Sharif Digital Repository

Multistimuli-responsive hyperbranched polymers were synthesized in one-step polymerization using reversible addition-fragmentation chain transfer self-condensing vinyl polymerization (RAFT-SCVP). These hyperbranched polymers responded to UV-vis or sunlight, pH changes, and temperature changes. 2-(dodecylthiocarbonothioylthio)-2-methylpropionic acid known as DDMAT participated in esterification with 2-hydroxyethyl methacrylate to obtain a chain transfer monomer in the name of 2-((2-(((dodecylthio)carbonothioyl)thio)-2-methylpropanoyl)oxy)ethylmethacrylate (MACDT). For the first time, smart hyperbranched polymers were produced with the RAFT-SCVP method in one step by using... 

The strong bases statistical associated fluid theory (SAFT) equations of state allow modeling for a wide range of scales and applications. The equilibrium calculations are very time-consuming in SAFT-based family of equations of state; therefore the number of components used in describing a fluid mixture must be reduced by grouping. On the other hand, in some applications it is required to retrieve the detailed fluid description from equilibrium calculation performed on the lumped fluid description. The purpose of this paper is to develop a systematic approach for lumping and delumping with equilibrium calculations using the Perturbed Chain (PC)-SAFT equation of state. The methodology... 

The synthesis of diamino triphenyl methanes from aniline and aromatic aldehydes was conducted in near critical water and supercritical water. The reaction parameters, such as temperature, density, and reaction time, have been studied. Significant acceleration of the condensation reaction of aniline and aromatic aldehydes can be achieved by using high temperature water, especially near the critical point, in the absence of any acid catalysts. It has been demonstrated that high temperature water act effectively in the place of conventional acid catalysts  

Gas condensate production using technology of multi-stage hydraulically fracturing in shale gas condensate reservoirs' horizontal wells is a new topic of unconventional resources studies. Thus, shale gas condensate as a new source of energy can be considered as an important issue for development and further studies. In this work, a semi-analytical solution of gas and oil two-phase flow is presented for pressure transient analysis (PTA) and rate transient analysis (RTA) of a shale gas condensate reservoir's production data. Fluid flow assumption here is flow in a pseudo triple-porosity porous media, which are matrix, natural fractures and adsorbed gas. Adsorbed gas is a form of gas in porous... 

Short ZnO nanorods and long ZnO nanowires have been produced on SiO2 and Si substrates by VLS and VS mechanisms via a double tube chemical vapor transport and condensation (CVTC) process. The role of reactants and droplet interfaces on the nucleation and growth of ZnO nanorods have been investigated. A conceptual model for nucleation of ZnO nanorods has been proposed by describing the half-oxidation and reduction reactions at the growth front. The importance of Zn vapor in the nucleation phenomena has been studied by changing starting materials. Atomic force microscopy (AFM), scanning electron microscopy (SEM), and EDX analysis have been used to characterize ZnO nanorods and investigate the... 

Techniques of production data analysis for single-phase oil and gas reservoirs have advanced significantly over the past few years. These techniques range from traditional (Arps and Fetkovich) to modern (for the variation of operating conditions at the wellbore). The application of these techniques for analysis of the production data of a gas condensate reservoir may not yield reliable answers due to the fact that the flow of fluid in gas condensate reservoirs is not single-phase. This paper presents the treatment of a modern method of production data analysis (single-phase flow) to analyze the production data of a gas condensate reservoir (two-phase flow). For this purpose, a single-phase... 

A depleted naturally fractured gas condensate reservoir with extremely tight matrix permeability in the center of Iran is used for gas storage. Due to the tightness of the matrix, simulation of this process may present a unique challenge in terms of the importance of diffusion process in flow behavior of the injected gas in matrix blocks. This article presents a multimechanistic (Darcian-type flow and Fickian-type flow) mathematical model to investigate the importance of diffusion process as a function of important rock and fluid parameters. The authors' approach consists of the following steps: (a) development of a 1-D governing equations for a single matrix block consists of a gas... 

Techniques of production data analysis for single-phase oil and gas reservoirs have advanced significantly over the past few years. These techniques range from traditional (Arps and Fetkovich) to modern (for the variation of operating conditions at the wellbore). The application of these techniques for analysis of the production data of a gas condensate reservoir may not yield reliable answers due to the fact that the flow of fluid in gas condensate reservoirs is not single-phase. This paper presents the treatment of a modern method of production data analysis (single-phase flow) to analyze the production data of a gas condensate reservoir (two-phase flow). For this purpose, a single-phase... 

In the present study, titanium nano-particles have been synthesized using chemical vapor condensation (CVC) process. Reaction of sodium and titanium tetrachloride vapors in the tube furnace resulted in the production of titanium nano-particles that were encapsulated in sodium chloride. Dried Argon gas was employed as a carrying agent. Titanium nano-particles were contained in an ethanol bath. Transmission Electron Microscopy (TEM), Scanning Electron Microscopy (SEM) and X-ray Diffraction (XRD) were employed for analysis and characterization of nano-particles. The size of primary particles was smaller than 100 nm and secondary particles were submicron agglomerations  

A novel reduced order formulation is proposed for the vibration analysis of conical shells containing stationary fluid. Hamiltonian approach is followed to obtain the governing equations of motion for the structure. Utilizing the Navier-Stokes equations and simplifying for irrotational, compressible and inviscid assumptions, the final fluid equation is obtained. A general solution based on the Galerkin method is proposed for the conical shell in vacuum. Several boundary conditions are investigated to show the capability of the proposed solution. A novel reduced order formulation based on the finite element method is developed for solution of the fluid equation. Static condensation technique... 

Condensate and water banking around gas condensate wells result in vital well deliverability issues. Wettability alteration of near wellbore region to gas wetting condition is known to be the most novel and the only permanent method, to improve condensate well productivity. In this work, a water based nanofluid is used to change the wettability of sandstone reservoir rocks from strongly liquid wetting to intermediate gas wetting condition. Static contact angle measurements demonstrated significant increase of liquid phase contact angle as a result of chemical treatment with SurfaPore M nanofluid. The characteristics of SurfaPore M adsorption on sandstone rock are quantified through kinetic... 

A complete cycle of droplet nucleation, growth, coalescence and jumping on different textured hydrophobic and superhydrophobic surfaces is studied for the first time, using a 2-D double distribution function thermal lattice Boltzmann method. First, droplet nucleation mechanism on smooth and rough surfaces is studied in detail. The results reveal the presence of cooled vapor layer instability in the condensation on completely smooth surfaces. However, on the rough surfaces and near the roughness a completely different mechanism is observed and the nucleation occurs on the roughness wedges. Also, the condensation on different textured surfaces with nominal contact angles θa=90°,120°,155° is... 

ZnO tetrapods and rods were grown on silicon and thermally oxidized porous silicon substrates with and without Au catalyst layer by carbothermal reduction of ZnO powder through chemical vapor transport and condensation method (CVTC). Porous silicon was fabricated by electrochemical etching of silicon in HF solution. The effect of substrates on morphology, structure and photoluminescence spectra of ZnO nanostructures has been studied. The texture coefficient (TC) of each sample was calculated from XRD data that demonstrated random orientation of ZnO nanostructures on the oxidized porous silicon substrate. Moreover, TC indicates the effect of Au catalyst layer on formation of more highly...