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Investigating Effect of Nano Ceramic Coating of Combustion Chamber on the Performance of Internal Combustion Engines
,
M.Sc. Thesis
Sharif University of Technology
;
Naghdabadi, Reza
(Supervisor)
Abstract
Thermal barrier coatings (TBCs) are used for increasing the efficiency and reducing pollutants of internal combustion engines (ICEs). In this paper, an optimization framework is developed in order to obtain the optimal dimensions for conventional coat, and the optimal dimensions and material property for functionally graded (FG) coat of a partially coated piston. A thermo mechanical analysis is investigated for Nano coat by finite element method. The conventional and Nano coats are made of MgZrO_3 as the insulating ceramic overlay and NiCrAl as the metallic bond-coat. The properties of the FG coat is assumed to vary according to power law through the thickness. For all tree conventional, FG...
Investigation and Fabrication of Cr2O3 Thin Film Coating on Soda Lime and Low Carbon Steel Substrate
, M.Sc. Thesis Sharif University of Technology ; Dolati, Abolghasem (Supervisor)
Abstract
Chromium oxide coatings (Cr2O3) have been widely used due to their remarkable properties in corrosion, wear, optical and mechanical applications. So far, several methods have been used to prepare Cr2O3 thin films. In this study, the chromium oxide was produced by the sol-gel method and dip coated on the low carbon steel and glass substrates. In this context, we encountered with the problem of incoherency of the Cr2O3 ceramic coating to the steel substrates. It is highly likely that this problem be due to causes such as: a) thermal stresses due to the difference between the thermal expansion coefficients of the substrate and the coating, b) incoherent substrate/coating interface due to their...
A Study on Properties of Composite Coating with Al2O3 Base Prepared by Hard Anodizing with ZrO2 Nanoparticles
, M.Sc. Thesis Sharif University of Technology ; Afshar, Abdollah (Supervisor)
Abstract
In this study anodized none composite and composite film containing ZrO2 nanoparticles were prepared on 1050 Al Alloy using hard anodizing method in sulfuric and oxalic acid mixed solution by pulse Currents. The microstructure and properties of the film were studied by field emission scanning electron microscopy with EDS analyzer and XRD diffraction and friction wear test were performed to evaluate the mechanical properties of coating . Results indicate that the composite film with ZrO2 nanoparticles have reduced friction coefficient with high micro hardness friction coefficient of composite film can be small as 0.16 which is much smaller than that 0.39 of none composite film. Micro hardness...
Study of TLP Bonding of Al/SiC Composite Using Coated Interlayer
, M.Sc. Thesis Sharif University of Technology ; Ekrami, Ali Akbar (Supervisor) ; Seyyed Reihani, Morteza (Supervisor)
Abstract
TLP diffusion bonding method refers to a method in which two metal pieces can be bonded by putting an interlayer between two pieces and heating to a temperature lower than base metal melting point. Theoretically, this process shows that the bonding line disappears completely at the end of the process and it is not possible to recognize it. However, these assumptions were not accomplished in practice. Therefore, various parameters such as material of interlayer, thickness of interlayer, temperature and time of bonding, temperature and time of homogenizing and applied pressure on metal pieces should be controlled to achieve the best shearing strength results. Aluminum based composites have...
Synthesis and Electrochemical Evaluation of Graphene-Ni/Cu/Zn Nanocomposite Coating Modified by Pt/Ru Nanoparticles
, Ph.D. Dissertation Sharif University of Technology ; Afshar, Abdollah (Supervisor)
Abstract
In this research,Graphene Oxide nanoplatelets (GO) were synthesized by chemically modified Hummer's method.After the GO nanosheets electrochemically reduced to graphene, nanoparticles imposed to this thin film.This optimized nanostructure coating was utilized for investigating the Hydrogen Evolution Reaction (HER) over the copper substrate. In order to optimize the kinetic of electrodeposition and reduction, diverse electrochemical approaches such as cyclic voltammetry, chronoamperometic and potentiometric as well as pulse electrodeposition methods were employed. Electrochemical procedures were aligned by Design of Experiment (DOE) ...
Formation and Investigation of Zinc-Nickel Two Cathionic Electrophospahte Coating Properties on Galvanized Steel
, M.Sc. Thesis Sharif University of Technology ; Afshar, Abdollah (Supervisor)
Abstract
By using electrophoaphating treatment in the metal coating process, the operating temperature of chemical phosphating bath is decrease and also difficulties with the use of high temperature bath is eliminated. The aim of this study is investigate the effect of operating parameter on coating properties and also investigation the deposition mechanism of Zn-Ni electrophosphate coating. Coating properties such as morphology, corrosion resistance and porosity of the coating characterized using SEM, polarization test and electrochemical method respectively. The values used for pH effect was 1.6,1.8,2 and 2.2 results indicated that by increasing the pH value from 1.6 to 1.8 the icorr decrease from...
, M.Sc. Thesis Sharif University of Technology ; Ghorbani, Mohammad (Supervisor)
Abstract
Phosphating is one of the most procedures as a final surface treatment or pre-treatment (lubrication and Infrastructure color) is done on ferrous and nonferrous alloys. Phosphate coating on the wire drawing, increase speed of drwing, increase die life, increased resistance to abrasion caused by the friction reduction, reduced maintenance costs and improved surface appearance are combustible and conditions. The aim of this study was to evaluate the effects of variables such as temperature, pH bath, the coating bath components concentration on coating properties and optimize calcium zinc phosphate coating on steel wire, for better lubrication and decrease friction in the wire drawing process....
Electroplating of Bronze-Graphite-SiC Composite Coating
, M.Sc. Thesis Sharif University of Technology ; Ghorbani, Mohammad (Supervisor)
Abstract
Composite coatings including self-lubricant particles such as graphite, MoS2, Al2O3 and SiC are extensively used to decrease the coefficient of friction of tribo-surfaces. Adding lubricant particles to an appropriate metallic matrix like copper, nickel, lead and their alloys is a suitable option in severe condition –for instance high temperature and low pressure- which liquid lubricants will be failed. Bronze can give various properties such as wear resistance, corrosion and oxidation protection, However cyanide solutions for electroplating process have environmentally limited for plating of Cu-Sn. In this research, a chloride electrolyte for bronze electroplating was developed and effect of...
Cobalt Based Spinel Coating on Stainless Steel by Sol-Gel Dip Coating Technique for Interconnects
, M.Sc. Thesis Sharif University of Technology ; Faghihi Sani, Mohammad Ali (Supervisor)
Abstract
Because of the high operating temperature, interconnect surface tends to be oxidized and Cr2O3 oxide layer will be created on the surface. This phenomenon is undesirable due to decreasing electrical conductivity, so a preservative coating is needed to improve the interconnect properties. In this paper, a dense spinel thin film was successfully synthesized on a ferritic stainless steel (type 430) substrate by a sol-gel dip coating method. This coating improved chemical stability, oxidation behavior of the substrate and decreased cathode poisoning. The Nickel-Cobalt spinel was coated on the substrate by sol-gel coating process. First, during a hydrolyze process, a stable sol was made up from...
Preparation and Characterization of ZrO2 Antistatic Coatings on Glass
, M.Sc. Thesis Sharif University of Technology ; Dolati, Abolghasem (Supervisor) ; Afshar, Abdollah (Supervisor)
Abstract
In this study, the zirconia antistatic coating was synthesized by dip coating sol-gel route on glass substrate. The solution contains ZrCl4 as precursor and isopropanol as solvent to synthesize zirconium oxide. The effects of environmental humidity and solution concentration on the coating characterization were analyzed. MPTS and primer binder were added as binding agents in the solution to observe the effect of binding agents on the coating adhesion. Solution stability and antistatic coating characterization were analyzed by zita potential test, FTIR spectroscopy, EDX analysis, FESEM and AFM microscopy, pencil hardness test, thickness test, antidust ability and spectrophotometer. The...
Corrosion Resistance of Graphene-Titania Coating on 316 Stainless Steel by Electrophoretic Deposition
, M.Sc. Thesis Sharif University of Technology ; Afshar, Abdollah (Supervisor)
Abstract
The aim of this thesis was creating Titania/RGO coating with electrophoretic method to evaluate the corrosion resistance of stainless steel 316. At first Graphene Oxide were synthesized with modified Hammers method and their physical, chemical and morphological properties have been investigated using XRD, FTIR, EDX, TGA, UV-Vis and Raman analysis. then Graphene Oxide was added to the bath of titanium and was deposited on 316 stainless steel substrates. Moreover, corrosion protection of coating has been examined using Poarization test and Electrochemical Impedance Spectrometry. The effect of deposition parameters on corrosion properties of composite coatings were examined. The key variables...
Investigation on Photocatalytic and Corrosion Properties of Titania-Graphene Nanocomposite Coated by Electrophoretic Method
, M.Sc. Thesis Sharif University of Technology ; Nemati, Ali (Supervisor) ; Sadeghian, Zahra (Supervisor)
Abstract
The main purpose of this research was functionalizing graphene, in order to achieve higher hydrophobicity, and producing nanocomposite of functionalized graphene and titanium dioxide by hydrothermal method, and sequently invastigation on photocatalytic properties of the powders and corrosion properties of EPD coated samples. Graphene oxide was synthesized by improved Hummers method and reduced and sequently was functionalized through the chemical process with hydrazine and octadecylamine respectively. Then the nanocomposite of functionalized graphene-titania was synthesized by use of titanium isopropoxide precursor and its photocatalytic properties were measured. The analysis of the...
Formation & Properties of Zn–Ca– Mn Tri – Cation’s Phosphate Coating on St37 Steels
, M.Sc. Thesis Sharif University of Technology ; Afshar, Abdollah (Supervisor) ; Ghorbani, Mohammad (Supervisor)
Abstract
Addition of heavy metal cations such as manganese and nickel in low zinc phosphating bath increases the corrosion resistance of coatings and provides more suitable substrates for painting (especially electrophoretic painting). In addition, due to accelerating property and low cost availability of heavy metal cations such as Mn, multi– cationic phosphating is cost effective. In the present study, chemical composition and operating parameters of zinc - calcium - manganese Tri- cationic phosphating solution were optimized. Then the effects of various parameters such as phosphating time, bath temperature and pH on properties of coating were investigated. According to the results, about 1 g/L was...
The Comparison Between TiN and Hard Chromium Coatings
, M.Sc. Thesis Sharif University of Technology ; Dolati, Abolghasem (Supervisor)
Abstract
This research focuses on finding an appropriate method for increasing wear and corrosion resistance of hard coating TiN PVD and chromium. The substrate was made up of 42CrMo4 (DIN) steel (used for marine industries) and coated by TiN Arc PVD process and hard chromium electro-deposition. The results of these two coatings are compared and the better coating which is TiN Arc PVD is suggested. To find the best method for coating, several test studies are organized such as: the mechanical and tribological properties of TiN PVD and hard chromium coatings for wear and corrosion resistance applications are organized. The potentiodynamic polarization technique was used to measure the corrosion rate...
The Corrosion Behavior of Zinc and SiO2 Composite Coating
, M.Sc. Thesis Sharif University of Technology ; Ghorbani, Mohammad (Supervisor)
Abstract
Main aim of this work was to obtain the harder zinc coating and increasing the anti corrosive properties by mean of adding SiO2 particles by electrophoretic method.
The coating was applied on the substrate surface by mean of electro co-deposition technique in three different electrolytes ethanol, methanol and water. The morphology of the coating in each electrolyte studied by scanning electron microscope (SEM).For the Zn/SiO2 coatings achieved in ethanol solvent the polarization and EIS tests was took place and found that for the Zn/SiO2 coating contain less than 10% SiO2 the corrosion rate decreased but for the coatings contains more than 10% SiO2 the paradox occurred because of the...
The coating was applied on the substrate surface by mean of electro co-deposition technique in three different electrolytes ethanol, methanol and water. The morphology of the coating in each electrolyte studied by scanning electron microscope (SEM).For the Zn/SiO2 coatings achieved in ethanol solvent the polarization and EIS tests was took place and found that for the Zn/SiO2 coating contain less than 10% SiO2 the corrosion rate decreased but for the coatings contains more than 10% SiO2 the paradox occurred because of the...
Improvement of Corrosion Resistance of Concrete Sewer Pipes Against Microbial Corrosion
, M.Sc. Thesis Sharif University of Technology ; Afshar, Abdollah (Supervisor)
Abstract
Microbiologically Influenced Corrosion (MIC) of concrete sewer ptpes and wastewater collection systems has been reported in many places of the world. Recently, numerous copper compounds have been used for bacterial growth control in sewer pipes. In this thesis, bath parameterswere optimized in order to maximize copper osmosis to the porous concrete matrix.Concrete pipes were electrochemically coated inCopper Lactate bath in a constant current mode (1=0.6 A), while temperature was set to 25, 50, 75 and 95
°Cand pH to 9,10 and 11. Specimens were then characterized by scanning electron
microscopy, optical microscopy, XRD andAAS. Copper Osmosis was highest in pH=9 and...
°Cand pH to 9,10 and 11. Specimens were then characterized by scanning electron
microscopy, optical microscopy, XRD andAAS. Copper Osmosis was highest in pH=9 and...
Tribological and Corrosion Properties of Ni-SiC (FGM) Coatings
, M.Sc. Thesis Sharif University of Technology ; Ghorbani, Mohammad (Supervisor)
Abstract
Ni-SiC nanocomposite coatings are considered as corrosion resistant coatings with better tribological properties. In order to get superior properties, the amount of added particles should be increased. But high concentration of particles has some drawbacks such as low adhesion to substrate, probability of cracking in coating due to heat expansion coefficient difference between substrate and coating and also embrittlement of coating and low elasticity. In this study, the possibility of producing Ni-SiC nanocomposite coatings with FGM structure was investigated. SiC particles concentration was 5 to 80 g/l and the current density was between 3 to 5 A/dm¬2. The pH of bath and temperature was...
Study of the Effect of Electroplated Nanocrystalline Nickel Grain Size on Corrosion Resistance
, M.Sc. Thesis Sharif University of Technology ; Baghalha, Morteza (Supervisor) ; Kazemeini, Mohammad (Supervisor)
Abstract
In this project, nonocrystalline nickel coatings with grain sizes within the range of 9-27 nanometers were produced on yellow-brass plates by electroplating in a modified Watts bath applying current densities from 2 to 6 A/dm2 and bath stirring speeds from 0 to 400 rpm. To determine crystallite size, X-ray diffraction technique (XRD) was utilized; it was observed that grain size declined continuously with increase in current density and then in bath stirring speed. The experimental results coming from XRD tests were compared with a theoretical model in order to verify their reliability; the obtained curve indicated a good correspondence between the experimental data and the theoretical...
Enhanced Photocatalytic Activity of Nano-scaled TiO2 Co-doped with N and Ag by Sol-gel Method
, M.Sc. Thesis Sharif University of Technology ; Dolati, Abolghasem (Supervisor)
Abstract
Transparent coatings with self-cleaning property in visible light spectrum, UV radiation resistance and antimicrobial are highly desirable. Titanium dioxide (TiO2) is used in this research has been widely studied as an efficient photocatalyst by researchers. In this research enhanced visible-light photocatalytic activity is gained with N and Ag co-doped titania. All samples were annealed at 450℃. Finally AgI was loaded TiO2 coating and the results were investigated. Peaks of XRD pattern wereattributed to different diffraction planes of anatase TiO2. Morphology of coatings were analyzed with using FE-SEM. Nano granis size of TiO2 and AgI loaded TiO2 were observed in FE-SEMimages. Nitrogen...
Hydroxyapaptite Coating on Zirconia Toughened Alumina Nanocomposite by Biomimetic Method
, M.Sc. Thesis Sharif University of Technology ; Nemati, Ali (Supervisor) ; Salahi, Esmaeil (Co-Advisor)
Abstract
Zirconia toughened alumina (ZTA) Nanocomposites were prepared using nano sized Zirconia (ZrO2) powders doped with 3% mol of yttria (Y2O3) nanopowders and the sintering behavior at different temperature (1450 °C, 1550 °C and 1650 °C) were studied. The ZTA composite with different amount of partially stabilized Zirconia (PSZ)(5, 10, 15 and 20% mol) were prepared via axial pressing and then sintered to achieve maximum densification. After that phase changes of the samples were monitored. SEM was used for microstructural study and hardness and fracture toughness were determined by means of Vickers indentation. X-ray diffraction pattern showed that at constant composition, tetragonal zirconia...