Loading...
Search for:
coatings
0.017 seconds
Total 688 records
Double layer bioglass-silica coatings on 316L stainless steel by sol-gel method
, Article Ceramics International ; Volume 40, Issue 1, Part A , January 2014 , Pages 993–1000 ; Afshar, A ; Sharif University of Technology
Abstract
The application of bioglass coatings on metallic implants provides link between bone and materials and prevents corrosion of metallic implants in body fluid. Therefore, in this research, 45S5 bioglass-silica coatings on 316L stainless steel were prepared by the sol-gel method and were characterized by different techniques. According to X-ray diffraction (XRD) results, by sintering 45S5 bioglass at 600 C for 5 h, coatings containing both amorphous phase and Na2Ca2Si3O9 crystalline phase were obtained. Scanning electron microscopy (SEM) results showed that coatings prepared via appropriate sol aging and substrate preparations are crack-free. Potentiodynamic polarization tests in simulated body...
Corrosion behaviour of Ni-Co alloy coatings at Kish Island (marine) atmosphere
, Article Bulletin of Materials Science ; Vol. 37, issue. 3 , May , 2014 , p. 713-719 ; Ghorbani, M ; Sharif University of Technology
Abstract
In this study, the corrosion behaviour of Ni-Co alloys with low Co content, electroplated on steel substrate in sulphate bath, was investigated. The morphology of coatings was studied by optical and SEM microscopy. The corrosion products were analyzed using EDX. The results showed that Ni-1%Co coatings had a better corrosion resistance 0.30, 0.92 and 3.75 mpy for atmospheric, salt spray and polarization tests, respectively. These are 0.41, 1.20 and 5.40 mpy for pure nickel coatings that indicate the least corrosion resistance. Surface analysis revealed the presence of oxides, sulphides and chlorides in corrosion products
A highly thermal-resistant electrospun-based polyetherimide nanofibers coating for solid-phase microextraction Microextraction Techniques
, Article Analytical and Bioanalytical Chemistry ; Vol. 406, issue. 8 , March , 2014 , p. 2141-2149 ; Akbarinejad, A ; Aghakhani, A ; Sharif University of Technology
Abstract
A high-temperature-resisant solid-phase microextraction (SPME) fiber was prepared based on polyetherimide (PEI) by the electrospinning method. The PEI polymeric solution was converted to nanofibers using high voltages and directly coated on a stainless steel SPME needle. The scanning electron microscopy images of PEI coating showed fibers with diameter range of 500-650 nm with a homogeneous and smooth surface morphology. The SPME nanofibers coating was optimized for PEI percentage, electrospinning voltage, and time. The extraction efficiency of the coating was investigated for headspace SPME of some environmentally important polycyclic aromatic hydrocarbons from aqueous samples followed by...
Titania nanostructured coating for corrosion mitigation of stainless steel
, Article Protection of Metals and Physical Chemistry of Surfaces ; Vol. 50, issue. 3 , 2014 , p. 371-377 ; Sani, M. A. F ; Sadeghian, Z ; Ghasemi, H ; Sharif University of Technology
Abstract
Anatase nanostructured coating has been prepared on 316 L stainless steel by sol-gel dip coating. The topography of the coatings surface has been analyzed using atomic force microscopy. The anticorrosion performance of the coatings has been evaluated using polarization curves. Effects of calcination temperature, withdrawal speed and times of coating on corrosion protection have been studied. The results showed calcination temperature of 400°C and withdrawal speed of 10 cm/min are desirable conditions to achieve high corrosion protection of 316 L stainless steel in chloride containing environments. Coatings with 3 times exhibit better resistance against corrosion in 0.5 molar NaCl solutions....
The electro-elastic scattered fields of an SH-wave by an eccentric two-phase circular piezoelectric sensor in an unbounded piezoelectric medium
, Article Mechanics of Materials ; Vol. 75 , 2014 , pp. 1-12 ; ISSN: 01676636 ; Jarfi, H ; Rashidinejad, E ; Sharif University of Technology
Abstract
The dynamic equivalent inclusion method (DEIM) which was first proposed by Fu and Mura (1983), in its original context has some shortcomings, which were pointed out and remedied by Shodja and Delfani (2009) who introduced the new consistency conditions along with the related micromechanically substantiated notion of eigenstress and eigenbody-force fields. However, these theories are bound to elastic media with isotropic phases. The present work extends the idea of the above-mentioned new DEIM to the dynamic electro-mechanical equivalent inclusion method (DEMEIM) for the treatment of the scattering of SH-waves by a two-phase circular piezoelectric obstacle bonded to a third phase...
Physically based wall boundary condition for dissipative particle dynamics
, Article Microfluidics and Nanofluidics ; Vol. 17, issue. 1 , July , 2014 , p. 181-198 ; Saidi, M. S ; Sharif University of Technology
Abstract
In this paper, we present a novel wall boundary condition model, which stands just on the physical facts, for the dissipative particle dynamics (DPD) method. After the validation of this model by means of the common benchmarks such as the Couette and the Poiseuille flows, we study the effects of this model on the diffusion coefficient in a wide variety of different coarse-graining levels. The obtained results show that the proposed model preserves the thermodynamics of the system, also eliminates the spurious effects of the wall, and consequently is able to preserve the accurate structural characteristics of the working DPD fluid in the wall's vicinity. We also study the fluid flow through a...
Towards greater mechanical, thermal and chemical stability in solid-phase microextraction
, Article TrAC - Trends in Analytical Chemistry ; Volume 34 , 2012 , Pages 126-138 ; 01659936 (ISSN) ; Piri-Moghadam, H ; Naderi, M ; Sharif University of Technology
Abstract
Solid-phase microextraction (SPME) is a fast, solvent-free technique, which, since its introduction in the 1990s, has been increasingly applied to sample preparation in analytical chemistry. Conventional SPME fibers are fabricated by making a physical bond between the usual silica substrate and the polymeric coatings. However, some applications are limited, as the lifetime and the stability of conventional SPME fibers cannot meet the demands of analyzing relatively non-volatile compounds with more polar moieties. There have been attempts to analyze less volatile compounds by increasing the thermal, physical and chemical stability of the fibers. In this review, we present some new...
Physical properties of sputtered amorphous carbon coating
, Article Journal of Alloys and Compounds ; Volume 513 , 2012 , Pages 135-138 ; 09258388 (ISSN) ; Larijani, M. M ; Afshar, A ; Eshghabadi, M ; Shokouhy, A ; Sharif University of Technology
Abstract
In this study the effect of deposition temperature and thickness on the physical properties of carbon films deposited by magnetron sputtering PVD was investigated. The results of Raman spectra and grazing incidence XRD (GIXRD) patterns show that the graphitization increases by increasing the deposition temperature. There is a change in deposition mechanism at 400 °C from amorphous carbon deposition to nano-structured graphite deposition. Also by increasing substrate temperature the electrical resistance of carbon films reduces significantly up to 300 °C and then remains largely constant. High intrinsic compressive stress in low temperature deposited carbon films causes cracks and...
Photocatalytic activity of TiO 2-capped ZnO nanoparticles
, Article Journal of Materials Science: Materials in Electronics ; Volume 23, Issue 2 , 2012 , Pages 361-369 ; 09574522 (ISSN) ; Simchi, A ; Nemati, Z. A ; Sharif University of Technology
Abstract
Using a combined hydrothermal and sol-gel route, TiO 2 -capped ZnO nanoparticles with an average size of 60 nm were prepared. The titania shell was amorphous with a thickness of ∼10 nm. Formation of Zn 2TiO 4 phase at higher calcination temperature was noticed. Effects of Ti/Zn molar ratio and coating time on the thickness of TiO 2 shell and the photoactivity of the particles for decolorization of Methylene Blue (MB) under UV lamp irradiation (3 mW/cm 2) were investigated. The nanoparticles were characterized by X-ray diffraction, transmission electron microscopy, fourier-transform infrared spectrometry (FTIR), diffuse reflectance spectroscopy (DLS), and atomic absorption spectroscopy....
Novel unbreakable solid-phase microextraction fiber by electrodeposition of silica sol-gel on gold
, Article Journal of Separation Science ; Volume 34, Issue 22 , 2011 , Pages 3246-3252 ; 16159306 (ISSN) ; Sistani, H ; Ayazi, Z ; Sharif University of Technology
Abstract
A new technique for preparation of an unbreakable solid-phase microextraction (SPME) fiber, using sol-gel technology is developed. Primarily, an ultrathin two-dimensional intermediate film was prepared by hydrolysis of 3-(trimethoxysilyl)-1-propanthiol self-assembled monolayer grafted onto gold, then a stationary phase by electrodeposition of 3-(trimethoxysilyl) propylmethacrylate as a precursor, tetramethyl orthosilicate and polyethylene glycol as a coating polymer was produced. The scanning electron microscopy images revealed that the new fiber exhibits a rather porous and homogenous surface. The thermal stability of the fabricated fiber was investigated by thermogravimetric analysis. The...
A polypyrrole-based sorptive microextraction coating for preconcentration of malathion from aquatic media
, Article Chromatographia ; Volume 74, Issue 9-10 , 2011 , Pages 731-735 ; 00095893 (ISSN) ; Aghakhani, A ; Ayazi, Z ; Khakinezhad, M ; Sharif University of Technology
Abstract
A new micro-solid phase extraction method was developed by combining solid-phase extraction and stir bar sorptive extraction to benefit from the advantages of both techniques. A polypyrrole coating was electrochemically synthesized on the surface of an already used graphite furnace, employed in electro-thermal atomic absorption spectroscopy. The cylindrical geometry of the graphite tube provided a rather huge surface area, suitable for sorptive extraction. The novel sorbent coating was examined as an extracting medium to isolate malathion. Effects of different parameters such as extraction time, salt concentration, sample volume, desorption solvent and time were investigated and optimized....
Electrodeposition of Ni/WC nano composite in sulfate solution
, Article Materials Chemistry and Physics ; Volume 129, Issue 3 , 2011 , Pages 746-750 ; 02540584 (ISSN) ; Dolati, A ; Rezagholibeiki, S ; Sharif University of Technology
Abstract
Metal matrix composite coatings have gained great attention due to their exclusive properties. They have shown the properties of a metallic host material modified by addition of a second phase. In electrodeposition of Ni/WC nano composite, nickel was deposited on the substrates by DC electrodeposition in Watt's based bath containing nickel sulfate, nickel chloride, boric acid and sodium dodecyl sulfate. WC content in the coating was determined by different parameters such as current density, powder content and surfactant amount. Mechanism of electrodeposition was analyzed by cyclic voltammetry and was confirmed by Guglielmi model. Surface morphology was studied by scanning electron...
Overall electroelastic moduli of particulate piezocomposites with non-dilute BCC microstructure
, Article International Journal of Mechanical Sciences ; Volume 53, Issue 9 , 2011 , Pages 777-785 ; 00207403 (ISSN) ; Kargarnovin, M. H ; Sharif University of Technology
Abstract
The present paper addresses an analytical method to determine the overall behavior of piezocomposite materials containing body centered cubic (BCC) distribution of arbitrary oriented ellipsoidal heterogeneities. This approach is based on the extension of the electromechanical equivalent inclusion method (EMEIM) to interacting multi-inhomogeneities. In this treatment the short and long range interactions of the piezoelectric particles are appropriately incorporated through the homogenizing eigenstrainelectric field. The periodicity of the microstructure of the medium suggests representing the eigenfields in terms of Fourier series, accounting for the matrixparticle, interparticle and...
Nitrate reduction by nano-Fe/Cu particles in packed column
, Article Desalination ; Volume 276, Issue 1-3 , 2011 , Pages 214-221 ; 00119164 (ISSN) ; Ataie Ashtiani, B ; Kholghi, M ; Sharif University of Technology
Abstract
In this work the application of a modified surface nano zero valent iron (NZVI) as bimetallic Fe/Cu particles to remove high concentration of NO3--N through packed sand column has been studied. Dispersed nano-Fe/Cu particles has been synthesized in water mixed ethanol solvent system (1:4v/v) and described by XRD pattern, TEM and SEM images and BET analyze. Batch experiments have been conducted to investigate the effect of percentage coating of Fe0 by Cu on the nitrate removal. Research on packed sand column (120cm length, 6.5cm inner diameter) has been done under conditions of Nano-Fe/Cu concentration (2, 5, and 8gl-1 of solution), high initial NO3--N concentration (100, 200, and 300mgl-1)...
Pore-Scale Monitoring of Wettability Alteration by Silica Nanoparticles During Polymer Flooding to Heavy Oil in a Five-Spot Glass Micromodel
, Article Transport in Porous Media ; Volume 87, Issue 3 , 2011 , Pages 653-664 ; 01693913 (ISSN) ; Mohebbi, A ; Kharrat, R ; Ghazanfari, M. H ; Sharif University of Technology
Abstract
It is well known that the oil recovery is affected by wettability of porous medium; however, the role of nanoparticles on wettability alteration of medium surfaces has remained a topic of debate in the literature. Furthermore, there is a little information of the way dispersed silica nanoparticles affect the oil recovery efficiency during polymer flooding, especially, when heavy oil is used. In this study, a series of injection experiments were performed in a five-spot glass micromodel after saturation with the heavy oil. Polyacrylamide solution and dispersed silica nanoparticles in polyacrylamide (DSNP) solution were used as injected fluids. The oil recovery as well as fluid distribution in...
Recent progress in inorganic and composite coatings with bactericidal capability for orthopaedic applications
, Article Nanomedicine: Nanotechnology, Biology, and Medicine ; Volume 7, Issue 1 , Feb , 2011 , Pages 22-39 ; 15499634 (ISSN) ; Tamjid, E ; Pishbin, F ; Boccaccini, A. R ; Sharif University of Technology
Abstract
This review covers the most recent developments of inorganic and organic-inorganic composite coatings for orthopedic implants, providing the interface with living tissue and with potential for drug delivery to combat infections. Conventional systemic delivery of drugs is an inefficient procedure that may cause toxicity and may require a patient's hospitalization for monitoring. Local delivery of antibiotics and other bioactive molecules maximizes their effect where they are required, reduces potential systemic toxicity and increases timeliness and cost efficiency. In addition, local delivery has broad applications in combating infection-related diseases. Polymeric coatings may present some...
Treatment of welding electrode manufacturing plant wastewater using coagulation/flocculationnanofiltration as a hybrid process
, Article Brazilian Journal of Chemical Engineering ; Volume 28, Issue 1 , Mar , 2011 , Pages 73-79 ; 01046632 (ISSN) ; Mousavi, M ; Borghei, M ; Sharif University of Technology
Abstract
High water consumption and water scarcity make industrial wastewater reuse necessary, especially in those industries characterized by polluted effluents such as welding electrode manufacturing industries. The present paper investigates the coupling of coagulation-flocculation with nanofiltration (NF) to recycle water and reuse it in the process. First, the effect of different concentrations of a mixture of alum (Al2(SO4) 3.18H2O) and ferric chloride (FeCl3) on the pretreatment process was closely studied. Then the NF process was applied for complementary treatment. The NF results show that, by increasing both flow rate and transmembrane pressure (TMP), permeate flux is increased. The NF...
Fabrication of aluminum nitride coatings by electrophoretic deposition: Effect of particle size on deposition and drying behavior
, Article Ceramics International ; Volume 37, Issue 1 , 2011 , Pages 313-319 ; 02728842 (ISSN) ; Zarabian, M ; Alizadeh, P ; Sadrnezhaad, S. K ; Sharif University of Technology
Abstract
Electrophoretic technique was used to deposit micro- and nano-sized aluminum nitride coatings on stainless steel surfaces by using a well-dispersed stable suspension produced by addition of AlN powder plus a small amount of iodine to ethanol. Parabolic regime governed the deposition. Electrophoretic deposition for 240 s at 100 V resulted in formation of a uniformly dense film on the top, but a porous inhomogeneous layer at the bottom. This was attributed to fast deposition of coarse particles and/or agglomerates at large electric fields. After drying, micro-sized particles led to a uniform crack-free interface while nano-particles resulted in fragmented non-cohesive layers. Weight loss...
Leaching of a zinc ore and concentrate using the Geocoat™ technology
, Article Minerals Engineering ; Volume 24, Issue 1 , 2011 , Pages 64-69 ; 08926875 (ISSN) ; Petersen, J ; Roostaazad, R ; Hosseini, S ; Mohammad Mousavi, S ; Najafi, A ; Vasiri, A. K ; Sharif University of Technology
Abstract
In this study, the Geocoat™ technology was used for the extraction of zinc from a mineral concentrate obtained from the Kooshk mine (Yazd, Iran) by a culture dominated by the mesophilic bacterium Acidithiobacillus ferrooxidans in a packed column bioreactor. A low grade sphalerite ore was used as support for the concentrate coating. During the 100 days of leaching pH, Fe3+, Fetotal, microbial population density and zinc extraction were measured. The final zinc extraction from concentrate and low grade support was 97% and 78%, respectively, and it was found that leaching from the support does not proceed significantly before leaching from the coating is completed
Al2O3/Si3N4 nanocomposite coating on aluminum alloy by the anodizing route: Fabrication, characterization, mechanical properties and electrochemical behavior
, Article Ceramics International ; 2016 ; 02728842 (ISSN) ; Afshar, A ; Ahmadi, S ; Sharif University of Technology
Abstract
An Al2O3/Si3N4 nanocomposite coating was successfully fabricated on commercial aluminum alloy. Hardness measurements, polarization and electrochemical impedance spectroscopy (EIS) were employed to study the mechanical and corrosion behaviors of the coatings. Field-Emission Scanning Electron Microscopy (FE-SEM) equipped with Energy Dispersive Spectroscopy (EDS) and X-ray diffraction (XRD) were utilized to characterize the surface morphology and phase composition of the coatings. Also, coatings abrasive wear properties were evaluated with a modified ASTM G105 standard. FE-SEM image, EDS and XRD analysis revealed the presence of Si3N4 in the coating. Furthermore, the results showed hardness of...