Sharif Digital Repository

An aniline-based polymer was electrochemically prepared and applied as a new fiber coating for solid phase microextraction (SPME) of some priority phenols from water samples. The polyaniline (PANI) film was directly electrodeposited on the platinum wire surface in sulfuric acid solution using cyclic voltammetry (CV) technique. The efficiency of new coating was investigated using a laboratory-made SPME device and gas chromatography with flame ionization detection for the extraction of some phenols from the headspace of aqueous samples. The scanning electron microscopy (SEM) images showed the homogeneity and the porous surface structure of the film. The results obtained proved the ability of... 

A metal organic framework-polyaniline (MOF/PANI) nanocomposite was electrodeposited on a stainless steel wire and used as a solid phase microextraction (SPME) fiber coating. The electropolymerization process was carried out under a constant deposition potential and applied to the corresponding aqueous electrolyte containing aniline and MOF particles. The employment of MOFs with their large and small cages and 3-D structures in synthesizing a nanocomposite was assumed to be efficient constitutes to induce more non-smooth and porous structures, approved by scanning electron microscopy (SEM) images. Three different MOFs were incorporated to synthesize the desired nanocomposites and the... 

This work concerns with experimental and analytical investigation of role of ultrasonic wave radiation in relative permeability of both wetting and non-wetting phases in a free gravity drainage process in porous media under the influence of ultrasonic wave. Glass beads ranged from 70 to 100 mesh sizes were packed and used in the tests. The working fluids consist of distilled water, kerosene and Doroud and Paidar crude oils as wetting and air as non-wetting phase. The measured oil recovery data along with Hagoort (1984) backward methodology were used to determine and to compare the relative permeability of wetting phases in presence and absence of ultrasonic radiation. In addition, the... 

This work concerns with experimentally and analytically investigation of free gravity drainage process in porous media under the influence of ultrasonic wave radiation. Glass beads ranges from 70 to 100 mesh sizes were packed and used in the tests. The working fluids consist of distilled water, kerosene and Doroud and Paidar crude oils as wetting and air as non-wetting phase. The measured oil recovery data along with Hagoort (1984) backward methodology were used to determine and to compare the relative permeability of wetting phases in presence and absence of ultrasonic radiation. In addition the relative permeability of non-wetting phases for both cases were calculated from inverse modeling...