and environmental conditions. Thermal treatment of this compound in the air atmosphere results in the production of at least three oxide forms of uranium (UO3, U3O8 and UO2) with different stoichiometric structure. The aim of this project was to study the effects of those parameters which play role in the decomposition of AUC and the production of UO2 compound in the presence of ammonia atmosphere. Therefore, an atmosphere control furnace was designed and constructed to establish the gas in the atmosphere of furnace chamber. On the other hand,... 

In this project, theoretical and experimental study of methane adsorption on Multiwall Carbon Nano-Tubes (MWCNT) has been performed. This study has been conducted in the way to achieve a suitable method for methane storage and transportation. To carry out the experiments, the volumetric method was used up to 500 psia at various temperatures of 298.15 K, 303.15 K, 308.15 K. The effect of moisture was also studied at 298.15 K. Also, various adsorption isotherms were used to model the experimental data collected in this work. The results showed that the amount of methane adsorbed on the MWCNT can decrease with increasing the moisture and temperature of the adsorption cell. In order to... 

Asphaltenedeposition is a major problem during natural depletion and EOR processes due to formation damage issues. It is necessary to reveal asphaltene deposition mechanisms and its effective parameters to prepare an acceptable prevention strategy. Therefore, different natural depletion and EOR experiments must performed on core samples. In this research, Effect of CO2 injection on asphaltene deposition phenomena has been surveyed. Two carbonate core samples and one sandstone core sample was used in experiments. The oil used in these experiments was recombinedoilfrom one of Iranian offshore oilfield.In order to estimate permeability reduction during experiment, injection of oil and CO2 was... 

Most of the Iranian oil reservoirs are reaching end of their natural production life, hence they are suitable candidates for EOR common processes like gas injection and WAG injection. Studies have shown that gas and WAG injection can be applied for optimal oil production. Past studies have been mainly on gas and WAG injection in immiscible or fully miscible conditions and there is a limited amount of data available on performance of these methods in near miscible conditions. Miscible injection is not feasible in old Iranian oil reservoirs due to their depleted pressure. Moreover injection in lower pressures is attractive from both economical and operational standpoints since this reduces the... 

A simultaneous water and CO2 injection study using sandstone cores with 21°API Sarvak (Azadegan field) oil has performed to evaluate oil recovery under four injection modes: secondary immiscible, secondary near-miscible, tertiary immiscible, and tertiary near-miscible. It is demonstrated that swag injection (secondary and tertiary) is an effective method for the recovery of significant amount of oil or residual oil from water-flooded porous media, but there is always some bypassing (at the pore level) of the oil due to topological effects, water-shielding and dead-end pores. In non-homogeneous porous medium, oil recovery is depending to SWAG ratio in immiscible and near-miscible conditions.... 

By continuous decreasing the fossil fuel energy resources and increasing demand of such energies on the other hand with decreasing exploration of the new ones, production from these limited resources are in grate consideration. As a few percentages of the oil recovers by primary oil production and also remaining a lot of oil after water and gas injection in the secondary oil recovery process, causes that new methods to increase the oil recovery has been proposed. Water injection is a simple and common method in enhanced oil recovery process. Also water alternating gas injection and simultaneous water and gas injection causes considerable increase in oil recovery. Recently utilization of... 

There is increasing evidence that injecting modified brines has a significant impact on the amount of oil recovered, but the exact mechanism by which this occurs is an unsettled issue, and is supposed to be a cause of the complex interactions occurring between the phases insitu. In this thesis, surface chemistry of smart water has been investigated. Fluid/solid and fluid/fluid interactions for Bangestan crude oil in tfhe presence of designed solutions and a set of dilutions of Persian Gulf seawater have been studied and compared. Fluid/solid interactions were investigated through wettability studies. Impact of salinity and ionic composition on this interaction was measured through contact... 

In this research performance of microbial fuel cells (MFCs) in continuous flow mode was studied. Different anodic chambers were tested and it was found that granular activated carbons (GACs) produced the highest power density (1228 mW/m3) in comparison with multiple anodes (731 mW/m3), single anode (294 mW/m3) and polymeric packings (40 mW/m3). It was also shown that in a plug-anodic chamber (PAC) the power output is reduced by reducing agitation of anodic volume. Adding more GACs to anodic chamber results in power increase, however by increasing occupied volume from 80% to 100% the power increase was negligible in result of cathodic reactions limitations. Feed flowrate was increased from... 

Fischer-Tropsch synthesis (FTS) is the main part of a Gas to Liquid (GTL) process. In this reaction which shall be done based upon iron or cobalt catalysts, H2 and CO molecules (namely Syngas) transform to long hydrocarbon chains. Regarding all of the advantages of cobalt catalysts in comparison with iron counterparts, Research Institute of Petroleum Industry (RIPI) began investigations since two decade ago. The present catalyst comprised of cobalt as active metal, ruthenium as activity promiter and lanthanum as support (gamma alumina) modifier. By the way, still some areas such as its lifetime duration and deactivation needs to be improved by complimentary researches. The present...