Sharif Digital Repository

Supported Ionic Liquid Membranes (SILMs) are fabricated by saturating the pores of a porous support with ionic liquids. To assess the performance of SILMS, it is necessary to obtain data about the properties of ionic liquids such as diffusivity, solubility, and etc. To accomplish this task, in this project the permeability and diffusivity of CO2 and CH4 through three immidazolium-based ionic liquids: [bmim][PF6], [hmim][Tf2N], and "1-methyl-3-(3- tri methoxi silil propyl) imidazolium bis (tri fluoro methyl solphonyl)" , in the temperature range between 27-45 ℃ and pressures within 10-50 kPa, are measured. It is shown in data validation section that the results of this study are in good... 

In this research project, Ni electrodeposition process has been modeled by a 3D coupled continuum-kinetic Monte Carlo simulation. Kinetic Monte Carlo module processes surface reactions along the substrate using electrochemical equations for the relating events. Continuum model also determines concentration of the whole system according to a 3D interpretation of diffusion law in solutions. After running each module, exchange of data between two codes is done and boundary conditions are updated. In fact, the whole simulation time is divided by small time steps relating to time fastest reactions need to proceed. Present model will generate three outputs: current-time curve, surface morphology... 

Each of us at some point in our life has been astonished by the observation of the collective motion of certain animals such as birds, fishes or insects. These coherent and synchronized structures are apparently produced without the active role of a leader in the grouping and it has been reported even for some microorganisms such as bacteria or red blood cells. In all the mentioned examples agents are surrounding with the moving fluid which can affect the collective behavior of the system. The collaborative flock of birds in windy conditions and the swimming of fishes in rivers or along oceanic currents are some examples. Moreover, micro-organisms produce different collective behavior in the... 

In recent years, there have been huge advancements in fabrication of micron-sized devices such that they enabled engineers to create a wide range of miniaturized systems, each of which is utilized in mechanical, electrical, and thermal applications. Micromixers are one of these devices with the role of mixing various micro flows. These devices are broadly used for chemical, biological, and biomedical assays. Among variety of micromixers, one that employs electrokinetic transport phenomenon is of great popularity. For instance, mixing under electroosmotic flow enables accurate process control and eliminates the need for moving components inside micromixer. The very complex nature of electric... 

The production of oil is challenging in the fractured reservoirs due to the large transmissibility contrast between matrix and fracture, and primary recovery is often low. The recovery efficiency depends on the relationship between the fracture and matrix permeability, and is strongly dependent on the wettability of the matrix, which reflects the imbibition potential of the reservoir. Among these parameters the multiphase fluid flow in gas invaded zone is the point of interest in this project. Gas injection in naturally fractured reservoirs maintains the reservoir pressure, and increases oil recovery primarily by gravity drainage and to a lesser extent by mass transfer between the flowing... 

We used spectroscopic techniques to study self-assembled structures based on nucleobases like G-quadruplexes and macrocycles. Also we used DOSY NMR technique to study hydrogen bonding network in alcohol solutions. First part of our results indicate thermodynamic stability and slow kinetic of G-quadruplexes in apolar aromatic solvents like toluene. Also our results show easy monitoring of formation of each K+ or Na+ complex by NMR, due to the low solubility of alkaline metal salts in apolar media and possibility to stop at any given time in order to control G-quadruplex yield. When combined with suitable functional units, these valuable attributes may be used for the noncovalent synthesis of... 

Given a snapshot of a network, link preditction methods try to infer future intractions be-tween its nodes. These methods may be used in either analyzing current state of the network or predicting future links of it. Link prediction techniques have many applications among which we can mention recommendation systems. These systems are implemented for com-mercial reasons or preventing user confusion in huge amount of information available.A new perspective toward link prediction is based on supervised random walk. In such methods, a random walker starts from a node in the network and randomly traverses to one of the current node’s neighbours with a probability proportional to the chosen link’s... 

Social networks play an important role in the spread of information, news and users’decisions. An important type of these networks are location-based networks where users can post the time and location of their checks in different places. Check-ins of a user may incentivize her friends to visit the same location in the near future.This phenomena is called diffusion process. Previous works often assume that the generation of an event just increases the probability of subsequent events in a near future. Even though the assumption is quite valid in the social networks like Twitter,it is not the sufcient assumption in spatio-temporal social networks where the users’physical limitations and... 

Lithium ion battery is one of the innovative and emerging technologies in energy sector that has played a major role in electricity supply security by integration of renewable energy technologies in electrical grid, implementation of electrical transportation system and de-carbonation of the both sectors in recent years. On the other hand, the formation of the potential market of technology as one of the functions of the technological innovation system plays an essential role in creation and advancement of innovation in the energy sector. Therefore, in this thesis, the development of lithium ion battery technology in Iran has been investigated from the perspective of the technology market in... 

In this project, using experimental results for permeation of gases H2, He, N2, and CO on a microporous membrane (the applied sample was a ceramic membrane) and modified equations, pore diameter, tortuosity, and porosity were determined for this type of membrane. Furthermore, pore diameter, critical volume, and characteristic energy of a carbon molecular sieve membrane were calculated using experimental data for CO2 adsorption on this type of membrane. Diffusivities of CO2, N2, and Ar were also calculated by means of the uptake, time lag/adsorption, and permeability/adsorption tests on carbon molecular sieve membranes utilizing experimental data obtained for this type of membranes and the... 

Modern technology is accompanied by miniaturized devices. With increasing the use of micro satellites and micro airial vehicles (MAVs), finding new power-generating resources is inevitable. Batteries were always an option however high efficiency, long life-span and environmental consideration have encouraged the researches to focus on micro combustion. On the other hand, hydrocarbon fuel contains about 100 times more energy per unit mass than lithium-ion batteries. Micro combustion is defined as a combustion which is occurred bellow quenching distance and old literatures were uncertain about occurrence of such combustion. In this paper we present the fundamental concepts of micro combustion... 

In this study the feasibility of xenon separation from xenon-krypton mixture was investigated by utilizing of the chromatographic column filled with nano and micron sized NaY zeolite. For this purpose the nano NaY with the yield of 100% related to Al2O3 and the average size of 98.6 nm was synthesized through the clear solution method with the mid-adding of NaOH. Furthermore, a novel method for granulation of nano zeolite was developed by utilizing sodium alginate as an external template. In this method the production of uniform spherical granules with the different sizes in the range of several milimiteres to 100 µm was easily performed. Moreover, the results showed that the adding of... 

In this study, at first the V2O5 spent catalysts were characterized. The aim was to identifying whether these catalyst may be regenerated. Then, for feasibility study of them, three methods were applied: washing, diffusion and milling the spent catalysts for their subsequent reproduction. A variety of techniques such as XRD, XRF, AAS, TPR and TPO were applied in order to identify factors contributing in vanadium pentoxide catalysts deactivation. The results showed that approximately all of pollutants caused their performance deterioration, while they still have some active phases. Then, the polluted catalysts were washed (their yield increased from 43% to 72.2%). In the underside of the... 

Diffusion Weighted Imaging (DWI) is a non-invasive method for investigating the brain white matter. Assuming the Gaussian model for diffusion process, diffusion tensor is constructed and Diffusion Tensor Images (DTI) are obtained. White matter is constructed from fiber bundles which have crossing in most of the regions. In the crossing regions, the Gaussian model cannot work. In this situation, DTI cannot reconstruct the fiber structures correctly. Therefore, High Angular Resolution Diffusion Imaging (HARDI) was proposed to solve this problem. Q-ball imaging is a new technique for HARDI reconstruction which is useful for estimating diffusion Orientation Distribution Function (ODF). ODF is a... 

The aim of this research is to model the separation and transport of multi-component gas mixture through a nanoporous membrane by using pore network models (PNM).
The first part of this project represents the membrane simulating by means of the PNM. A three-dimensional network is used to represent the membrane’s pore space and it consists of two parts; pore and throat. The pores are the main parts of the network and their diameter is characterized according to the pore size distribution of the membrane. Every throat connects two pores and the number of throats which is connected to each pore is named "coordination number". Using a variety size of pores and throats leads to production of... 

This study consists of two parts: steady state calculations and neutron noise calculations in the frequency domain for two rectangular and hexagonal geometries. In the steady state calculation, the neutron diffusion and its adjoint equations are approximated by two-dimensional coordinates in two-group energy and are solved using the average current nodal expansion method. Then, by considering the node size in the dimensions of a fuel assembly, different orders of flux expansion are investigated. For verification purposes, the calculations have been performed by power iteration method for two test problems of BIBLIS-2D and IAEA-2D. For rectangular geometry with increasing flux expansion order... 

The emergence of online social networks (OSN) has encouraged scientists to investigate them more deeply due to availability of excessive data and increased computational power. Diffusion is a fundamental process taking place in such networks. The spread of news, ideas, influence and diseases are examples of diffusion in social networks. The importance of information diffusion in different disciplines such as economics, politics and social behavior has motivated us to study diffusion networks in this thesis. Diffusion’s behavior is strongly influenced by the underlying network in social networks. Despite this fact most research done in this area ignores the dynamics of the underlying network.... 

The results of a theoretical and experimental study of a resonant interaction between a surface wave and two internal waves are presented. It is shown that the motion of a surface wave in a horizontally infinite two-layer fluid can lead to generation of two oblique internal waves. The internal waves have short wave length compared to the surface wave and have nearly opposite propagation directions. The frequencies of the internal waves are approximately half of the frequency of the surface wave.
In present thesis, Higher-order effects in sub-harmonic resonant interaction of a surface wave with a pair of interfacial waves in a two-layer fluid are studied theoretically and experimentally.... 

New materials as hybrid materials or laminate composites, due to combination of many properties, can be used in many industries. The aim of this research is bonding of three-layered St/AZ31/St composite by roll-bonding process. The roll-bonding process was performed at three preheating temperatures, 340, 400 and 450 ⁰C, with thickness reduction of 30 to 68% and different thicknesses of intermediate layer (AZ31). In order to improve the bonding strength, the as-rolled specimens were annealed at constant temperature of 375 ⁰C. For evaluation of bond strength and investigating the formation of a diffusion layer, the results of peel test and microscopic images were studied. Tensile specimens... 

Fuel Cell with Polymer membrane uses a reaction with Hydrogen and Oxygen as reactants to produce electricity. As the product of this reaction is water, this fuel cell produce clean energy. But if the produced water accumulates it can cause problems for fuel cell which can lead to complete failed of fuel cell. On the other hand water shortage in PEM fuel cell also can cause problems. So we need to have continues water management inside of PEM fuel cell. For this sake having knowledge about water inside of PEM fuel cell and specially the Gas Diffusion Layer which is the layer with responsibly to help the fuel cell to manage the water, is necessary. One of the ways for gaining that knowledge...