Sharif Digital Repository

27Al NMR spectroscopy is a powerful tool for the study of coordination and solvation in both aqueous and nonaqueous solutions. In this study, the complexes coexisting upon dissolution of AlCl3 in acidic acetone + methanol solutions are shown to consist essentially of mixed hexacoordinated species of the general formula [Al(CH3OH) 6-n (CH3COCH3) n ]3+ (n=1,2 and 3), all exhibiting distinctly different 27Al shielding effects. The relative populations of the various mixed species are found to be highly dependent upon the acetone:methanol mole ratio that in the more acetone-rich mixtures with aluminum become appreciably coordinated by acetone. The results demonstrate that the key factor for the... 

In peer-to-peer (P2P) overlay networks, the mechanism of a peer randomly joining and leaving a network, causes a topology mismatch between the overlay and the underlying physical topology. This causes a large volume of redundant traffic in the underlying physical network as well as an extra delay in message delivery in the overlay network. Topology mismatch occurs because overlay networks are not aware of their underlying physical networks. In this paper we present a mathematical model for topology awareness of overlay networks (degree of matching between an overlay and its underlying physical network) and the efficiency of message delivery on them. We also after determining the... 

Conventional implementation of multi-dimensional wavelet transform (e.g. 3-D wavelet) requires whether a high amount of "in access" memory or a continual access to slow memory of a processor which makes it infeasible for most applications. In this paper, we proposed a novel algorithm for computation of an n-D discrete wavelet transform (DWT) based on lifting scheme. In addition to benefits of lifting scheme (which causes a major reduction in computational complexity and performs the total computations in time domain), our real-time approach computes the coefficients for all kinds of 1st and 2 nd generation wavelets with short delay and optimized utilization of the slow and fast memories of a... 

Operational modal analysis techniques classically have been developed based on the assumption that the input to the system is a stationary white noise. While, in many practical cases, the systems are excited by combination of white noise and colored noises (harmonic excitations). Consequently, in conditions where non-white noises are present, the existing OMA methods cannot completely distinguish between the system poles and the induced poles due to colored noises. In order to overcome this weakness of OMA methods, some researches have been conducted in the field. In this paper, a new method is proposed for identifying the modal parameters of the system under the unknown colored noises,... 

A comparative investigation has been developed for the stability constants of several amino acid complexes with divalent metal ions, which have been determined by potentiometric pH titration. Depending on the metal ion-binding properties, vital differences in the building complexes were observed. The present study indicates that in some M(L) complexes, metal ions are arranged in carboxyl groups, but in other M(L)complexes, some metal ions are able to build chelate over amine groups. The results mentioned-above demonstrate that for some M(L) complexes, the stability constants are also largely determined by the affinity of metal ions for amine group. This leads to a kind of selectivity of... 

The current literature lacks the VLSI realization of hig-horder multiple-input-multiple-output (MIMO) detectors in the complex domain, which finds applications in advanced wireless standards such as WiMAX and Long Term Evolution (LTE) systems. In this paper, a novel modified complex K-Best algorithm and its VLSI implementation for a 4 ×4, 64QAM complex MIMO detector are proposed. The main contributions of this paper are the modified hard-output complex K-Best algorithm as well as its efficient architecture, which is well-suited for a pipelined VLSI implementation. By using an efficient fast multiplier and applying both fine-grain pipelining and coarse-grain pipelining to the architecture of... 

OFDM is an effective multicarrier transmission technique with one primary disadvantage; it suffers from high Peak-to-Average Power Ratio (PAPR). Although clipping and filtering is a simple and effective method for PAPR reduction, it makes in-band and out-of-band noise, which degrades the bit error rate performance and spectral efficiency. Publications on this subject show that clipped samples could be reconstructed at the receiver by using oversampled signal and bandwidth expansion. By building on published literature, this paper aims to achieve a low-complexity method. The proposed method has complexity order of O(L2) to solve linear system, where L indicates the number of clipped samples.... 

A multi-stage secret sharing (MSS) scheme is a method of sharing a number of secrets among a set of participants, such that any authorized subset of participants could recover one secret in every stage. The first MSS scheme was proposed by He and Dawson in 1994, based on Shamir's well-known secret sharing scheme and one-way functions. Several other schemes based on different methods have been proposed since then. In this paper, the authors propose an MSS scheme using All-Or-Nothing Transform (AONT) approach. An AONT is an invertible map with the property that having "almost all" bits of its output, one could not obtain any information about the input. This characteristic is employed in the... 

This paper presents a low-order and accurate method for the design of FIR fractional delay (FD) filters with complex coefficients. This method employs least square technique in Hilbert space to approximate the ideal FD transfer function with a FIR filter and to calculate its coefficients. The main advantages of the resulting filter are: very good response at all frequencies compared to other FD filter design methods and a good method to create very small delay. Design examples are presented to illustrate the effectiveness of this new design approach. © World Scientific Publishing Company  

A great deal of computational power and time is necessary for simulating highly heterogeneous fractured reservoirs with complex geometry; the efficiency of these computations is a major subject especially in large-scale heterogeneous and fractured reservoirs. So, simulating large scale, complex and fractured reservoirs with both minimum time and maximum accuracy is the scope of current work. The BiCG-Stabilized solver preconditioned by CPR-AAMG has been developed to achieve acceptable results of high efficiency and robustness for large heterogeneous fractured Black-Oil models. The solver's efficiency is demonstrated in an Iranian fractured field model with heterogeneity. As an observation,... 

This paper applies a novel adaptive approach consisting of Artificial Neural Network (ANN) and Fuzzy Linear Regression (FLR) to improve car ownership forecasting in complex, ambiguous, and uncertain environments. This integrated approach is applied to forecast car ownership in Iran from 1930 to 2007. In this study, the level of car ownership is viewed as the result of demographic, politico-social, and urban structure factors including average family size, total population density, urban population density, urbanization rate, gross national product per capita, gasoline price, and total road length. To capture the potential complexity, uncertainty, and linearity relation between the car... 

Primal-dual interior-point methods (IPMs) have shown their power in solving large classes of optimization problems. However, there is still a discrepancy between the practical behavior of these algorithms and their theoretical worst-case complexity results with respect to the update strategies of the duality gap parameter in the algorithm. Recently, this discrepancy was significantly reduced by Peng, J., Roos, C. and Terlaky, T., 2002, Self-Regularity: A New Paradigm for Primal-Dual Interior-Point Algorithms (Princeton, NJ: Princeton University Press) who introduced a new family of self-regular (SR)-proximity functions based IPMs. In this paper, based on a class of SR proximities, we propose... 

Watermarking is a suitable approach for digital image authentication. Robustness regarding attacks that aim to remove the watermark is one of the most important challenges in watermarking, in general. Several different attacks are reported that aim to make it difficult or impossible for the real owner of the digital watermarked image to extract the watermark. Some of such common attacks are noise addition, compression, scaling, rotation, clipping, cropping, etc. In this paper we address the issue of print and scan attack by introducing a method to model the scanner and printer. Then we will simulate the print and scan attack on the digital images to evaluate its robustness. In addition, we... 

High Density Lipoprotein (HDL) is a lipid-protein complex responsible for transporting cholesterol and triglyceride molecules, as these compounds are unable to dissolve in aqueous environments such as a bloodstream. Among the most well-known possible structures, the belt-like structure is the most common shape proposed for this vital bimolecular complex. In this structure, the protein scaffold encompasses the lipid bilayer and a planar circular structure is formed. Several HDL simulations with embedded components in the lipid section were performed. Here, we applied a series of molecular dynamic simulations using the MARTINI coarse grain force field to investigate an HDL model, with pores of... 

A novel N-path filter using a complex impedance is designed to replace the frontend SAW filters in receivers with on-chip bandpass filters. It is demonstrated that the center frequency of the filter can be tuned solely by changing the value of some capacitances without the need to change the clock frequency. In addition, thanks to the use of smaller capacitors, the silicon area is reduced compared to similar designs. The high-Q bandpass filter is realized utilizing two gyrators and an arrangement of four baseband capacitors with NMOS switches, driven by 4-phase 25% duty cycle clock signals. This paper also analyzes the performance of the proposed filter against imperfections such as thermal... 

Analysis of gamma-ray spectra is an important step for identification and quantification of radionuclides in a sample. In this paper a new gamma-ray spectra analysis algorithm based on Particle Swarm Optimization (PSO) is developed to identify different isotopes of a mixed gamma-ray source and determine their fractional abundances. PSO is an iterative algorithm that imitates the social behaviors observed in nature to solve complex optimization problems. The PSO method is used for complex fitting to the response of a 3 [Formula presented] 3 inch NaI (Tl) scintillation detector and the fitting process is controlled by a test for significance of abundance and computation of Theil coefficient.... 

In this paper, we analyze the role of the number of quantization bits on the third phase of the hierarchical cooperation scheme proposed by Ozgur et al. in 2007. The hierarchical cooperation scheme has a digital architecture and requires quantization of MIMO (Multiple-Input Multiple-Output) observations in the third phase. The choice of the number of quantization bits Q has direct effect on the pre-constant factor of the network throughput. By increasing the number of quantization bits, the MIMO capacity in the second phase increases at the expense of higher computational complexity of the third phase. We investigate such trade-off and show that there is an optimum number of quantization... 

In this research, effective length of one-dimensional combustion in a dilute monopropellant spray, constant area and fixed volume chamber is analytically predicted. A new evaporation rate in the form of d k+1 relation is introduced. In the case of controlling vaporization by radiative heat transfer, k is equal to zero, and when molecular processes control the vaporization, k will be equal to one and in some cases vaporization data need the value of k greater than one to fit properly to related equation. Development of this approach can be used in the design of combustion chambers with optimum length and with using vaporization rate of R = R0〈r〉 0 k/〈r〉k. Spray equation and distribution... 

The analytical study of microchannels has been considered as a preliminary approach to alleviate the difficulties which are normally encountered in numerical and experimental studies. Among the analytical solutions, those with high robustness and low complexities are certainly more attractive. In this work, we present a theoretical approach to predict the temperature field in micro-Poiseuille channel flow with constant wall temperature. The use of power series method simplifies the solution in the current analytical approach. The current analytical derivations are examined for channels with both hot-wall and cold-wall conditions. The current solutions agree well with the numerical solutions... 

The analytical solution of steady-state asymmetric thermo-electro-mechanical loads of a hollow thick infinite cylinder made of porous piezoelectric materials (2D-PPMs) based on two-dimensional equations of thermoelasticity is considered. The general form of thermal and mechanical boundary conditions is considered on the inside and outside surfaces. A direct method is used to solve the heat conduction equation and the non-homogenous system of partial differential Navier equations using the complex Fourier series and the power-exponential law functions method. The material properties are assumed to depend on the radial and circumferential variable and are expressed as power-exponential law...