Sharif Digital Repository

The out-of-pack cementation method was applied to coat the Nickel-based super alloy IN738LC with Si-modified aluminide. Different mixtures of the pack containing pure Al, Si, alumina powders as an inert filler, and NH4Cl as a halide salt activator were used for co-deposition at 950 and 1,050°C. The results showed although the amount of subhalide vapour pressures of Al and Si were equal at 1,050°C, Al atoms diffused only after Si atoms had been deposited. Before heat treatment, the coating thickness formed by the pack containing 2.3 wt.% Al was 6 μm more than that containing 3.5 wt.% Al. After heat treatment, thickening coatings formed within the pack containing 2.3 wt.% Al was less than that... 

Asphaltene deposition during enhanced oil recovery (EOR) processes is one of the most problematic challenges in the petroleum industry, potentially resulting in flow blockage. Our understanding of the deposition mechanism with emphasis on the rate of the asphaltene deposition is still in its infancy and must be developed through a range of experiments and modelling studies. This study aims to investigate the rate of asphaltene deposition through a visual study under different gas injection scenarios. To visualise the asphaltene deposition, a high-pressure setup was designed and constructed, which enables us to record high-quality images of the deposition process over time. Present research... 

This study uses a 5-lobe symmetric model to investigate total, lobar and generational particle deposition fractions in the lungs during successive cycles. It was found that for the particle size between 0.05 and 2 μm and the tidal volumes greater than 1000 ml, the effect of successive cycles helped predict more deposition fraction per cycle up to about 16% than that of a single cycle. The mentioned range of tidal volumes corresponds to light or heavy physical activities. Therefore, it can be understood that people, when physically active, exposed to particulate matter within the mentioned size range are at higher health risk as compared to both the resting state and the same state... 

In this study, titanium dioxide nano powders were electrophoretically deposited on the stainless steel in Isopropanol and Triethanolamine as a solvent and dispersant, respectively. The effects of deposition parameters including deposition voltage (5 to 20 V) and deposition time (5 to 60 s) on the microstructure and surface topography were examined by scanning electron microscope (SEM) and scanning probe microscope (SPM), respectively. In addition, the effects of these deposition parameters on packing density were investigated. This research revealed that substrate surface is fully covered with increasing deposition voltage and deposition time. Therefore packing density of deposited films is... 

Carbon nanotubes (CNTs) were grown on deposited Ni on macroporous silicon by thermal chemical vapor deposition (TCVD) method using CH4 as the reaction gas. Macroporous silicon was fabricated by electrochemical etching of P-type silicon in organic electrolytes. The effect of oxidation of porous silicon (PS) on growth rate, morphology and structure of CNTs has been studied. The SEM micrographs and Raman spectra indicated that the nanotubes grown on the oxidized PS are more homogeneous and regular than those grown on the pristine PS and growth rate of CNTs grown on oxidized PS higher than those grown on pristine PS. In addition, the CNTs grown on the non-oxidized PS have different morphology... 

In the metal deposition process, the performance of the nozzle is crucial to the quality of clad. Continuous coaxial nozzles are broadly used in this process for repairing two- and three-dimensional parts, because it can create a homogeneous distribution of powder particles. In addition, an inert gas can be applied using this type of nozzles which shields powder particles and laser interaction zone, and prevents the surface from oxidizing at high process temperatures. However, when this type of nozzle is tilted from the vertical axis for cladding non-horizontal surfaces, the effect of gravity on powder particles affects the uniformity of powder distribution at the nozzle outlet. This matter... 

In the metal deposition process, the performance of the nozzle is crucial to the quality of clad. Continuous coaxial nozzles are broadly used in this process for repairing two- and three-dimensional parts, because it can create a homogeneous distribution of powder particles. In addition, an inert gas can be applied using this type of nozzles which shields powder particles and laser interaction zone, and prevents the surface from oxidizing at high process temperatures. However, when this type of nozzle is tilted from the vertical axis for cladding non-horizontal surfaces, the effect of gravity on powder particles affects the uniformity of powder distribution at the nozzle outlet. This matter... 

We present a procedure for simultaneous deposition of enzyme-laden chitosan/reduced graphene oxide (rGO) film by electrophoretic deposition (EPD) for fast and efficient detection of glucose. The role of rGO nanosheets is studied on the EPD kinetics of the enzyme-laden suspensions. Investigating the performance of the biosensor by electrochemical techniques indicates its high sensitivity (9700 μA.mM−1.cm−2), low limit of detection (4 µM), and suitable selectivity. © 2021 Elsevier B.V  

This paper is a continuation of our previous paper (part 1; 10.1021/ef401857t), which discussed the roles of different phenomena effecting the deposition of asphaltene from model oil systems and before the onset of asphaltene precipitation. The study in this paper is to understand the depositional tendency of asphaltene using a quartz crystal microbalance with dissipation (QCM-D) measurements and their corresponding modeling for real crude oil systems with emphasis after the onset of asphaltene precipitation  

In the first stage, chitosan (CH)-hydroxyapatite (HA)-multiwalled carbon nanotube (MWCNT) composite coatings were synthesized by electrophoretic deposition technique (EPD) on 316L stainless steel substrates at different levels of pH and characterized by X-ray diffraction (XRD), Raman spectroscopy, FTIR and field emission scanning electron microscopy (FESEM). A smooth distribution of HA and MWCNT particles in a chitosan matrix with strong interfacial bonding was obtained. In the next stage, effects of pH and MWCNT content of the suspension on the corrosion behavior and deposition mechanism were studied. Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) curves... 

Different models have been proposed for deposition of asphaltene on reservoir rocks that due to complexity of asphaltene nature, most of them have not been productive. Here, a reliable model is proposed which despite of previous models, considers the change in asphaltene saturation in the core. The obtained experimental data in the laboratory was used for model validation. In this work, a series of core flooding tests was carried out in presence of connate water at different solvent-oil volume ratios. Pressure drop was measured at three different terminals along the core. The obtained experimental data as well as mass balance equations, momentum equation, asphaltene deposition and... 

Alkaline doping (Cs, Rb) in CH3NH3PbI3 (MAPbI3) is known to enhance the stability of perovskite solar cells. The films are usually deposited using anti-solvent method, which is tricky and not applicable for large scale deposition. Besides, in case of CsxMA1−xPbI3 the amount of Cs must be carefully controlled to prevent CsI phase formation. Herein, we report an atmospheric pressure vapor assisted solution process (AP-VASP) for the growth of Cs doped MAPbI3 perovskite films that features highly uniform morphology, pin-hole free films, large grain size, as well as being scalable. The CsxMA1−xPbI3 films are formed by the reaction of Cs doped PbI2 films with MAI vapor in a simple oven. We... 

A high performance asymmetric supercapacitor (ASC)has been fabricated by using nickel oxide-cobalt oxide nanosheets (NiO–CoO NSs), which were directly grown on carbon nanotubes (CNTs)and hydrothermal carbon spheres (HTCs)as positive and negative electrodes, respectively. Both electrode materials are binder-free prepared by using a catalytic chemical vapour deposition (CVD)approach followed by a facile hydrothermal method for cathode and a one-step environmental-friendly route called hydrothermal carbonization for anode. Using NiO–CoO NSs@CNTs and HTCs, which were directly grown on Ni foam, not only leads to a very small equivalent series resistance, but also provides an impressive capacitive... 

The biodegradation behavior of Mg, coated by polymethyl methacrylate as well as polymethyl methacrylate (PMMA)−bioactive glass (BG) composite was investigated. Electrophoretic deposition and dip coating techniques were adopted to prepare composite coating using a suspension of different percentages of the above two chemical materials. The deposited coatings were characterized using SEM, EDS, FTIR, and water contact angle measurements. Biodegradation behavior study of the coated Mg was performed using linear polarization, impedance spectroscopy, and immersion tests in simulated body fluid. The compact and homogeneous composite coating was developed as evidenced by electron microscopy results.... 

Vertically aligned ZnO nanowires (NWs) hybridized with reduced graphene oxide sheets (rGO) were applied in efficient visible light photoinactivation of bacteria. To incorporate graphene oxide (GO) sheets within the NWs two different methods of drop-casting and electrophoretic deposition (EPD) were utilized. The EPD method yielded effective penetration of the positively charged GO sheets into the NWs to form a spider net-like structure, whereas the drop-casting method resulted in only a surface coverage of the GO sheets on top of the NWs. The electrical connection between the EPD-incorporated sheets and the NWs was checked by monitoring the electron transfer from UV-assisted photoexcited ZnO... 

Hydroxyapatite (HA) coatings in and onto anodized TiO2 nanotube arrays were presented and prepared by electrophoretic deposition technique (EPD). Coatings were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). EPD proved to be an innovative and versatile technique to coat HA on and into nanotubular structures of TiO2 with enhanced adhesion between nanotubes and HA particles provided by mechanical interlocking. After EPD of HA on TiO2 layer, samples were sintered at 400 °C, 600 °C and 800 °C for 2 h in an Ar atmosphere. Effect of EPD processing parameters on thickness of the deposits and rate of deposition was elucidated for HA coatings on the nanotubular TiO2... 

In this study, tungsten oxide films were deposited by pulsed-laser deposition (PLD) technique. The as-deposited films were annealed at 250 °C in air for 1 h. The surface morphology, microstructure, crystalline phase, and chemical composition of the films were characterized by SEM, XRD and XPS techniques. Pt nanoparticles were deposited onto the tungsten oxide films through a two-step process. First of all, a layer of PtCl2 was coated on the WO3 surface by drop-drying the PtCl2 solution onto the WO3 surface at 60 °C. Consequently, the reduction of the PtCl2 into the metallic Pt nanoparticles was performed at 200 °C. In this study, the effect of the temperature during hydrogen reduction of... 

By fabrication of several bolometric detectors on the YBCO film made of Metal-Organic Deposition (MOD) and the effect of pattering and film parameters on the optical responsivity of transition edge sensors is investigated. The low cost nonfluorine (MOD) method has been applied to fabricate YBCO thin films with different patterning parameters. The measurement results of the optical responsivity versus modulation frequency up to 100 KHz for these devices are reported  

The suspension of titania nanoparticles in different alcohols (methanol, ethanol, and butanol) was prepared and triethanolamine (TEA) was used as a dispersant. The suspensions were characterized by different tests such as sedimentation, zeta potential, and Fourier transform infrared spectroscopy. The electrophoretic deposition (EPD) was performed at various voltages and times. EPD from butanolic suspension (0.8 g/L TEA) showed the slowest kinetics, because of the low electrophoretic mobility of titania nanoparticles in it (2.40 × 10-5 cm2·(V·s)-1). Also, it was observed that at low voltages (5, 10, and 20 V), the EPD kinetics from methanolic suspension (0 g/L TEA) was the fastest; however,...